Effect of thermal-calcium peroxide mediated exopolymer release on disperser pre-treatment for efficient anaerobic digestion.

The present study aimed to improve the hydrolysis potential of paper mill sludge through a two-phase disintegration process. In Particular, attention was focused on removal of extracellular polymeric substance (EPS) i.e. deflocculation of sludge in order to improve the efficiency of subsequent disperser disintegration. During deflocculation, carbohydrate, protein and deoxyribonucleic acids (DNA) were used as assessment parameters. During disintegration, soluble chemical oxygen demand (SCOD) and suspended solids (SS) reduction were used as assessment index to evaluate the efficiency of disintegration. A greater EPS removal was attained while deflocculating the sludge at calcium peroxide dosage of 0.05 g/g suspended solids (SS) and at a temperature of 70 °C. When comparing the disintegrated samples, a clear variation was noted in deflocculated and disintegrated sludge (19.2%) than the disintegrated sludge alone (13.5%). This clearly shows the need for deflocculation prior to disintegration. Likewise, a higher biomethane production of 0.214 L/g COD was achieved in deflocculated and disintegrated sludge than the pretreated sludge alone. Deflocculation reduces sludge management cost from 170 USD (Disperser alone (D alone disintegration)) to 51 USD (Thermal calcium peroxide mediated-Disperser (TCaO2-D disintegration), indicating the efficiency of the proposed disintegration.

Semi-continuous anaerobic co-digestion of thermal and thermal-alkali processed organic fraction of municipal solid waste: Methane yield, energy analysis, anaerobic microbiome.

The semi-continuous anaerobic co-digestion (AcoD) of thermal and thermal-alkali pretreated organic fraction of municipal solid waste (OFMSW) and sewage sludge (SS) was studied under varying hydraulic retention times (HRT) and organic loading rates (OLR Three semi-continuous digesters were operated under control (non-pre-treated), thermally pretreated (125 °C), and thermal-alkali pretreated (125°C-3g/L NaOH) conditions at variable OLRs at 2.5, 4.0, 5.1, and 7.6 kgVS/m3.d and corresponding HRTs of 30, 20, 15, and 10 days. The 10 and 43% higher methane yield (0.445 m3/kgVS) and 11 and 57% higher VS removal (52%) was achieved for thermal-alkali pretreated digester at 5.1 kgVS/m3.d OLR over thermally pretreated (0.408 m3/kgVS, 45% VS removal) and control digesters (0.310 m3/kgVS, 33% VS removal), respectively. Thermal and thermal-alkali digesters failed on increasing the OLR to 7.6 kgVS/m3.d, whereas the control digester becomes upset at 5.1 kgVS/m3.d OLR. The metagenomic study revealed that Firmicutes, Bacteroidetes, Chloroflexi, Euryarchaeota, Proteobacteria, and Actinobacteria were the predominant bacterial population, whereas Methanosarcina and Methanothrix dominated the archaeal community. Energy balance analysis revealed that thermal alkali pretreatment showed the highest positive energy balance of 114.6 MJ/ton with an energy ratio of 1.25 compared with thermally pretreated (81.5 MJ/ton) and control samples (-46.9 MJ/ton). This work pave the way for scaleup of both thermal and thermal-alkali pre-treatment at 125 °C to realize the techno-economic and energy potential of the process.

Novel framework of GIS based automated monitoring process on environmental biodegradability and risk analysis using Internet of Things.

A proper method on real-time monitoring of organic biomass degradation and its evaluation for safeguarding the ecosystem is the need of the hour. The work process designed in this study is to demarcate the anaerobic digestion potential using kinetic modelling and web GIS application methods. Wastewater source that causes pollution are identified through satellite maps such as solid earth, drain system, surface of earth structure, land filling and land use. The grabbed data are utilized for identifying the concentration of sludge availability. Based on literature resource multi influencing factor techniques are introduced along with overlay method to differentiate digestion potential of sludge source. This study optimizes the biodegradation potential of domestic sewage at different sludge concentrations in a pilot model operated with the samples identified through topographical drainage survey. The materialization of devices is using the Internet of Things (IoTs), that is pragmatic to be the promising tendency. Kinetic study, methanogenic assay test are performed with three different cation binding agents to find its solubilization potential and methane evolution, which is further subjected to digestion potential in anaerobic conditions for possible application in the field of environmental science. Risk analysis reveals that land filling method will have highest impact on maintaining sustainable environment. The results outcome on natural biodegradation may be used for individual house hold wastewater management for the locality.

