Pore size distribution and Al oxide content significantly regulated the effects of humic acid on perfluorooctanoic acid transport in natural soils.

ABSTRACT

The ubiquity of dissolved organic matter (DOM) makes it encounter the released perfluorooctanoic acid (PFOA) in subsurface environment. However, the effect of DOM (e.g., humic acid, HA) on PFOA transport in soils and the critical influencing factors and mechanisms remain obscure. Column experiments were conducted to explore PFOA transport with the presence of different concentrations of HA in three types of soils and two types of Al oxide coated sand. Results revealed soil properties significantly regulate the effects of HA on PFOA transport, for which pore size distribution, minerals content (e.g., Al oxide) and pH were critical influencing soil-properties. For soil with large mesopore volume, pore blockage caused by HA controlled the effect of HA on PFOA transport. Large mesopore volume significantly alleviated pore blockage of HA, and led to insignificant effects of HA on PFOA transport. For soil exhibited minimum mesopore volume, Al oxide content and pH dominated the effect of HA on PFOA transport. Results from Al oxide coated sand (low mesopore volume) columns further proved that higher Al oxide content and lower pH caused more significant facilitating effect of HA on PFOA transport via site competition. Results highlighted the importance of considering pore size distribution and Al oxide content when assessing PFOA mobility capacity with co-transport with DOM in soils.