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Organophotocatalytic access to C-glycosides: multicomponent coupling reactions using glycosyl bromides.
Sawada, Naoya; Yu, Ziyi; Takinami, Hiryu; Inoue, Daichi; Ghosh, Titli; Sasaki, Norihiko; Nokami, Toshiki; Taniguchi, Tsuyoshi; Abe, Manabu; Koike, Takashi.
Afiliação
  • Sawada N; Department of Chemistry and Biotechnology, Tottori University, 4-101 Koyamacho minami, Tottori city, 680-8552 Tottori, Japan.
  • Yu Z; Department of Chemistry and Biotechnology, Tottori University, 4-101 Koyamacho minami, Tottori city, 680-8552 Tottori, Japan.
  • Takinami H; Department of Chemistry and Biotechnology, Tottori University, 4-101 Koyamacho minami, Tottori city, 680-8552 Tottori, Japan.
  • Inoue D; Department of Chemistry and Biotechnology, Tottori University, 4-101 Koyamacho minami, Tottori city, 680-8552 Tottori, Japan.
  • Ghosh T; Department of Chemistry and Biotechnology, Tottori University, 4-101 Koyamacho minami, Tottori city, 680-8552 Tottori, Japan.
  • Sasaki N; Department of Chemistry and Biotechnology, Tottori University, 4-101 Koyamacho minami, Tottori city, 680-8552 Tottori, Japan.
  • Nokami T; Centre for Research on Green Sustainable Chemistry, Faculty of Engineering, Tottori University, 4-101 Koyamacho minami, Tottori city, 680-8552 Tottori, Japan.
  • Taniguchi T; Department of Chemistry and Biotechnology, Tottori University, 4-101 Koyamacho minami, Tottori city, 680-8552 Tottori, Japan.
  • Abe M; Centre for Research on Green Sustainable Chemistry, Faculty of Engineering, Tottori University, 4-101 Koyamacho minami, Tottori city, 680-8552 Tottori, Japan.
  • Koike T; Interdisciplinary Research Center for Catalytic Chemistry, National Institute of Advanced Industrial Science and Technology, 1-1-1 Higashi, Tsukuba city, Ibaraki, 305-8565, Japan.
Chem Commun (Camb) ; 60(66): 8684-8687, 2024 Aug 13.
Article em En | MEDLINE | ID: mdl-39034774
ABSTRACT
Photochemical multi-component coupling reactions initiated by the activation of glycosyl bromides in the presence of 1,4-bis(diphenylamino)benzene (BDB) as an organic photocatalyst were developed. C-glycosides accompanied by olefin (di)functionalization were obtained. This method allows us to access various C-glycosides with alkene, carbonyl, alcohol, ether, and amide functionalities.
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Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2024 Tipo de documento: Article
Texto completo
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XML
PubMed Links
Buscar no Google

Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2024 Tipo de documento: Article