Enhanced phytoextraction of multi-metal contaminated soils under increased atmospheric temperature by bioaugmentation with plant growth promoting Bacillus cereus.

The co-occurrence of environmental stresses such as heavy metals (HM) and increased atmospheric temperature (IAT) pose serious implications on plant growth and productivity. In this work, we evaluated the role of plant growth-promoting bacteria (PGPB) and its effectiveness on Zea mays growth, stress tolerance and phytoremediation potential in multi-metal (MM) contaminated soils under IAT stress conditions. The PGPB strain TCU11 was isolated from metal contaminated soils and identified as Bacillus cereus. TCU11 was able to resist abiotic stresses such as IAT (45 °C), MM (Pb, Zn, Ni, Cu, and Cd), antibiotics and induced in vitro plant growth promotion (PGP) by producing siderophores (catechol and hydroxymate) and indole 3-acetic acid even in the presence of MM under IAT. Inoculation of TCU11 significantly increased the biomass, chlorophyll, carotenoids, and protein content of Z. mays compared to the respective control under MM, IAT, and MM + IAT stress. A decrease of malondialdehyde and over-accumulation of total phenolics, proline along with the increased activity of superoxide dismutase, catalase and ascorbic peroxidase were observed in TCU11 inoculated plants under stress conditions. These results suggested MM and/or IAT significantly reduced the maize growth, whereas TCU11 inoculation mitigated the combined stress effects on maize performance. Moreover, the inoculation of TCU11 under IAT stress increased the MM (Pb, Zn, Ni, Cu, and Cd) accumulation in plant tissues and also increased the translocation of HM from root to shoot except for Ni. The results of soil HM mobilization further indicates that IAT increased the HM mobilizing activity of TCU11, thus increasing the concentrations of bio-available HM in soil. These results suggested that TCU11 not only alleviates MM and IAT stresses but also enhances the biomass production and HM accumulation in plants. Therefore, TCU11 can be exploited as inoculums for improving the phytoremediation efficiency in MM polluted soils under IAT conditions.

Mechanical-biological treatment of municipal solid waste: Case study of 100 TPD Goa plant, India.

A long-term feasibility analysis of a 100 ton per day mechanical biological treatment (MBT) plant for municipal solid waste (MSW) valorization and material and energy recovery was carried out. It involves the material recovery and segregation stage (MRSS), organic extraction (pulping), thermophilic anaerobic digestion (AD), composting, effluent treatment plant (ETP), and biogas genset stages producing: 11.90% recyclables, 33% refused derived fuel (RDF), 5% compost of total waste received, 70 m3/day recyclable water and 0.435 MWh/day electricity. The biogas and methane yield were 0.535 and 0.350 m3/kg VSadded (avg.), respectively, with 40% VS removal (avg total solids (TS) 10%). Less than 3% (inert) of total waste received was subjected to landfill disposal. The MBT plant's revenue generation is 995 US$ per day/148 tons ($ 6.72/ton) waste processed. The gross OPEX is 24 US$/ton making the net OPEX of 17 US$/ton (minus revenue), which could be considered as the excellent OPEX for MSW based MBT plants as per global benchmarks. Further, local usage of RDF can significantly reduce the OPEX to 14 US$/ton, as almost 16% of the OPEX goes towards RDF disposal to cement companies located at a distance of 200-500 km from the MBT plant site. As per LCA study, the total GHG emissions have been calculated to be -25.68 tons CO2 eq./100 tons MSW. The negative emissions result from the export of electricity, compost, and RDF as well as recycling of paper and plastic products. Our study presents a cutting-edge scenario of all-inclusive recycling, recovery, and reuse loop of MSW direly required for accomplishing a circular economy.

A brief review of anaerobic membrane bioreactors emphasizing recent advancements, fouling issues and future perspectives.

This review summarizes the recent development and studies of anaerobic membrane bioreactor (AnMBR) to control fouling issues. AnMBR is an emerging waste water treatment technology mainly because of its low sludge residual, high volumetric organic removal rate, complete liquid-solid separation, better effluent quality, efficient resource recovery and the small footprint. This paper surveys the fundamental aspects of AnMBRs, including its applications, membrane configurations, and recent progress for enhanced reactor performance. Furthermore, the membrane fouling, a major restriction in the practical application of AnMBR, its mechanism and antifouling strategies like membrane cleaning, quorum quenching, ultrasonic treatment, membrane modifications, and antifouling agents are briefly discussed. Based on the review, the key issues that require urgent attention to facilitate large scale and integrated application of AnMBR technology are identified and future research perspectives relating to the prevalent issues are proposed.

