Viologen-Derived Covalent Organic Frameworks: Advancing PFAS Removal Technology with High Adsorption Capacity.
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; : e2405176, 2024 Aug 08.
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| MEDLINE
| ID: mdl-39115339
ABSTRACT
The escalating presence of per- and polyfluoroalkyl substances (PFAS) in drinking water poses urgent public health concerns, necessitating effective removal. This study presents a groundbreaking approach, using viologen to synthesize covalent organic framework nanospheres MELEM-COF and MEL-COF. Characterized by highly crystalline features, these nanospheres exhibit exceptional affinity for diverse anionic PFAS compounds, achieving simultaneous removal of multiple contaminants within 30 min. Investigating six anionic PFAS compounds, MEL- and MELEM-COFs achieved 90.0-99.0% removal efficiency. The integrated analysis unveils the synergistic contributions of COF morphology and functional properties to PFAS adsorption. Notably, MELEM-COF, with cationic surfaces, exploits electrostatic and dipole interactions, with a 2500 mg g-1 adsorption capacity-surpassing all reported COFs to date. MELEM-COF exhibits rapid exchange kinetics, reaching equilibrium within 30 min. These findings deepen the understanding of COF materials and promise avenues for refining COF-based adsorption strategies.
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MEDLINE
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En
Ano de publicação:
2024
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Article