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Synthetic applications of the Cannizzaro reaction.
Chatterjee, Bhaskar; Mondal, Dhananjoy; Bera, Smritilekha.
Afiliação
  • Chatterjee B; Department of Chemistry, Nabadwip Vidyasagar College, West Bengal, India.
  • Mondal D; School of Chemical Sciences, Central University of Gujarat, Gandhinagar-382030, India.
  • Bera S; School of Chemical Sciences, Central University of Gujarat, Gandhinagar-382030, India.
Beilstein J Org Chem ; 20: 1376-1395, 2024.
Article em En | MEDLINE | ID: mdl-38919603
ABSTRACT
The Cannizzaro reaction has emerged as a versatile synthetic tool for the construction of functionalized molecules. Dating back to the 19th century, this reaction, though initially used for the synthesis of an alcohol and acid functionality from aldehydes, has henceforth proven useful to generate diverse molecular entities using both intermolecular and intramolecular synthetic strategies. Immense applications in the synthesis of hydroxy acids and esters, heterocycles, fused carbocycles, natural products, and others with broad substrate scope have raised profound interest from methodological and synthetic standpoints. The ongoing development of reagents, solvents, and technologies for the Cannizzaro reaction reflects the broader trend in organic synthesis towards more sustainable and efficient practices. The focus of this review is to highlight some recent advances in synthetic strategies and applications of the Cannizzaro reaction towards the synthesis of potentially useful molecules.
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Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2024 Tipo de documento: Article

Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2024 Tipo de documento: Article