Soft chemistry-derived Al-substituted hydrated nickel hydroxide electrodes for rechargeable aqueous batteries.

ABSTRACT

Hydrated nickel hydroxides with partial aluminum substitution were synthesized using the conventional coprecipitation and soft chemistry methods. The soft chemistry derived sample showed better reversibility owing to the low activity for oxygen evolution during charging. Operando X-ray diffraction indicated the increased interlayer distance and decreased crystallinity during discharging caused by water accommodation.