Advanced hydrostable, recyclable and degradable cellulose hybrid films as renewable alternatives to synthetic plastics.

Strong, tough and sustainable materials are in high demand in various engineering applications. We demonstrate a potential sustainable hybrid film made from natural cellulose and a biobased slurry. Through a simple and scalable approach, cellulose can be processed into an advanced material with over 2.8 and 9.2-fold increase in dry strength and toughness after curing and a 728-fold increase in wet strength, respectively. In addition, these hybrid composite films display an outstanding antioxidant activity surpassing 90 %, along with excellent ultraviolet radiation shielding and thermal insulation properties. Further, the hybrid films can be fabricated by integrating all-natural materials and still guarantee their unique functionality. We also demonstrate the feasibility of a circular bioeconomy by recycling the hybrid film using a green, deep eutectic solvent to fabricate a recycled hybrid film that displays excellent mechanical and optical properties. When recycling is unsuitable or economical, the hybrid film can naturally degrade in the soil under 6 months. These encouraging findings suggest the promise of cellulose hybrid films as a renewable, low-cost, tough, and strong material with the potential to replace nonrenewable synthetic plastics and products.

Ultrastrong, Hydrostable, and Degradable Straws Derived from Microplastic-Free Thermoset Films for Sustainable Development.

Single-use plastics such as straws have caused intricate environmental challenges since they are not readily assimilated into nature at the end of life. Paper straws, on the contrary, become soggy and collapse in drinks resulting in an obnoxious user experience. Here, all-natural, biocompatible, degradable straws and thermoset films are engineered by integrating economical natural resources-lignin and citric acid-into edible starch and poly(vinyl alcohol), making them the casting slurry. The slurries were cast on a glass substrate, partially dried, and rolled on a Teflon rod to fabricate the straws. The straws are perfectly adhered at the edges by the strong hydrogen bonds from the crosslinker-citric acid-during drying, thus eliminating the need for adhesives and binders. Further, curing the straws and films in a vacuum oven at 180 °C results in enhanced hydrostability and endows the films with excellent tensile strength, toughness, and ultraviolet radiation shielding. The functionality of the straws and films surpassed paper and plastic straws, making them quintessential candidates for all-natural sustainable development.

Effect of bio-based derived epoxy resin on interfacial adhesion of cellulose film and applicability towards natural jute fiber-reinforced composites.

This paper reports a bio-based vanillin-derived epoxy (VDE) resin for bio-based natural fiber-reinforced composites. VDE monomer was synthesized, and curing agents, namely, 4,4´-diaminodiphenyl methane (DDM) and isophorone diamine, were used. The prepared VDE resins with various curing parameters were characterized using FTIR, NMR, tensile test, bending test and water contact angle. Further, the interfacial adhesion feasibility of VDE resins on cellulose film was studied through the single-lap shear joint examination and compared with a commercial epoxy, DGEBA. The VDE-DDM resin exhibited excellent interfacial adhesion with cellulose than VDE-IPDA and DGEBA-DDM resins. The cured VDE-DDM thermoset showed a tensile strength of 86.0 ± 6.5 MPa, thermal stability of 241.0 °C at Td5%, and an elastic modulus of 2.9 ± 0.3 GPa, which is better than the commercial epoxy resin. Besides, the developed VDE-DDM resin was used to fabricate treated-jute fiber (TJF)-reinforced composites. The bio-based VDE-DDM/TJF composite's flexural strength was higher than the commercial epoxy resin composite, DGEBA-DDM/TJF. Furthermore, the phosphorus moiety of the VDE-DDM resin endows flame retardancy to the VDE-DDM/TJF composite during combustion. Overall, the appealing properties of bio-based VDE-DDM/TJF composite render environment-friendly and high-performance structural applications.

All-biobased transparent-wood: A new approach and its environmental-friendly packaging application.

Transparent-wood (TW) is an emerging research topic that can be applied to biobased products. However, it is necessary to fill pores in TW with natural substances to prepare all-biobased TW. This paper reports an all-biobased TW by infiltrating cellulose nanofiber (CNF) and chitosan (CTS) suspensions into the bleached wood. CNF was isolated by combining the chemical and physical methods, and CTS was dissolved in acetic acid, and they were infiltrated into the pores of the bleached Fir veneer wood using a vacuum jar. The CNF and chitosan effects on the mechanical properties of the TW were studied, and the morphologies, crystallinity index, water contact angle, antioxidant, thermal degradation, and UV-shielding properties were investigated. The prepared TW showed 80 % total transmittance and 30-60 % haze, suitable for solar cell application. The all-biobased TW showed good thermal stability up to 315 °C and excellent UV shielding property for UV-B and UV-C. The antioxidant property of the CTS-TW significantly increased as compared to the original wood. The CNF-TW showed considerable tensile strength and yield strength of more than 200 % improved from the original wood. The potential for environment-friendly packaging applications was demonstrated by making a bag, medicine packaging, and straw for a drink.

Recent Research Progress on Lignin-Derived Resins for Natural Fiber Composite Applications.

By increasing the environmental concerns and depletion of petroleum resources, bio-based resins have gained interest. Recently, lignin, vanillin (4-hydroxy-3-methoxybenzaldehyde), and divanillin (6,6'-dihydroxy-5,5'-dimethoxybiphenyl-3,3'-dicarbaldehyde)-based resins have attracted attention due to the low cost, environmental benefits, good thermal stability, excellent mechanical properties, and suitability for high-performance natural fiber composite applications. This review highlights the recent use of lignin, vanillin, and divanillin-based resins with natural fiber composites and their synthesized processes. Finally, discussions are made on the curing kinetics, mechanical properties, flame retardancy, and bio-based resins' adhesion property.