Preparing Coordination Polymers with Acentric-Centric Structural Arrangements Related to SHG Response.
Inorg Chem
; 63(27): 12651-12657, 2024 Jul 08.
Article
em En
| MEDLINE
| ID: mdl-38922623
ABSTRACT
Three coordination polymers were successfully constructed in this work by applying biligands and were distinctly characterized through single crystal X-ray diffraction. The compounds crystallized in acentric and centric space groups under the direction of coordination bonds and adopted 1-dimensional link and 2-dimensional layer structures, as well as different coordination geometries for metal atoms. All compounds exhibited good thermal stability and luminescence properties, and compound 2 exhibited a good second harmonic generation (SHG) response. The method used in this work offers a feasible approach to using biligand and changing metal salt to obtain the microstructures of coordination materials with specific properties.
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MEDLINE
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En
Ano de publicação:
2024
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Article