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Interfacial Membranization of Regenerated Cellulose Nanoparticles and a Protein Renders Stable Water-in-Water Emulsion.
Zhu, Ya; Beaumont, Marco; Solin, Katariina; Spiliopoulos, Panagiotis; Zhao, Bin; Tao, Han; Kontturi, Eero; Bai, Long; Rojas, Orlando J.
Afiliação
  • Zhu Y; Department of Bioproducts and Biosystems, School of Chemical Engineering, Aalto University, P.O. Box 16300, FIN-00076 Aalto, Espoo, Finland.
  • Beaumont M; Department of Chemistry, Institute of Chemistry of Renewable Resources, University of Natural Resources and Life Sciences (BOKU), Konrad-Lorenz-Str. 24, Tulln, A-3430, Austria.
  • Solin K; Department of Bioproducts and Biosystems, School of Chemical Engineering, Aalto University, P.O. Box 16300, FIN-00076 Aalto, Espoo, Finland.
  • Spiliopoulos P; Department of Bioproducts and Biosystems, School of Chemical Engineering, Aalto University, P.O. Box 16300, FIN-00076 Aalto, Espoo, Finland.
  • Zhao B; Department of Bioproducts and Biosystems, School of Chemical Engineering, Aalto University, P.O. Box 16300, FIN-00076 Aalto, Espoo, Finland.
  • Tao H; Department of Bioproducts and Biosystems, School of Chemical Engineering, Aalto University, P.O. Box 16300, FIN-00076 Aalto, Espoo, Finland.
  • Kontturi E; Department of Bioproducts and Biosystems, School of Chemical Engineering, Aalto University, P.O. Box 16300, FIN-00076 Aalto, Espoo, Finland.
  • Bai L; Key Laboratory of Biobased Material Science and Technology (Ministry of Education), Northeast Forestry University, Harbin, Heilongjiang, 150040, P. R. China.
  • Rojas OJ; Department of Bioproducts and Biosystems, School of Chemical Engineering, Aalto University, P.O. Box 16300, FIN-00076 Aalto, Espoo, Finland.
Small ; : e2400952, 2024 Jul 16.
Article em En | MEDLINE | ID: mdl-39011941
ABSTRACT
Pickering water-in-water (W/W) emulsions stabilized by biobased colloids are pertinent to engineering biomaterials with hierarchical and confined architectures. In this study, stable W/W emulsions are developed through membranization utilizing biopolymer structures formed by the adsorption of cellulose II nanospheres and a globular protein, bovine serum albumin (BSA), at droplet surfaces. The produced cellulose II nanospheres (NPcat, 63 nm diameter) bearing a soft and highly accessible shell, endow rapid and significant binding (16 mg cm- 2) with BSA. NPcat and BSA formed complexes that spontaneously stabilized liquid droplets, resulting in stable W/W emulsions. It is proposed that such a system is a versatile all-aqueous platform for encapsulation, (bio)catalysis, delivery, and synthetic cell mimetics.
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Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2024 Tipo de documento: Article

Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2024 Tipo de documento: Article