Manganese(I)-catalyzed nucleophilic addition of C(sp3)-H bonds to aldehydes.
Chem Commun (Camb)
; 60(38): 5066-5069, 2024 May 07.
Article
em En
| MEDLINE
| ID: mdl-38639013
ABSTRACT
The C-H bond activation catalyzed by a manganese(I) complex has achieved significant development but is limited to C(sp2)-H bonds. In this work, an efficient manganese(I)-catalyzed direct nucleophilic addition reaction of C(sp3)-H bonds to aromatic aldehydes has been developed. This is the first example of manganese(I)-catalyzed C(sp3)-H bond transformation. A manganacycle complex was isolated and proved to be the key active intermediate in the catalytic cycle.
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MEDLINE
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En
Ano de publicação:
2024
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Article