Electrochemical nickel-catalyzed cross-coupling of glycosyl thiols with preactivated phenols and ketones.
Org Biomol Chem
; 22(18): 3597-3601, 2024 May 08.
Article
em En
| MEDLINE
| ID: mdl-38625707
ABSTRACT
An efficient electrochemical nickel-catalyzed cross-coupling reaction has been reported here for the synthesis of S-glycosides from preactivated phenols and ketones under mild conditions. Various glycosyl thiols, including unprotected sugar, and a diverse range of aryl/alkenyl triflates, including some complex biorelevant phenols and ketones, were well tolerated in this method.
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MEDLINE
Idioma:
En
Ano de publicação:
2024
Tipo de documento:
Article