Superconductivity and spin-orbit coupling in non-centrosymmetric materials: a review.

In non-centrosymmetric superconductors, where the crystal structure lacks a centre of inversion, parity is no longer a good quantum number and an electronic antisymmetric spin-orbit coupling (ASOC) is allowed to exist by symmetry. If this ASOC is sufficiently large, it has profound consequences on the superconducting state. For example, it generally leads to a superconducting pairing state which is a mixture of spin-singlet and spin-triplet components. The possibility of such novel pairing states, as well as the potential for observing a variety of unusual behaviors, led to intensive theoretical and experimental investigations. Here we review the experimental and theoretical results for superconducting systems lacking inversion symmetry. Firstly we give a conceptual overview of the key theoretical results. We then review the experimental properties of both strongly and weakly correlated bulk materials, as well as two dimensional systems. Here the focus is on evaluating the effects of ASOC on the superconducting properties and the extent to which there is evidence for singlet-triplet mixing. This is followed by a more detailed overview of theoretical aspects of non-centrosymmetric superconductivity. This includes the effects of the ASOC on the pairing symmetry and the superconducting magnetic response, magneto-electric effects, superconducting finite momentum pairing states, and the potential for non-centrosymmetric superconductors to display topological superconductivity.

Bogoliubov Fermi Surfaces in Superconductors with Broken Time-Reversal Symmetry.

It is commonly believed that, in the absence of disorder or an external magnetic field, there are three possible types of superconducting excitation gaps: The gap is nodeless, it has point nodes, or it has line nodes. Here, we show that, for an even-parity nodal superconducting state which spontaneously breaks time-reversal symmetry, the low-energy excitation spectrum generally does not belong to any of these categories; instead, it has extended Bogoliubov Fermi surfaces. These Fermi surfaces can be visualized as two-dimensional surfaces generated by "inflating" point or line nodes into spheroids or tori, respectively. These inflated nodes are topologically protected from being gapped by a Z_{2} invariant, which we give in terms of a Pfaffian. We also show that superconducting states possessing these Fermi surfaces can be energetically stable. A crucial ingredient in our theory is that more than one band is involved in the pairing; since all candidate materials for even-parity superconductivity with broken time-reversal symmetry are multiband systems, we expect these Z_{2}-protected Fermi surfaces to be ubiquitous.

Resilient Nodeless d-Wave Superconductivity in Monolayer FeSe.

Monolayer FeSe exhibits the highest transition temperature among the iron based superconductors and appears to be fully gapped, seemingly consistent with s-wave superconductivity. Here, we develop a theory for the superconductivity based on coupling to fluctuations of checkerboard magnetic order (which has the same translation symmetry as the lattice). The electronic states are described by a symmetry based k·p-like theory and naturally account for the states observed by angle resolved photoemission spectroscopy. We show that a prediction of this theory is that the resultant superconducting state is a fully gapped, nodeless, d-wave state. This state, which would usually have nodes, stays nodeless because, as seen experimentally, the relevant spin-orbit coupling has an energy scale smaller than the superconducting gap.

Pairing of j=3/2 Fermions in Half-Heusler Superconductors.

We theoretically consider the superconductivity of the topological half-Heusler semimetals YPtBi and LuPtBi. We show that pairing occurs between j=3/2 fermion states, which leads to qualitative differences from the conventional theory of pairing between j=1/2 states. In particular, this permits Cooper pairs with quintet or septet total angular momentum, in addition to the usual singlet and triplet states. Purely on-site interactions can generate s-wave quintet time-reversal symmetry-breaking states with topologically nontrivial point or line nodes. These local s-wave quintet pairs reveal themselves as d-wave states in momentum space. Furthermore, due to the broken inversion symmetry in these materials, the s-wave singlet state can mix with a p-wave septet state, again with topologically stable line nodes. Our analysis lays the foundation for understanding the unconventional superconductivity of the half-Heuslers.

Multicomponent superconducting order parameter in UTe2.

An unconventional superconducting state was recently discovered in uranium ditelluride (UTe2), in which spin-triplet superconductivity emerges from the paramagnetic normal state of a heavy-fermion material. The coexistence of magnetic fluctuations and superconductivity, together with the crystal structure of this material, suggests that a distinctive set of symmetries, magnetic properties, and topology underlie the superconducting state. Here, we report observations of a nonzero polar Kerr effect and of two transitions in the specific heat upon entering the superconducting state, which together suggest that the superconductivity in UTe2 is characterized by a two-component order parameter that breaks time-reversal symmetry. These data place constraints on the symmetries of the order parameter and inform the discussion on the presence of topological superconductivity in UTe2.

Field-induced transition within the superconducting state of CeRh2As2.

Materials with multiple superconducting phases are rare. Here, we report the discovery of two-phase unconventional superconductivity in CeRh2As2 Using thermodynamic probes, we establish that the superconducting critical field of its high-field phase is as high as 14 tesla, even though the transition temperature is only 0.26 kelvin. Furthermore, a transition between two different superconducting phases is observed in a c axis magnetic field. Local inversion-symmetry breaking at the cerium sites enables Rashba spin-orbit coupling alternating between the cerium sublayers. The staggered Rashba coupling introduces a layer degree of freedom to which the field-induced transition and high critical field seen in experiment are likely related.

