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Electronic interaction between dimethyl carbonate and Li+ studied by attenuated total reflectance far-ultraviolet spectroscopy.
Sato, Hitomi; Ueno, Nami; Tanabe, Ichiro.
Afiliação
  • Sato H; Department of Chemistry, College of Science, Rikkyo University, 3-34-1, Nishi-Ikebukuro, Toshima-ku, Tokyo 171-8501, Japan. itanabe@rikkyo.ac.jp.
  • Ueno N; Department of Chemistry, College of Science, Rikkyo University, 3-34-1, Nishi-Ikebukuro, Toshima-ku, Tokyo 171-8501, Japan. itanabe@rikkyo.ac.jp.
  • Tanabe I; Department of Chemistry, College of Science, Rikkyo University, 3-34-1, Nishi-Ikebukuro, Toshima-ku, Tokyo 171-8501, Japan. itanabe@rikkyo.ac.jp.
Chem Commun (Camb) ; 60(50): 6375-6378, 2024 Jun 18.
Article em En | MEDLINE | ID: mdl-38808541
ABSTRACT
Organic electrolytes with Li+ were analyzed by far-ultraviolet (≤200 nm) spectroscopy, achieved by an attenuated total reflectance setup. The spectra showed a redshift with Li+ addition, attributed to the charge transfer, as revealed by quantum chemical calculations. Multivariate analysis successfully decomposed the spectra into pure solvent and Li-coordinated solvent components.
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Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2024 Tipo de documento: Article
Texto completo
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Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2024 Tipo de documento: Article