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Complexation study of a 1,3-phenylene-bridged cyclic hexa-naphthalene with fullerenes C60 and C70 in solution and 1D-alignment of fullerenes in the crystals.
Mei, Peifeng; Morimoto, Hirofumi; Okada, Yuta; Matsuo, Kyohei; Hayashi, Hironobu; Saeki, Akinori; Yamada, Hiroko; Aratani, Naoki.
Afiliação
  • Mei P; Division of Materials Science, Nara Institute of Science and Technology (NAIST) 8916-5 Takayama-cho Ikoma 630-0192 Japan aratani@ms.naist.jp.
  • Morimoto H; Division of Materials Science, Nara Institute of Science and Technology (NAIST) 8916-5 Takayama-cho Ikoma 630-0192 Japan aratani@ms.naist.jp.
  • Okada Y; Division of Materials Science, Nara Institute of Science and Technology (NAIST) 8916-5 Takayama-cho Ikoma 630-0192 Japan aratani@ms.naist.jp.
  • Matsuo K; Division of Materials Science, Nara Institute of Science and Technology (NAIST) 8916-5 Takayama-cho Ikoma 630-0192 Japan aratani@ms.naist.jp.
  • Hayashi H; Division of Materials Science, Nara Institute of Science and Technology (NAIST) 8916-5 Takayama-cho Ikoma 630-0192 Japan aratani@ms.naist.jp.
  • Saeki A; Department of Applied Chemistry, Graduate School of Engineering, Osaka University 2-1 Yamadaoka Suita 565-0871 Japan.
  • Yamada H; Division of Materials Science, Nara Institute of Science and Technology (NAIST) 8916-5 Takayama-cho Ikoma 630-0192 Japan aratani@ms.naist.jp.
  • Aratani N; Division of Materials Science, Nara Institute of Science and Technology (NAIST) 8916-5 Takayama-cho Ikoma 630-0192 Japan aratani@ms.naist.jp.
RSC Adv ; 13(47): 33459-33462, 2023 Nov 07.
Article em En | MEDLINE | ID: mdl-38025867
ABSTRACT
To investigate the host ability of a simple macrocycle, 1,3-phenylene-bridged naphthalene hexamer N6, we evaluated the complexation of N6 with fullerenes in toluene and in the crystals. The complexes in the solid-state demonstrate the one-dimensional alignment of fullerenes. The single-crystals of the C60@N6 composite have semiconductive properties revealed by photoconductivity measurements.

Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2023 Tipo de documento: Article

Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2023 Tipo de documento: Article