Hydroxamic acid mediated heterogeneous Fenton-like catalysts for the efficient removal of Acid Red 88, textile wastewater and their phytotoxicity studies.

Heterogeneous Fenton-like catalyst and its industrial application are increasingly given importance for its non-selective mineralization of organic pollutants in broad pH range. Current study, utilized an aromatic hydroxamic acid derivative 2-hydroxypyridine-N-oxide (HpO), for the construction of iron-Hpo ligand catalyst supported on granular activated carbon (GAC). 8-Hydroxyquinoline and citric acid as non-hydroxamic aromatic and aliphatic Fenton-like catalysts were used for comparative evaluation of the efficiency with targeted catalyst (iron-HpO-GAC). This novel catalyst iron-HpO-GAC exhibits excellent efficiency in Acid Red 88 dye removal in the presence of hydrogen peroxide as oxidant at acidic, basic as well as at neutral conditions. Operational conditions for the catalytic oxidation including temperature, dye concentration, pH and catalyst dosage were systematically investigated and analyzed through kinetic studies. Thermodynamic analysis of the catalytic dye removal revealed that the system could oxidize pollutants faster with less activation energy requirement. Higher level of recyclability and stability of the catalyst with less iron leaching was achieved. Finally, the real time application of the catalyst was investigated through successful repeated treatment for actual industrial wastewater. The phytotoxicity assay (with respect to plant Phaseolus mungo) revealed that the degradation of Acid Red 88 and dye wastewater produced nontoxic metabolites which increases its potential application. This study emphasizes the viability of hydroxamate mediated efficient Fenton-like oxidation as a novel approach in designing economically viable pollutant removal technology.

Feasibility analysis of homogenizer coupled solar photo Fenton process for waste activated sludge reduction.

In this study, an attempt has been made to reduce the sludge using novel homogenizer coupled solar photo Fenton (HPF) process. At an optimum pH of 3 and Fe2+ to H2O2 dosage of 1:6, PF process yielded 63.7% solids reduction at a time interval of 45 min. Coupling of homogenizers with photo Fenton (PF) process effectively enhanced treatment efficiency. When homogenizer (specific energy - 1150.694 kJ/kg TS) was coupled with PF, a sharp increase in solid reduction 73.5% and decrease in reaction time (20 min) were observed. Cost benefit analysis revealed the efficiency of HPF process and achieved a net cost of 15.59 USD whereas PF achieved a negative net cost of -82.69 USD. Based on the above study it can be concluded that coupling of homogenizers with PF not only increased its efficiency but also make it field applicable.

Combinative treatment of phenol-rich retting-pond wastewater by a hybrid upflow anaerobic sludge blanket reactor and solar photofenton process.

In this study, recalcitrant rich retting-pond wastewater was treated primarily by anaerobic treatment and subsequently treated with a solar photofenton process to remove phenol and organics. The anaerobic treatment was carried out in a granulated laboratory scale hybrid upflow anaerobic sludge blanket reactor (HUASBR) with a working volume of 5.9 L. It was operated at different hydraulic retention times (HRT) from 40 to 20 h over a period of 140 days. The optimum HRT of the anaerobic reactor was found to be 30 h, with corresponding chemical oxygen demand (COD) and phenol removal of 60% and 47%, respectively. Primary anaerobically treated wastewater was subjected to secondary solar photofenton treatment which was carried out at pH 3.5. Response surface methodology (RSM) was used to design and optimize the performance of the solar photofenton process. Regression quadratic model describing COD removal efficiency of the solar photofenton process was developed and confirmed by analysis of variance (ANOVA). Optimum parameters of the solar photofenton process were found to be: 4 g/L of fenton as catalysts, 25 mL of hydrogen peroxide, and 30 min of reaction time. After the primary anaerobic treatment, solar photofenton oxidation process removed 94% and 96.58% of COD and phenol, respectively. Integration of anaerobic and solar photofenton treatment resulted in 97.5% and 98.4% removal of COD and phenol, respectively, from retting-pond wastewater.

A hybrid constructed wetland for organic-material and nutrient removal from sewage: Process performance and multi-kinetic models.

