Sequential C-F Bond Transformation of the Difluoromethylene Unit in Perfluoroalkyl Groups: A Combination of Fine-Tuned Phenothiazine Photoredox Catalyst and Lewis Acid.

Sugihara, Naoki; Nishimoto, Yoshihiro; Osakada, Yasuko; Fujitsuka, Mamoru; Abe, Manabu; Yasuda, Makoto

Sugihara, Naoki; Nishimoto, Yoshihiro; Osakada, Yasuko; Fujitsuka, Mamoru; Abe, Manabu; Yasuda, Makoto.

Afiliação

Sugihara N; Department of Applied Chemistry, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka, 565-0871, Japan.
Nishimoto Y; Department of Applied Chemistry, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka, 565-0871, Japan.
Osakada Y; Innovative Catalysis Science Division, Institute for Open and Transdisciplinary Research Initiatives (ICS-OTRI), Osaka University, 2-1 Yamadaoka, Suita, Osaka, 565-0871, Japan.
Fujitsuka M; Innovative Catalysis Science Division, Institute for Open and Transdisciplinary Research Initiatives (ICS-OTRI), Osaka University, 2-1 Yamadaoka, Suita, Osaka, 565-0871, Japan.
Abe M; SANKEN (The Institute of Scientific and Industrial Research), Osaka University, Mihogaoka 8-1, Ibaraki, Osaka, 567-0047, Japan.
Yasuda M; Institute for Advanced Co-Creation Studies, Osaka University, Yamadagaoka 1-1, Suita, Osaka, 565-0871, Japan.

Angew Chem Int Ed Engl ; 63(14): e202401117, 2024 Apr 02.

Article em En | MEDLINE | ID: mdl-38380969