Metal-Mediated Synthesis of a Mixed Arduengo-Fischer Carbodicarbene Ligand.
Angew Chem Int Ed Engl
; : e202407945, 2024 Jun 10.
Article
em En
| MEDLINE
| ID: mdl-38856098
ABSTRACT
Carbodicarbenes are strong C-donor ligands, which have found numerous applications in organometallic and main group element chemistry. Herein, we report a structurally distinct carbodicarbene ligand, which is formed by dinitrogenative coupling of a Fischer carbene complex with an N-heterocyclic diazoolefin. The resulting carbonyl complex serves as a stable source for the mixed Arduengo-Fischer carbodicarbene ligand. Facile ligand transfer reactions were demonstrated to occur with gold(I), copper(I), palladium(II), and rhodium(I) complexes.
Texto completo:
1
Base de dados:
MEDLINE
Idioma:
En
Ano de publicação:
2024
Tipo de documento:
Article