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Spectroscopic characterization and reactivity studies of a copper(II) iminoxyl radical complex.
Kaur, Simarjeet; Das, Avijit; Velasco, Lucia; Sauvan, Maxime; Bera, Moumita; Ugale, Ashok; Charisiadis, Asterios; Moonshiram, Dooshaye; Paria, Sayantan.
Afiliação
  • Kaur S; Department of Chemistry, Indian Institute of Technology Delhi, Hauz Khas, New Delhi, 110016, India. sparia@chemistry.iitd.ac.in.
  • Das A; Department of Chemistry, Indian Institute of Technology Delhi, Hauz Khas, New Delhi, 110016, India. sparia@chemistry.iitd.ac.in.
  • Velasco L; Instituto de Ciencia de Materiales de Madrid, Consejo Superior de Investigaciones Científicas, Sor Juana Inés de la Cruz, 3, 28049, Madrid, Spain. dooshaye.moonshiram@csic.es.
  • Sauvan M; Instituto de Ciencia de Materiales de Madrid, Consejo Superior de Investigaciones Científicas, Sor Juana Inés de la Cruz, 3, 28049, Madrid, Spain. dooshaye.moonshiram@csic.es.
  • Bera M; Department of Chemistry, Indian Institute of Technology Delhi, Hauz Khas, New Delhi, 110016, India. sparia@chemistry.iitd.ac.in.
  • Ugale A; Instituto de Ciencia de Materiales de Madrid, Consejo Superior de Investigaciones Científicas, Sor Juana Inés de la Cruz, 3, 28049, Madrid, Spain. dooshaye.moonshiram@csic.es.
  • Charisiadis A; Instituto de Ciencia de Materiales de Madrid, Consejo Superior de Investigaciones Científicas, Sor Juana Inés de la Cruz, 3, 28049, Madrid, Spain. dooshaye.moonshiram@csic.es.
  • Moonshiram D; Instituto de Ciencia de Materiales de Madrid, Consejo Superior de Investigaciones Científicas, Sor Juana Inés de la Cruz, 3, 28049, Madrid, Spain. dooshaye.moonshiram@csic.es.
  • Paria S; Department of Chemistry, Indian Institute of Technology Delhi, Hauz Khas, New Delhi, 110016, India. sparia@chemistry.iitd.ac.in.
Chem Commun (Camb) ; 60(73): 9934-9937, 2024 Sep 10.
Article em En | MEDLINE | ID: mdl-39072688
ABSTRACT
A CuII complex (1) of a bis-pyridine-dioxime ligand and its one-electron oxidized analog (1-ox) were thoroughly characterized by various spectroscopic techniques, including X-ray absorption spectroscopy. 1-ox was found to be a CuII complex of a ligand iminoxyl radical and represents the first example of such a type. Reorganization energy (λ) of 2.12 eV was determined for the 1-ox/1 couple, which is considerably higher than the type 1 protein and synthetic CuIII/II(OH) complexes.
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Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2024 Tipo de documento: Article
Texto completo
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Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2024 Tipo de documento: Article