Adamantylidene Addition to M3 N@Ih -C80 (M=Sc, Lu) and Sc3 N@D5h -C80 : Synthesis and Crystallographic Characterization of the [5,6]-Open and [6,6]-Open Adducts.

Additions of adamantylidene (Ad) to M3 N@Ih -C80 (M=Sc, Lu) and Sc3 N@D5h -C80 have been accomplished by photochemical reactions with 2-adamantyl-2,3'-[3H]-diazirine (1). In M3 N@Ih -C80 , the addition led to rupture of the [6,6]- or [5,6]-bonds of the Ih -C80 cage, forming the [6,6]-open fulleroid as the major isomer and the [5,6]-open fulleroid as the minor isomer. In Sc3 N@D5h -C80 , the addition also proceeded regioselectively to yield three major isomeric Ad mono-adducts, despite the fact that there are nine types of C-C bonds in the D5h -C80 cage. The molecular structures of the seven Ad mono-adducts, including the positions of the encaged trimetallic nitride clusters, have been unambiguously determined through single-crystal XRD analyses. Furthermore, results have shown that stepwise addition of Ad to Lu3 N@Ih -C80 affords several Ad bis-adducts, two of which have been isolated and characterized. The X-ray structure of one bis-adduct clearly revealed that the second Ad addition took place at a [6,6]-bond close to an endohedral metal atom. Theoretical calculations have also been performed to rationalize the regioselectivity.

D2d(23)-C84 versus Sc2C2@D2d(23)-C84: Impact of Endohedral Sc2C2 Doping on Chemical Reactivity in the Photolysis of Diazirine.

We compared the chemical reactivity of D2d(23)-C84 and that of Sc2C2@D2d(23)-C84, both having the same carbon cage geometry, in the photolysis of 2-adamantane-2,3'-[3H]-diazirine, to clarify metal-atom doping effects on the chemical reactivity of the carbon cage. Experimental and computational studies have revealed that the chemical reactivity of the D2d(23)-C84 carbon cage is altered drastically by endohedral Sc2C2 doping. The reaction of empty D2d(23)-C84 with the diazirine under photoirradiation yields two adamantylidene (Ad) adducts. NMR spectroscopic studies revealed that the major Ad monoadduct (C84(Ad)-A) has a fulleroid structure and that the minor Ad monoadduct (C84(Ad)-B) has a methanofullerene structure. The latter was also characterized using X-ray crystallography. C84(Ad)-A is stable under photoirradiation, but it interconverted to C84(Ad)-B by heating at 80 °C. In contrast, the reaction of endohedral Sc2C2@D2d(23)-C84 with diazirine under photoirradiation affords four Ad monoadducts (Sc2C2@C84(Ad)-A, Sc2C2@C84(Ad)-B, Sc2C2@C84(Ad)-C, and Sc2C2@C84(Ad)-D). The structure of Sc2C2@C84(Ad)-C was characterized using X-ray crystallography. Thermal interconversion of Sc2C2@C84(Ad)-A and Sc2C2@C84(Ad)-B to Sc2C2@C84(Ad)-C was also observed. The reaction mechanisms of the Ad addition and thermal interconversion were elucidated from theoretical calculations. Calculation results suggest that C84(Ad)-B and Sc2C2@C84(Ad)-C are thermodynamically favorable products. Their different chemical reactivities derive from Sc2C2 doping, which raises the HOMO and LUMO levels of the D2d(23)-C84 carbon cage.

[The effects of security camera, past littering, environment, and signboards on littering prevention].

Two experiments were conducted to assess litter control at a riverside location. Experiment 1 examined the effects of a security camera (presence/absence), past littering (presence/absence), and environmental features (tussock/plain ground/flowerbed). Two scenes containing combinations of these factors were presented. Participants chose the scene in which they felt it was to easier to litter. Participants also reported their emotional response to the presence/absence of a security camera and environmental features in scenes with litter. The results revealed that the presence of a security camera, no past littering, flowerbeds, and plain ground inhibited littering. Littering in the presence of a security camera facilitated discomfort, anger, and shame, and littering in flowerbeds caused discomfort, anger, shame, and sadness. Using a similar method, Experiment 2 addressed the particular effects of a security camera combined with other factors: past littering, environmental features, and signboards (no sign/sign with eyes/security camera images). The results demonstrated the effectiveness of a security camera, no past littering, flowerbeds, plain ground, signboards presenting eyes, and images from a security camera in preventing littering.

[Development of the Emotion and Arousal Checklist (EACL)].

