An Analysis of Hydromorphological Index for Rivers (HIR) Model Components, Based on a Hydromorphological Assessment of Watercourses in the Central European Plain.

Assessing the hydromorphological conditions of watercourses is a requirement of the Water Framework Directive (WFD) and national river status monitors (e.g., in Poland,the State Environmental Monitoring, and Water Monitoring coordinated by Chief Inspectorate of Environmental Protection). This paper evaluates the hydromorphological status of 10 watercourses (30 measurement sections) in Poland based on the multimetric Hydromorphological Index for Rivers (HIR). A new approach to the delineation of the river valley (small watercourses) is proposed. An analysis of the influence of river valley management on the value of HIR and its components was carried out using statistical methods (basic statistics, Mann-Whitney U Test and Ward's cluster analysis). In addition, the relationship between the components of the HDS (Hydromorphological Diversity Score) and HMS (Hydromorphological Modification Score) was analyzed (Spearman's Rank Correlation Coefficient). HIR values for the watercourse sections ranged from 0.553 to 0.825. HDS values ranged from 27.5 to 75.5 and HMS from 2.0 to 17.5. The results of the basic statistical analyses showed slight differences between the two river valley delineation methods. The Mann-Whitney U Test showed a significant difference in the test significance level of the HDS, HMS and HIR for the river valley delineation methods. Spearman's rank correlation analysis showed that most of the HDS and HMS parameters components had a low degree of correlation. The juxtaposition of the two methods for delineating a river valley and its influence on the HIR allows for a better understanding of the interdependence between its parameters.

Preparation, Characterization of Granulated Sulfur Fertilizers and Their Effects on a Sandy Soils.

There is a potential for using sulfur waste in agriculture. The main objective of this study was to design a granular fertilizer based on waste elemental sulfur. Humic acids and halloysite were used to improve the properties and their influence on soil properties. This is the first report on the use of proposed materials for fertilizer production. The following granular fertilizers were prepared (the percentage share of component weight is given in brackets): fertilizer A (waste sulfur (95%) + halloysite (5%)), fertilizer B (waste sulfur (81%) + halloysite (5%) + humic acids (14%)), fertilizer C (waste sulfur (50%) + halloysite (50%)) and fertilizer D (waste sulfur (46%) + halloysite (46%) + humic acids (8%)). Basic properties of the obtained granulates were determined. Furthermore, the effect of the addition of the prepared fertilizers on soil pH, electrolytic conductivity, and sulfate content was examined in a 90-day incubation experiment. Enrichment with humic acids and the higher amount of halloysite increased the fertilizer properties (especially the share of larger granules and bulk density). In addition, it stabilized soil pH and increased the sulfur content (extracted with 0.01 mol·L-1 CaCl2 and Mehlich 3) in the soil.

Environmental and Production Aspects of Using Fertilizers Based on Waste Elemental Sulfur and Organic Materials.

Crop fertilization with sulfur is an important part of agricultural practices, as is the systematic increase in soil organic matter content. Materials of waste origin constitute a source of plant-available sulfur, as well as soil organic matter. The study was to verify the hypothesis assuming that combining waste sulfur pulp and its mixtures with organic materials enables simultaneous soil enrichment with readily available sulfur and organic matter. A 240-day incubation experiment was conducted, on two soils: very light and heavy; with two sulfur doses applied to each soil (20 and 40 mg S/kg d.m. for very light soil, and 30 and 60 mg S/kg d.m. for heavy soil). The sulfate sulfur content in the incubated soil material, treated with the addition of sulfur pulp and its mixtures with organic materials, increased significantly up to day 60 and then decreased. The application of these materials significantly increased the content of available sulfur and decreased the pH value of the incubated material. The effect of the introduced materials on dehydrogenase activity depended on soil granulometric composition (the impact of the applied materials on the activity of these enzymes in very light soil was small, and in heavy soil, their activity was usually limited by the presence of introduced materials). Application of the studied materials had little effect on the total organic carbon content in the incubated soil material (a significant change in the value of this parameter, in relation to the control soil, was recorded in some treatments of heavy soil).

Nitrate leaching losses from two Baltic Sea catchments under scenarios of changes in land use, land management and climate.

Pollution with excess nutrients deteriorate the water quality of the Baltic Sea. The effect of combined land use and climate scenarios on nitrate leaching and nitrogen (N) loads to surface waters from two Baltic Sea catchments (Norsminde in Denmark and Kocinka in Poland) was explored using different models; the NLES and Daisy models for nitrate leaching, and MIKE SHE or MODFLOW/MT3DMS for N transport. Three Shared Socioeconomic Pathways (SSP1, SSP2 and SSP5) defined change in land use and agricultural activities. The climate change scenarios covered 2041-2060 compared with 1991-2010 under RCP8.5, applying four different climate models. Increases in predicted N-load from climate change vary from 20 to 60% depending on climate model. SSPs moderate these N-load changes with small changes for SSP1 to large increases for SSP5, with greater increases for Norsminde than Kocinka due to land use differences. This stresses needs for new measures and governing schemes to meet sustainability targets.