InCl3 catalyzed simultaneous reductive sulfoximination and O-silylation: synthesis of silyloxy benzylsulfoximine.
Org Biomol Chem
; 22(33): 6699-6702, 2024 Aug 22.
Article
em En
| MEDLINE
| ID: mdl-39109548
ABSTRACT
This article describes the synthesis of ortho-silyloxy benzylsulfoximine via the reaction of salicylaldehyde and sulfoximine in the presence of silane and InCl3. The steps include simultaneous reductive sulfoximination and an O-silylation process. To the best of our knowledge, this is the first report of this kind of reaction, where both reductive amination (here sulfoximination) and O-silylation occur concurrently.
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MEDLINE
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En
Ano de publicação:
2024
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Article