A pilot-scale hybrid constructed wetland with vertical flow and horizontal flow in series was constructed and used to investigate organic material and nutrient removal rate constants for wastewater treatment and establish a practical predictive model for use. For this purpose, the performance of multiple parameters was statistically evaluated during the process and predictive models were suggested. The measurement of the kinetic rate constant was based on the use of the first-order derivation and Monod kinetic derivation (Monod) paired with a plug flow reactor (PFR) and a continuously stirred tank reactor (CSTR). Both the Lindeman, Merenda, and Gold (LMG) analysis and Bayesian model averaging (BMA) method were employed for identifying the relative importance of variables and their optimal multiple regression (MR). The results showed that the first-order-PFR (M2) model did not fit the data (P > 0.05, and R2 < 0.5), whereas the first-order-CSTR (M1) model for the chemical oxygen demand (CODCr) and Monod-CSTR (M3) model for the CODCr and ammonium nitrogen (NH4-N) showed a high correlation with the experimental data (R2 > 0.5). The pollutant removal rates in the case of M1 were 0.19 m/d (CODCr) and those for M3 were 25.2 g/m2∙d for CODCr and 2.63 g/m2∙d for NH4-N. By applying a multi-variable linear regression method, the optimal empirical models were established for predicting the final effluent concentration of five days' biochemical oxygen demand (BOD5) and NH4-N. In general, the hydraulic loading rate was considered an important variable having a high value of relative importance, which appeared in all the optimal predictive models.

A magnetically separable and recyclable Ag-supported magnetic TiO2 composite catalyst: Fabrication, characterization, and photocatalytic activity.

In this study, a magnetically separable, highly active, and recyclable photocatalyst was synthesized by physico-chemical incorporation of Ag, TiO2, and Fe3O4 into one structure. The physical and chemical properties of the catalysts were evaluated by X-ray diffraction, X-ray fluorescence spectrometry, scanning electron microscopy, field emission transmission electron microscopy, energy dispersive X-ray spectroscopy, and diffuse reflectance spectroscopy. The Ag-supported magnetic TiO2 composite demonstrated desirable properties and features such as a narrow band gap of 1.163 eV, modifiable structure, and high degradation efficiency. The activity and durability of the synthesized photocatalyst in the degradation of methyl orange (MO) in aqueous solutions under visible light irradiation and different experimental conditions were evaluated and compared to those of commercial TiO2 and Ag/TiO2 composites. It was found that the synthesized composite showed a much higher MO photodegradation efficiency than the other composites under visible light irradiation. Moreover, it exhibited a high photocatalytic activity and was recoverable and durable; its photocatalytic efficiency in MO removal was consistently higher than 93.1% after five reuses without any evident signs of deactivation. Thus, the developed photocatalyst is a very promising material for practical applications in environmental pollution remediation.

Treatment of seafood processing wastewater using upflow microbial fuel cell for power generation and identification of bacterial community in anodic biofilm.

Tubular upflow microbial fuel cell (MFC) utilizing sea food processing wastewater was evaluated for wastewater treatment efficiency and power generation. At an organic loading rate (OLR) of 0.6 g d(-1), the MFC accomplished total and soluble chemical oxygen demand (COD) removal of 83 and 95%, respectively. A maximum power density of 105 mW m(-2) (2.21 W m(-3)) was achieved at an OLR of 2.57 g d(-1). The predominant bacterial communities of anode biofilm were identified as RB1A (LC035455), RB1B (LC035456), RB1C (LC035457) and RB1E (LC035458). All the four strains belonged to genera Stenotrophomonas. The results of the study reaffirms that the seafood processing wastewater can be treated in an upflow MFC for simultaneous power generation and wastewater treatment.

Co-metabolic degradation of benzo(e)pyrene by halophilic bacterial consortium at different saline conditions.

Polyaromatic hydrocarbons (PAHs) with high molecular weight (more than three benzene rings) were difficult to degrade in saline environment. The present study details about the bacterial consortium enriched from industrial sludge from salt manufacturing company, Tuticorin, Tamilnadu (India), which was capable of degrading 1, 4 dioxane (Emerging micropollutant) and also phenanthrene as sole carbon source under saline condition. The halophilic bacterial consortium was able to degrade low molecular weight (LMW) phenanthrene, but unable to degrade high molecular weight (HMW) benzo(e)pyrene. To overcome this problem, phenanthrene was added as co-substrate along with benzo(e)pyrene which enhanced the biodegradation process by co-metabolism under saline conditions. The consortium potentially degraded 80% and 99% of benzo(e)pyrene in 7 days and phenanthrene in 5 days at 30 g l⁻¹ of NaCl concentration. When the saline concentration increased to 60 g l⁻¹, degradation of phenanthrene (97% in 8 days) and benzo(e)pyrene (65% in 10 days) was observed. Further increase in saline concentration to 90 g I⁻¹ of NaCI showed reduction in the percent degradation of phenanthrene and benzo(e)pyrene leads to 30.3% and 9% respectively in 6 days. Potential bacterial strains, present in PAHs degrading bacterial consortium were identified as Achromobacter sp. AYS3 (JQ419751), Marinobacter sp. AYS4 (JQ419752) and Rhodanobacter sp. AYS5 (JQ419753). The present study details about the effect of salinity on PAHs degradation and vital role of co-metabolism on biodegradation of benzo(e)pyrene with phenanthrene under saline conditions.

