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Phosphine-Catalyzed 1,2-cis-Diboration of 1,3-Butadiynes.
Li, Weipeng; Ricker, Robert; Lok Chan, Ka; Fung Lau, Pak; Buchbinder, Nicklas W; Krebs, Johannes; Friedrich, Alexandra; Lin, Zhenyang; Santos, Webster L; Radius, Udo; Marder, Todd B.
Afiliação
  • Li W; School of Chemistry and Chemical Engineering, Nanjing University, Nanjing, 210023, China.
  • Ricker R; Institute of Inorganic Chemistry and Institute for Sustainable Chemistry & Catalysis with Boron, Julius-Maximilians-Universität Würzburg, Würzburg, 97074, Germany.
  • Lok Chan K; Institute of Inorganic Chemistry and Institute for Sustainable Chemistry & Catalysis with Boron, Julius-Maximilians-Universität Würzburg, Würzburg, 97074, Germany.
  • Fung Lau P; Department of Chemistry, The Hong Kong University of Science and Technology, Clear Water Bay, Kowloon, Hong Kong SAR, China.
  • Buchbinder NW; Department of Chemistry, The Hong Kong University of Science and Technology, Clear Water Bay, Kowloon, Hong Kong SAR, China.
  • Krebs J; Department of Chemistry Virginia Tech, Blacksburg, VA, 24061, USA.
  • Friedrich A; Institute of Inorganic Chemistry and Institute for Sustainable Chemistry & Catalysis with Boron, Julius-Maximilians-Universität Würzburg, Würzburg, 97074, Germany.
  • Lin Z; Institute of Inorganic Chemistry and Institute for Sustainable Chemistry & Catalysis with Boron, Julius-Maximilians-Universität Würzburg, Würzburg, 97074, Germany.
  • Santos WL; Department of Chemistry, The Hong Kong University of Science and Technology, Clear Water Bay, Kowloon, Hong Kong SAR, China.
  • Radius U; Department of Chemistry Virginia Tech, Blacksburg, VA, 24061, USA.
  • Marder TB; Institute of Inorganic Chemistry and Institute for Sustainable Chemistry & Catalysis with Boron, Julius-Maximilians-Universität Würzburg, Würzburg, 97074, Germany.
Chemistry ; 30(33): e202401235, 2024 Jun 12.
Article em En | MEDLINE | ID: mdl-38593362
ABSTRACT
Trialkyl phosphines PMe3 and PEt3 catalyze the 1,2-cis-diboration of 1,3-butadiynes to give 1,2-diboryl enynes. The products were utilized to synthesize 1,1,2,4-tetraaryl enynes using a Suzuki-Miyaura protocol and can readily undergo proto-deborylation.
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Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2024 Tipo de documento: Article
Texto completo
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Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2024 Tipo de documento: Article