Modular Synthesis of Improbable Rotaxanes with All-Benzene Scaffolds.
Angew Chem Int Ed Engl
; 63(18): e202401838, 2024 Apr 24.
Article
em En
| MEDLINE
| ID: mdl-38404165
ABSTRACT
"Improbable" rotaxanes consisting of interlocked conjugated components represent non-trivial synthetic targets, not to mention those with all-benzene scaffolds. Herein, a modular synthetic strategy has been established using an isolable azo-linked pre-rotaxane as the core module, in which the azo group functions as a tracelessly removable template to direct mechanical bond formations. Through versatile connections of the pre-rotaxane and other customizable modules, [2]- and [3]rotaxanes derived from all-benzene scaffolds have been accomplished, demonstrating the utility and potential of the synthetic design for all-benzene interlocked supramolecules.
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MEDLINE
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En
Ano de publicação:
2024
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Article