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Synthesis of Chiral α-Aryl Ketones by Photoredox/Nickel-Catalyzed Enantioconvergent Acyl Cross-Coupling with Organotrifluoroborate.
Wang, Weichen; Shen, Chaoren; Zhang, Linli; Dong, Kaiwu.
Afiliação
  • Wang W; Shanghai Frontiers Science Center of Molecule Intelligent Syntheses and Shanghai Key Laboratory of Green Chemistry and Chemical Processes, School of Chemistry and Molecular Engineering, East China Normal University, Shanghai 200062, China.
  • Shen C; Shanghai Frontiers Science Center of Molecule Intelligent Syntheses and Shanghai Key Laboratory of Green Chemistry and Chemical Processes, School of Chemistry and Molecular Engineering, East China Normal University, Shanghai 200062, China.
  • Zhang L; Shanghai Frontiers Science Center of Molecule Intelligent Syntheses and Shanghai Key Laboratory of Green Chemistry and Chemical Processes, School of Chemistry and Molecular Engineering, East China Normal University, Shanghai 200062, China.
  • Dong K; Shanghai Frontiers Science Center of Molecule Intelligent Syntheses and Shanghai Key Laboratory of Green Chemistry and Chemical Processes, School of Chemistry and Molecular Engineering, East China Normal University, Shanghai 200062, China.
Org Lett ; 26(4): 850-854, 2024 Feb 02.
Article em En | MEDLINE | ID: mdl-38251833
ABSTRACT
Photoredox/nickel-catalyzed enantioconvergent acyl cross-coupling of carboxylic derivatives with racemic secondary organotrifluoroborate was developed for the synthesis of an enolizable chiral α-aryl ketone under mild neutral conditions. Moderate to high yields and good enantioselectivities were achieved.
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Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2024 Tipo de documento: Article
Texto completo
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Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2024 Tipo de documento: Article