Heterogenization of molecular catalysts within porous solids: the case of Ni-catalyzed ethylene oligomerization from zeolites to metal-organic frameworks.
Chem Soc Rev
; 52(22): 8059-8076, 2023 Nov 13.
Article
em En
| MEDLINE
| ID: mdl-37902965
ABSTRACT
The last decade has seen a tremendous expansion of the field of heterogenized molecular catalysis, especially with the growing interest in metal-organic frameworks and related porous hybrid solids. With successful achievements in the transfer from molecular homogeneous catalysis to heterogenized processes come the necessary discussions on methodologies used and a critical assessment on the advantages of heterogenizing molecular catalysis. Here we use the example of nickel-catalyzed ethylene oligomerization, a reaction of both fundamental and applied interest, to review heterogenization methodologies of well-defined molecular catalysts within porous solids while addressing the biases in the comparison between original molecular systems and heterogenized counterparts.
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MEDLINE
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En
Ano de publicação:
2023
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Article