Order parameter and vortices in the superconducting Q phase of CeCoIn5.

Recently, it has been reported that the low-temperature high-magnetic field superconducting phase in CeCoIn(5) (Q phase), has spin-density wave (SDW) order that only exists within this phase. This indicates that the SDW order is the result of the development of pair density wave (PDW) order in the superconducting phase that coexists with d-wave superconductivity. Here we develop a phenomenological theory for these coexisting orders. This provides selection rules for the PDW order and further shows that the detailed structure of this order is highly constrained. We then apply our theory to the vortex phase. This reveals vortex phases in which the d-wave vortex cores exhibit charge density wave order and further reveals that the SDW order provides detailed information about the vortex phase.

Spatial line nodes and fractional vortex pairs in the Fulde-Ferrell-Larkin-Ovchinnikov vortex state of spin-singlet superconductors.

A Zeeman magnetic field can induce a Fulde-Ferrell-Larkin-Ovchinnikov (FFLO) phase in spin-singlet superconductors. Here we argue that there is a nontrivial solution for the FFLO vortex phase that exists near the upper critical field in which the wave function has only spatial line nodes that form intricate and unusual three-dimensional structures. These structures include a crisscrossing lattice of two sets of nonparallel line nodes. We show that these solutions arise from the decay of conventional Abrikosov vortices into pairs of fractional vortices. We propose that neutron scattering studies can observe these fractional vortex pairs through the observation of a lattice of 1/2 flux quanta vortices. We also consider related phases in noncentrosymmetric superconductors.

S-wave spin-triplet order in superconductors without inversion symmetry: Li2Pd3B and Li2Pt3B.

We investigate the order parameter of noncentrosymmetric superconductors Li2Pd3B and Li2Pt3B via the behavior of the penetration depth lambda(T). The low-temperature penetration depth shows BCS-like behavior in Li2Pd3B, while in Li2Pt3B it follows a linear temperature dependence. We propose that broken inversion symmetry and the accompanying antisymmetric spin-orbit coupling, which admix spin-singlet and spin-triplet pairing, are responsible for this behavior. The triplet contribution is weak in Li2Pd3B, leading to a wholly open but anisotropic gap. The significantly larger spin-orbit coupling in Li2Pt3B allows the spin-triplet component to be larger in Li2Pt3B, producing line nodes in the energy gap as evidenced by the linear temperature dependence of lambda(T). The experimental data are in quantitative agreement with theory.

Helical vortex phase in the noncentrosymmetric CePt3Si.

We consider the role of magnetic fields on the broken inversion superconductor CePt3Si. We show that the upper critical field for a field along the c axis exhibits a much weaker paramagnetic effect than for a field applied perpendicular to the c axis. The in-plane paramagnetic effect is strongly reduced by the appearance of helical structure in the order parameter. We find that, to get good agreement between theory and recent experimental measurements of H(c2), this helical structure is required. We propose a Josephson junction experiment that can be used to detect this helical order. In particular, we predict that the Josephson current will exhibit a magnetic interference pattern for a magnetic field applied perpendicular to the junction normal. We also discuss unusual magnetic effects associated with the helical order.

London theory for superconducting phase transitions in external magnetic fields: application to UPt3.

For multicomponent superconductors, it is known that the presence of symmetry breaking fields can lead to multiple superconducting phase transitions. Motivated by recent small angle neutron scattering experiments on the vortex state of UPt3, the London theory in the vicinity of such phase transitions is determined. It is found that the form of this London theory is in general quite different than that for conventional superconductors. This is due to the existence of a diverging correlation length associated with these phase transitions. One striking consequence is that nontrivial vortex lattices exist arbitrarily close to H(c1). Applications to UPt3, CeIn3, U(1-x)Th(x)Be(13), electron doped cuprate superconductors, Sr(2)RuO(4), and MgCNi(3) are discussed.

Superconductivity without inversion symmetry: MnSi versus CePt3Si.

Superconductivity in materials without spatial inversion symmetry is studied. We show that in contrast to common belief, spin-triplet pairing is not entirely excluded in such systems. Moreover, paramagnetic limiting is analyzed for both spin-singlet and -triplet pairing. The lack of inversion symmetry reduces the effect of the paramagnetic limiting for spin-singlet pairing. These results are applied to MnSi and CePt3Si.

Reconstruction from small-angle neutron scattering measurements of the real space magnetic field distribution in the mixed state of Sr2RuO4.

We have measured the diffracted neutron scattering intensities from the square magnetic flux lattice in the perovskite superconductor Sr2RuO4, which is thought to exhibit p-wave pairing with a two-component order parameter. The relative intensities of different flux lattice Bragg reflections over a wide range of field and temperature have been shown to be inconsistent with a single component Ginzburg-Landau theory but qualitatively agree with a two-component p-wave Ginzburg-Landau theory.