We developed the 33-item Emotion and Arousal Checklist (EACL), which consisted of five subscales to assess emotions (Fear, Anger, Sadness, Disgust, and Happiness) and four subscales to assess arousal (Energetic arousal + Energetic arousal -, Tense arousal+, and Tense arousal -). This checklist was developed to assess psychological state, both at a given moment and during the past week. In Study 1, confirmatory factor analyses identified nine subscales, whose internal consistency was indicated by their reliability. In Study 2, the EACL's validity was demonstrated by its correlation with the State-Trait Anxiety Inventory, Multiple Mood Scale, General Arousal Checklist, Japanese UWIST Mood Adjective Checklist, and Profile of Mood States. In Study 3, changes caused by tasks that involved either reading emotion-inducing articles or performing a calculation indicated the validity of the EACL for measuring psychological state at a given moment. Further, the test-retest reliability of the EACL for assessing psychological state during the past week was confirmed. These studies confirmed the reliability and the validity of the EACL.

Belief in a Just World Decreases Blame for Celebrity Infidelity.

Justice motivation has been considered one cause of celebrity infidelity scandals becoming flaming incidents. Nevertheless, few studies have examined how the belief in a just world (BJW), one motivation for justice, affects people's attitudes toward these incidents. This study was conducted to identify the relations among BJW, negative emotions toward infidelity (NE), and celebrity infidelity blaming (CIB). Data were collected from 1186 Japanese adults (mean age = 44.9 years, SD = 13.8; 49.4% male). The results of structural equation modeling revealed that NE positively relates to CIB and plays a mediating role between BJW and CIB. However, BJW neither facilitates NE nor positively predicts CIB; on the contrary, it suppresses both NE and CIB. The findings indicate that BJW decreases people's blame on celebrity infidelity and suggest future directions for mitigating the issues posed by casting blame on celebrities' cheating scandals.

[Olfactory influences on the perceived effects of lip balm].

This study examined the influence of olfactory impressions on the perceived effects of lip balm. Twenty female college students used two types of lip balm: one with natural essences (lemon or vanilla) and one without. Then they rated their perceived experience of the balms. The results showed that the participants felt that the balm with lemon essence was significantly smoother than the ones with vanilla or without natural essences. Furthermore, the participants felt that the balm with vanilla essence was significantly stickier than the ones with lemon or without natural essences. Also, the participants felt that the balm with lemon essence had marginally better moisturizing properties than the one with vanilla. These results suggest that olfactory cognition influences the perception of tactile sensations.

A multifactorial framework of psychobehavioral determinants of coping behaviors: an online survey at the early stage of the COVID-19 pandemic.

Coronavirus disease 2019 dramatically changed people's behavior because of the need to adhere to infection prevention and to overcome general adversity resulting from the implementation of infection prevention measures. However, coping behavior has not been fully distinguished from risk perception, and a comprehensive picture of demographic, risk-perception, and psychobehavioral factors that influence the major coping-behavior factors remain to be elucidated. In this study, we recruited 2,885 Japanese participants. Major coping-behavior and risk-perception factors were identified via exploratory factor analysis of 50 candidate items. Then, we conducted a hierarchical multiple regression analysis to investigate factors associated with each coping-behavior factor. We identified four types of coping behavior [CB1 (mask-wearing), CB2 (information-seeking), CB3 (resistance to social stagnation), and CB4 (infection-prevention)] and three risk-perception factors [RP1 (shortages of daily necessities), RP2 (medical concerns), and RP3 (socioeconomic concerns)]. CB1 was positively associated with female sex and etiquette. CB2 was positively related to RP1 and RP3. CB3 was positively related to RP1 and leadership, and negatively associated with etiquette. CB4 was positively associated with female sex, etiquette, and active well-being. This parsimonious model may help to elucidate essential social dynamics and provide a theoretical framework for coping behavior during a pandemic.

Does the eight-factor "power to live" in disaster exist since childhood?

Background: Studies on the survivors of the 2011 Great East Japan earthquake and tsunami have revealed eight factors, called power to live, which are closely related to resilience and effective coping after intense and prolonged stress. However, whether the eight factors, which were examined in adults, are applicable to children is unclear. The purpose of this study is to evaluate whether the eight-factor structure of power to live was present since late childhood. Method: A 34-item power to live questionnaire was filled by middle- to upper-grade elementary (n = 378) and junior high school students (n = 456). Moreover, because elementary school students may lack introspective ability, their power to live was evaluated through a parental assessment (n = 358). Additionally, we examined the relationship between each power to live factor and questions regarding disaster prevention awareness among 25 elementary school students. Results: The results from confirmatory factor analysis for factor structure revealed generally acceptable fit indices. The reports from elementary school students and their parents significantly positively correlated with each power to live factor. Although reliability indices for factors such as stubbornness, etiquette, self-transcendence, and active well-being were not good for elementary school students, the reliability indices for all factors, excluding stubbornness, increased in junior high school students. Moreover, we identified a correlation between problem-solving, altruism, and emotional regulation and questionnaire items regarding awareness of disaster prevention in elementary school students. Conclusion: Our results suggest that although factors common to adults, such as leadership, problem-solving, altruism, and emotional regulation, were identified at the elementary school stage, some factors, such as stubbornness, are in the process of being formed. Future studies should examine the developmental changes assumed to underlie these factors and their relationship to experience and neurodevelopmental basis.

