Enhanced activation of persulfate by modified red mud biochar for degradation of dye pollutant: Resource utilization and non-radical activation.

ABSTRACT

The substantial development of the dyeing and printing industry has resulted in an increased discharge of dye wastewater containing a large amount of recalcitrant organic pollutants. Furthermore, the landfill disposal of red mud has led to significant environmental pollution such as soil erosion and groundwater contamination. Therefore, this study aimed to promote the resource utilization of red mud by preparing advanced oxidation catalyst, resulting in effective treatment of dye wastewater, and the primary reaction mechanism was revealed. In this study, biochar-loading red mud (RBC) was applied to activate persulfate (PDS) for the degradation of acid orange 7 (AO7) with the initial concentration of 50 mg L-1. The maximum removal rate of 2.45 mg L·min-1 was achieved in 20 min and corresponding with the removal ratio of 98.0% under the PDS concentration of 20 mM (4.76 g L-1). Eventually, the removal ratio of 99.2% was attained within 60 min. The high catalytic efficiency was probably ascribed to the singlet oxygen (1O2) dominant non-radical pathway and RBC-mediated electron transfer mechanism. It was found that Fe(II), specific surface areas and functional groups on the catalyst were highly related to its catalytic efficiency and passivation. RBC had better reusability due to the loading of biochar and the reduction of zero-valent iron. The non-radical pathway mechanism and electron transfer mechanism were proposed for the activation of PDS, and non-radical pathway played a dominant role. Besides, the degradation pathways and toxicity assessment were analyzed. This research proposed a new electron transfer mechanism for activation process of PDS, which can provide a theoretical support for further studies. Overall, this study demonstrated that catalysts synthesized from red mud and biomass exhibit highly efficient activation in degrading the model pollutant AO7 through PDS activation. The catalyst displayed promising reusability and practical applicability, offering potential advancements in both the resource utilization and reduction of red mud.