Biological pretreatment of non-flocculated sludge augments the biogas production in the anaerobic digestion of the pretreated waste activated sludge.

High-efficiency resource recovery from municipal solid waste (MSW) has been a focus of attention. The objective of this research is to develop a bio-pretreatment process for application prior to the anaerobic digestion of MSW to improve methane productivity. Bacillus licheniformis was used for pretreating MSW (non-flocculated with 0.07% citric acid), followed by anaerobic digestion. Laboratory-scale experiments were carried out in semi-continuous bioreactors, with a total volume of 5 L and working volume of 3 L. Among the nine organic loading rates (OLRs) investigated, the OLR of 0.84 kg SS m(-3) reactor day(-1) was found to be the most appropriate for economic operation of the reactor. Pretreatment of MSW prior to anaerobic digestion led to 55% and 64% increase of suspended solids (SS) and volatile solids reduction, respectively, with an improvement of 57% in biogas production. The results indicate that the pretreatment of non-flocculated sludge with Bacillus licheniformis which consumes less energy compared to other pretreatment techniques could be a cost-effective and environmentally sound method for producing methane from MSW.

Augmentation in polyhydroxybutyrate and biogas production from waste activated sludge through mild sonication induced thermo-fenton disintegration.

In this study, an innovative approach was developed to enhance the hydrolysis through phase-separated pretreatment by removing exopolymeric substances via mild sonication followed by thermo-Fenton disintegration. The exopolymeric substances fragmentation was enhanced at the sonic specific energy input of 2.58 kJ/kg total solids. After exopolymeric substance removal, the disintegration of biomass by thermo-Fenton yield the solubilization of 29.8 % at Fe2+:H2O2 dosage and temperature of 0.009:0.036 g/g suspended solids and 80 °C as compared to thermo-Fenton alone disintegration. The polyhydroxybutyrate content of 93.1 % was accumulated by Bacillus aryabhattai at the optimum time of 42 h, while providing 70 % (v/v) pre-treated supernatant as a carbon source under nutrient-limiting condition. Moreover, the biogas generation of 0.187 L/g chemical oxygen demand was achieved using settled pretreated sludge. The pretreated sludge sample thus served as a carbon source for polyhydroxybutyrate producers as well as substrate for biogas production.

Combined sodium citrate and ultrasonic pretreatment of waste activated sludge for cost effective production of biogas.

This study aimed to pretreat the waste activated sludge (WAS) by ultrasonication in an energy efficient way by combining sodium citrate with ultrasonic pretreatment at 0.03 g/g suspended solids (SS) of dosage. The ultrasonic pretreatment was done at various (20-200 W) power levels, sludge concentration (7 to 30 g/L), sodium citrate dosages (0.01 to 0.2 g/g SS). An elevated COD solubilization of 26.07 ± 0.6 % was achieved by combined pretreatment at a treatment time of 10 min, ultrasonic power level of 160 W when compared to individual ultrasonic pretreatment (18.6 ± 0.5 %). A higher biomethane yield of 0.26 ± 0.009 L/g COD was achieved in sodium citrate combined ultrasonic pretreatment (SCUP) than ultrasonic pretreatment (UP) 0.145 ± 0.006 L/g COD. Almost 50% of the energy can be saved through SCUP when compared to UP. Future study evaluating SCUP in continuous mode anaerobic digestion is vital.

Microbial Exopolysaccharide Composites in Biomedicine and Healthcare: Trends and Advances.

