Effect of "black carbon" on antimony accumulation in traffic-loaded topsoil.

ABSTRACT

Traffic-loaded areas have been of increasing concern due to the potential risk of carcinogenic pollutants, including antimony (Sb), which accumulates mostly in atmospheric particles (PM) and can interact with soil organic matter (Corg). The stability of Sb in topsoils was studied via the adsorption mechanism using standard soils and Corg-reach vehicle-produced particles as the unique source of "traffic" Sb. The mixed adsorbents were prepared from loamy sand and clay standard soils, and braking abrasion dust and diesel engine soot as Sb sources in atmospheric PM. Whereas the black carbon (BC), as part of Corg, disposes of exceptional adsorption properties compared to the other Corg, all adsorption experiments were performed identically on the adsorbents prepared from the original standard soils and Sb source materials and on the adsorbents prepared from the same materials annealed at 375 °C to ensure only BC participation in adsorption processes. The concentration of the Sb model solution corresponded to the average Sb content in rainwater from traffic-loaded localities. In addition to Sb, the Corg and iron (Fe) were monitored. The sorbability of Sb on the loamy sand soil mixtures increased up to 90% compared with the pure soil due to new active surface sites for Sb binding created due to the Corg added with the source material. The clay soil mixture containing 10 times more Corg compared with the loamy sand soil accumulated the Corg from the source material, which resulted in blocking active sites and a decline in Sb sorbability by up to 20%. The processes performed identically with original and annealed materials showed the same trends and confirmed the key role of BC and soil quality in the accumulation and stability of Sb in traffic-loaded topsoils. The participation of Fe in Sb surface interactions was not observed.