Iridium-Catalyzed Ortho-Selective C-H Borylation of Aryl Ketones with Transient Imine Ligands.
Org Lett
; 26(20): 4224-4228, 2024 May 24.
Article
em En
| MEDLINE
| ID: mdl-38726872
ABSTRACT
Ortho-selective C-H borylation of aromatic ketones has not been extensively explored. Herein, we report the iridium-catalyzed ortho-selective C-H borylation of aromatic ketones using in situ-formed imine as the ligand. Good compatibility is observed for various substituted acetophenones and other aromatic ketones, and corresponding products are obtained with medium to excellent yields.
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MEDLINE
Idioma:
En
Ano de publicação:
2024
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Article