Self-help and mutual assistance in the aftermath of a tsunami: How individual factors contribute to resolving difficulties.

Self-aid and mutual assistance among victims are critical for resolving difficulties in the immediate aftermath of a disaster, but individual facilitative factors for such resolution processes are poorly understood. To identify such individual factors in the background (i.e., disaster damage and demographic) and personality domains considering different types of difficulty and resolution, we analyzed survey data collected in the 3-year aftermath of the 2011 Great East Japan Earthquake and Tsunami. We first identified major types of difficulty using a cluster analysis of 18 difficulty domains and then explored individual factors that facilitated six types of resolution (self-help, request for help, help from family, help from an acquaintance, help through cooperation, and public assistance) of these difficulty types. We identified general life difficulties and medico-psychological difficulties as two broad types of difficulty; disaster damage contributed to both types, while some personality factors (e.g., neuroticism) exacerbated the latter. Disaster damage hampered self-resolution and forced a reliance on resolution through cooperation or public assistance. On the other hand, some demographic factors, such as being young and living in a three-generation household, facilitated resolution thorough the family. Several personality factors facilitated different types of resolution, primarily of general life difficulties; the problem-solving factor facilitated self-resolution, altruism, or stubbornness resolutions through requests, leadership resolution through acquaintance, and emotion-regulation resolution through public assistance. Our findings are the first to demonstrate the involvement of different individual, particularly personality, factors in survival in the complex social dynamics of this disaster stage. They may contribute to disaster risk mitigation, allowing sophisticated risk evaluation and community resilience building.

Survival-oriented personality factors are associated with various types of social support in an emergency disaster situation.

Mutual help is common in human society, particularly during a disaster. The psychological processes underlying such social support are of interest in social and evolutionary psychology, as well as in the promotion of community resilience. However, research in terms of personality factors or support types is sporadic and has yet to address actual emergency situations. In this study, we analyzed survey data from survivors of the 2011 Tohoku earthquake and tsunami. The data included five types of social support occurring during the evacuation from a potential tsunami area: providing and receiving actual help and oral encouragement, as well as perceived support. The personality factor items included the Big Five dimensions and eight "power to live" factors, which were identified as advantageous for survival during this disaster. While none of the Big Five dimensions were associated with social support, six of the power to live factors were. Altruism, problem solving, etiquette, and self-transcendence contributed to the provision of actual help. Leadership and active well-being contributed to oral encouragement with the latter contributing also to perceived support. The findings were largely consistent with the literature in a non-emergency context. The relevance of the majority of these pro-survival personality factors to social support appeared to support the view that the propensity to cooperate in service of human survival in a disaster situation is primarily a social, rather than an individual, phenomenon, and encourages research on the mechanisms underlying how personality factors provide a benefit to both the individual and their community.

Eight Personal Characteristics Associated with the Power to Live with Disasters as Indicated by Survivors of the 2011 Great East Japan Earthquake Disaster.

People perceive, judge, and behave differently in disasters and in a wide range of other difficult situations depending on their personal characteristics. The power to live, as captured by characteristics that are advantageous for survival in such situations, has thus far been modeled in arbitrary ways. Conceptualizing such characteristics in more objective ways may be helpful for systematic preparations for future disasters and life difficulties. Here, we attempted to identify the major factors of the power to live by summarizing the opinions of survivors of the 2011 Great East Japan Earthquake disaster. We conducted personal interviews with 78 survivors about their survival experiences and elicited their opinions about the power to live as relevant to those experiences. We then incorporated these opinions into a questionnaire that was completed by 1400 survivors. Factor analysis identified eight factors related to the power to live: leadership, problem solving, altruism, stubbornness, etiquette, emotional regulation, self-transcendence, and active well-being. All factors had sufficient internal construct validity, and six of them showed significant associations with one or more measures of survival success in the disaster, including immediate tsunami evacuation, problem solving in refugee situations, recovery during reconstruction, physical health, and mental health. Overall, the personal characteristics described by the eight factors largely overlap with those described in previous arbitrary models. Further research should investigate the domains, phases, and contexts in which each factor contributes to survival, address whether the factors are rooted in nature or in nurture, and explore their psychological or physiological bases.