Microbial exopolysaccharides (EPSs), e.g., xanthan, dextran, gellan, curdlan, etc., have significant applications in several industries (pharma, food, textiles, petroleum, etc.) due to their biocompatibility, nontoxicity, and functional characteristics. However, biodegradability, poor cell adhesion, mineralization, and lower enzyme activity are some other factors that might hinder commercial applications in healthcare practices. Some EPSs lack biological activities that make them prone to degradation in ex vivo, as well as in vivo environments. The blending of EPSs with other natural and synthetic polymers can improve the structural, functional, and physiological characteristics, and make the composites suitable for a diverse range of applications. In comparison to EPS, composites have more mechanical strength, porosity, and stress-bearing capacity, along with a higher cell adhesion rate, and mineralization that is required for tissue engineering. Composites have a better possibility for biomedical and healthcare applications and are used for 2D and 3D scaffold fabrication, drug carrying and delivery, wound healing, tissue regeneration, and engineering. However, the commercialization of these products still needs in-depth research, considering commercial aspects such as stability within ex vivo and in vivo environments, the presence of biological fluids and enzymes, degradation profile, and interaction within living systems. The opportunities and potential applications are diverse, but more elaborative research is needed to address the challenges. In the current article, efforts have been made to summarize the recent advancements in applications of exopolysaccharide composites with natural and synthetic components, with special consideration of pharma and healthcare applications.

Green chemical and hybrid enzymatic pretreatments for lignocellulosic biorefineries: Mechanism and challenges.

The greener chemical and enzymatic pretreatments for lignocellulosic biomasses are portraying a crucial role owing to their recalcitrant nature. Traditional pretreatments lead to partial degradation of lignin and hemicellulose moieties from the pretreated biomass. But it still restricts the enzyme accessibility for the digestibility towards the celluloses and the interaction of lignin-enzymes, nonproductively. Moreover, incursion of certain special chemical treatments and other lignin sulfonation techniques to the enzymatic pretreatment (hybrid enzymatic pretreatment) enhances the lignin structural modification, solubilization of the hemicelluloses and both saccharification and fermentation processes (SAF). This article concentrates on recent developments in various chemical and hybrid enzymatic pretreatments on biomass materials with their mode of activities. Furthermore, the issues on strategies of the existing pretreatments towards their industrial applications are highlighted, which could lead to innovative ideas to overcome the challenges and give guideline for the researchers towards the lignocellulosic biorefineries.

A review on the pollution assessment of hazardous materials and the resultant biorefinery products in Palm oil mill effluent.

The voluminous nature of palm oil mill effluent (POME) is directly associated with environmental hazards and could be turned into biorefinery products. The POME, rich in BOD, COD, and oil and grease, with few hazardous materials such as siloxanes, fatty acid methyl ester, and phenolic compounds that may significantly increase the risk of violating the effluent quality standards. Recently, the application of chemical and biological risk assessment that can use electrochemical sensors and microalgae-like species has gained paramount attention towards its remediation. This review describes the existing risk assessment for POME and recommends a novel assessment approach using fish species including invasive ones as suitable for identifying the toxicants. Various physico-chemical and biological treatments such as adsorption, coagulation-flocculation, photo-oxidation, solar-assisted extraction, anaerobic digestion, integrated anaerobic-aerobic, and microalgae cultivation has been investigated. This paper offers an overview of anaerobic technologies, with particular emphasis on advanced bioreactors and their prospects for industrial-level applications. To illustrate, palmitic acid and oleic acid, the precursors of fatty acid methyl ester found in POME pave the way to produce biodiesel with 91.45%. Although there are some challenges in attaining production at an economic scale, this review offers some opportunities that could help in overcoming these challenges.

A novel method of sludge pretreatment using the combination of alkalis.

The present study aims to utilise the advantage of higher sludge solubilisation potential of sodium hydroxide (NaOH) and sludge management properties of lime to achieve sludge pretreatment and its subsequent management. The optimum dosage and time required for sludge pretreatment using NaOH was found to be 1.6 g l(-1) and 3 hr, respectively. At the optimized condition, lime was added at varying concentration (0.3 to 1.6 g l(-1)) to study its effect on capillary suction time, soluble chemical oxygen demand (SCOD) release and total phosphorous (TP) removal. A lime dosage of 0.7g l(-1) was found to be beneficial for soluble chemical oxygen demand (COD) release. When compared to control, the combination of alkalis (NaOH and lime) reduced the TP and capillary suction time (CST) in the supernatant of the sludge. The TP removal was from 100 to 40 mg l(-1) and CST reduction was from 1360 to 350 sec, respectively. The combined alkali pretreatment not only prevent the subsequent TP increase in the effluent, but also decreased the time to filter the sludge, thus makes the digested sludge easier to manage.