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Synthesis and Optoelectronic Properties of Threaded BODIPYs.
Hicguet, Matthieu; Mongin, Olivier; Leroux, Yann R; Roisnel, Thierry; Berrée, Fabienne; Trolez, Yann.
Afiliação
  • Hicguet M; ISCR - UMR6226, École Nationale Supérieure de Chimie de Rennes, CNRS, ISCR - UMR6226, Univ Rennes, F-35000, Rennes, France.
  • Mongin O; ISCR - UMR6226, École Nationale Supérieure de Chimie de Rennes, CNRS, ISCR - UMR6226, Univ Rennes, F-35000, Rennes, France.
  • Leroux YR; ISCR - UMR6226, École Nationale Supérieure de Chimie de Rennes, CNRS, ISCR - UMR6226, Univ Rennes, F-35000, Rennes, France.
  • Roisnel T; ISCR - UMR6226, École Nationale Supérieure de Chimie de Rennes, CNRS, ISCR - UMR6226, Univ Rennes, F-35000, Rennes, France.
  • Berrée F; ISCR - UMR6226, École Nationale Supérieure de Chimie de Rennes, CNRS, ISCR - UMR6226, Univ Rennes, F-35000, Rennes, France.
  • Trolez Y; ISCR - UMR6226, École Nationale Supérieure de Chimie de Rennes, CNRS, ISCR - UMR6226, Univ Rennes, F-35000, Rennes, France.
ChemistryOpen ; : e202400196, 2024 Jul 23.
Article em En | MEDLINE | ID: mdl-39041684
ABSTRACT
We report on the synthesis of two new threaded BODIPYs 5 and 6 in good yields using boron as a gathering atom and a macrocycle with a 2,2'-biphenol unit. In addition to usual techniques, they were characterized by X-ray crystallography. Their electrochemical and optical properties were investigated. In particular, both compounds are highly emissive with photoluminescence quantum yields of 54 and 81 % respectively. In addition, they both show a high photostability.
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Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2024 Tipo de documento: Article
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Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2024 Tipo de documento: Article