Dispersion of single walled carbon nanotubes in amidine solvents.

The excellent electronic and material properties of single walled carbon nanotubes (SWNTs) makes this nanomaterial very attractive for incorporation into flexible and stretchable electronics. However, the widespread application of SWNTs in electronic devices is still limited. To purify, process and place SWNTs, appropriate solvents for dispersion are needed. However, a fundamental understanding of the reasons why certain solvents are capable of dispersing SWNTs is still missing. Here we report on two new potential solvents containing amidine moieties, 1,8-diazabicycloundec-7-ene (DBU) and 1,5-diazabicyclo(4.3.0)non-5-ene (DBN). Even though these solvents' molecular structures differ by only two -CH(2)- groups, we found that DBU is capable of dispersing SWNTs, while DBN is not. We carried out density functional theory (DFT) calculations to investigate the interaction between DBU and DBN, and we elucidated the reasons for the different performances of the two solvents. DBU has a preferential edge-on interaction with the SWNT, thus allowing for a higher solvent coverage than DBN. In addition, the CH(2)-SWNT interaction present for DBU substantially increases the adsorption energy compared to DBN. Our results point to the important interplay between the interaction of pi electrons, nitrogen lone pairs and the -CH(2)- groups present in aprotic solvent molecules and the delocalized pi electrons in SWNTs.

Studies on plant-mediated fate of the explosives RDX and HMX.

The fate of the explosives RDX and HMX on exposure to plants was investigated in 'natural' aquatic systems of Myriophyllum aquaticum for 16 days, and in axenic hairy root cultures of Catharanthus roseus for > or = 9 weeks. Exposure levels were: HMX, 5 mg/l; and RDX, approximately 8 mg/l. Exposure outcomes observed include: HMX, no transformation by aquatic plants, and minimal biological activity by axenic roots; and RDX, removal by both plant systems. In the case of RDX exposure to axenic roots, since 14C-RDX was included, removal was confirmed by the accumulation of 14C-label in the biomass. The intracellular 14C-label in these RDX studies was detected in two forms: intact RDX and bound unknown(s).

Acute epiglottitis in an adult.

A 33-year old man developed acute epiglottitis of sudden onset which resulted in severe respiratory distress. A small endotracheal tube was passed as an emergency procedure. Respiratory arrest developed after he pulled it out 12 hr later. Subsequent progress was satisfactory following endotracheal intubation and treatment with ampicillin and hydrocortisone. Blood cultures grew Haemophilus influenzae.