Nanomaterials in Smart Packaging Applications: A Review.

Food wastage is a critical and world-wide issue resulting from an excess of food supply, poor food storage, poor marketing, and unstable markets. Since food quality depends on consumer standards, it becomes necessary to monitor the quality to ensure it meets those standards. Embedding sensors with active nanomaterials in food packaging enables customers to monitor the quality of their food in real-time. Though there are many different sensors that can monitor food quality and safety, pH sensors and time-temperature indicators (TTIs) are the most critical metrics in indicating quality. This review showcases some of the recent progress, their importance, preconditions, and the various future needs of pH sensors and TTIs in food packaging for smart sensors in food packaging applications. In discussing these topics, this review includes the materials used to make these sensors, which vary from polymers, metals, metal-oxides, carbon-based materials; and their modes of fabrication, ranging from thin or thick film deposition methods, solution-based chemistry, and electrodeposition. By discussing the use of these materials, novel fabrication process, and problems for the two sensors, this review offers solutions to a brighter future for the use of nanomaterials for pH indicator and TTIs in food packaging applications.

A reusable, reagent-less free chlorine sensor using gold thin film electrode.

Free chlorine is widely used as a disinfectant in the water industry. Accurate monitoring of the residual free chlorine concentration in water cycles is critical to maintain public health safety. Here, we report on a thin gold film-based reusable and reagent-less free chlorine sensor. A gold thin film of 300 nm thickness was deposited on a polyimide tape, which was placed on a glass substrate and a simple Styrofoam adhesive tape was used to cover the film and expose 0.36 cm2 circular area as the sensing surface. The sensor showed a high sensitivity of 0.327 µA ppm-1, with a linear range of 0 to 6 ppm, and an accuracy of <0.1 ppm with high selectivity in the presence of commonly interfering ions. The sensor response time was 50 s with a negligible hysteresis of 0.06 ppm. The sensor showed very little change in output current in the pH range between 5.2 to 8.4, and temperature range of 20 to 30 °C. Therefore, the sensor operation is reagent-less, does not need frequent calibration, and showed consistent sensing performance with real water samples. The simple fabrication, ease-of-use and reliable sensing performance of the proposed sensor shows feasibility for mass-production and application in remote and resource-limited areas.

A Low-Cost Multi-Parameter Water Quality Monitoring System.

Multi-parameter water quality monitoring is crucial in resource-limited areas to provide persistent water safety. Conventional water monitoring techniques are time-consuming, require skilled personnel, are not user-friendly and are incompatible with operating on-site. Here, we develop a multi-parameter water quality monitoring system (MWQMS) that includes an array of low-cost, easy-to-use, high-sensitivity electrochemical sensors, as well as custom-designed sensor readout circuitry and smartphone application with wireless connectivity. The system overcomes the need of costly laboratory-based testing methods and the requirement of skilled workers. The proposed MWQMS system can simultaneously monitor pH, free chlorine, and temperature with sensitivities of 57.5 mV/pH, 186 nA/ppm and 16.9 mV/°C, respectively, as well as sensing of BPA with <10 nM limit of detection. The system also provides seamless interconnection between transduction of the sensors' signal, signal processing, wireless data transfer and smartphone app-based operation. This interconnection was accomplished by fabricating nanomaterial and carbon nanotube-based sensors on a common substrate, integrating these sensors to a readout circuit and transmitting the sensor data to an Android application. The MWQMS system provides a general platform technology where an array of other water monitoring sensors can also be easily integrated and programmed. Such a system can offer tremendous opportunity for a broad range of environmental monitoring applications.

Tailoring MWCNTs and ß-Cyclodextrin for Sensitive Detection of Acetaminophen and Estrogen.

Monitoring of trace amount of acetaminophen and estrogen in drinking water is of great importance because of their potential links to gastrointestinal diseases and breast and prostate cancers. The sensitive and accurate detection of acetaminophen and estrogen requires the development of advanced sensing materials that possess appropriate number of analyte-capturing sites and suitable signal conduction path. This can be achieved by implementing appropriate chemical attachment of multiwalled carbon nanotubes (MWCNTs) and ß-cyclodextrin (ßCD). Here, we report a systematic investigation of four types of modified MWCNT-ßCD: (1) physical mixing, (2) "click reaction", (3) thionyl chloride esterification, and (4) Steglich esterification. The Steglich esterification is a one-step approach with shorter reaction time, lower reaction temperature, and eliminates handling of air/moisture-sensitive reagents. MWCNT-ßCD prepared by Steglich esterification possessed moderate ßCD loading (5-10 wt %), large effective surface area, and fast electron transfer. The host-guest interaction of ßCD and redox properties of MWCNT enabled sensitive detection of acetaminophen and 17ß-estradiol (E2 is a primary female sex hormone) in the range of 0.005-20 and 0.01-15 µM, with low detection limits of 3.3 and 2.5 nM, respectively. We demonstrated accurate detection results of pharmaceutical compositions in water and urine samples. These results indicate that Steglich esterification method may be applied in fabricating pharmaceutical contaminants sensors for health and environmental applications.