A brief note on substantial sub-daily arsenic variability in pumping drinking-water wells in New Hampshire.
Sci Total Environ
; 919: 170838, 2024 Apr 01.
Article
em En
| MEDLINE
| ID: mdl-38340869
ABSTRACT
Large variations in redox-related water parameters, like pH and dissolved oxygen (DO), have been documented in New Hampshire (United States) drinking-water wells over the course of a few hours under pumping conditions. These findings suggest that comparable sub-daily variability in dissolved concentrations of redox-reactive and toxic arsenic (As) also may occur, representing a potentially critical public-health data gap and a fundamental challenge for long-term As-trends monitoring. To test this hypothesis, discrete groundwater As samples were collected approximately hourly during one day in May and again in August 2019 from three New Hampshire drinking-water wells (2 public-supply, 1 private) under active pumping conditions. Collected samples were assessed by laboratory analysis (total As [AsTot], As(III), As(V)) and by field analysis (AsTot) using a novel integrated biosensor system. Laboratory analysis revealed sub-daily variability (range) in AsTot concentrations equivalent to 16 % - 36 % of that observed in the antecedent 3-year bimonthly trend monitoring. Thus, the results indicated that, along with previously demonstrated seasonality effects, the timing and duration of pumping are important considerations when assessing trends in drinking-water As exposures and concomitant risks. Results also illustrated the utility of the field sensor for monitoring and management of AsTot exposures in near-real-time.
Texto completo:
1
Base de dados:
MEDLINE
Assunto principal:
Arsênio
/
Poluentes Químicos da Água
/
Água Potável
/
Água Subterrânea
País como assunto:
America do norte
Idioma:
En
Ano de publicação:
2024
Tipo de documento:
Article