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A calix[3]carbazole-based cavitand: synthesis, structure and its complexation with fullerenes.
Zhang, Fan; Du, Xu-Sheng; Song, Kui-Zhu; Han, Ying; Lu, Hai-Yan; Chen, Chuan-Feng.
Afiliação
  • Zhang F; University of Chinese Academy of Sciences, Beijing 100049, China. haiyanlu@ucas.ac.cn.
  • Du XS; Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Molecular Recognition and Function, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China. cchen@iccas.ac.cn.
  • Song KZ; Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Molecular Recognition and Function, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China. cchen@iccas.ac.cn.
  • Han Y; University of Chinese Academy of Sciences, Beijing 100049, China. haiyanlu@ucas.ac.cn.
  • Lu HY; Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Molecular Recognition and Function, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China. cchen@iccas.ac.cn.
  • Chen CF; University of Chinese Academy of Sciences, Beijing 100049, China. haiyanlu@ucas.ac.cn.
Chem Commun (Camb) ; 60(37): 4962-4965, 2024 May 02.
Article em En | MEDLINE | ID: mdl-38629394
ABSTRACT
A calix[3]carbazole-based cavitand was conveniently synthesized. It was found that the cavitand with adjustable conformation could show excellent complexation with fullerenes C60 and C70 in both solution and the solid state. Moreover, the crystal structures of the host-guest complexes show that the cavitand can stack into channel-like architectures, in which fullerenes are orderly arranged inside.

Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2024 Tipo de documento: Article

Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2024 Tipo de documento: Article