Effect of Load on Quartz Crystal Microbalance Sensor Response Addressed Using Fractional Order Calculus.

To accurately model the effect of the load caused by a liquid medium as a function of its viscosity, the fractional order Butterworth-Van Dyke (BVD) model of the QCM sensor is proposed in this study. A comprehensive understanding of the fractional order BVD model followed by a simulation of situations commonly encountered in experimental investigations underpins the new QCM sensor approach. The Levenberg-Marquardt (LM) algorithm is used in two fitting steps to extract all parameters of the fractional order BVD model. The integer-order electrical parameters were determined in the first step and the fractional order parameters were extracted in the second step. A parametric investigation was performed in air, water, and glycerol-water solutions in ten-percent steps for the fractional order BVD model. This indicated a change in the behavior of the QCM sensor when it swapped from air to water, modeled by the fractional order BVD model, followed by a specific dependence with increasing viscosity of the glycerol-water solution. The effect of the liquid medium on the reactive motional circuit elements of the BVD model in terms of fractional order calculus (FOC) was experimentally demonstrated. The experimental results demonstrated the value of the fractional order BVD model for a better understanding of the interactions occurring at the QCM sensor surface.

Spurious Resonance of the QCM Sensor: Load Analysis Based on Impedance Spectroscopy.

A research topic of equal importance to technological and application fields related to quartz crystal is the presence of unwanted responses known as spurious resonances. Spurious resonances are influenced by the surface finish of the quartz crystal, its diameter and thickness, and the mounting technique. In this paper, spurious resonances associated with fundamental resonance are studied by impedance spectroscopy to determine their evolution under load conditions. Investigation of the response of these spurious resonances provides new insights into the dissipation process at the QCM sensor surface. The significant increase of the motional resistance for spurious resonances at the transition from air to pure water is a specific situation revealed experimentally in this study. It has been shown experimentally that in the range between the air and water media, spurious resonances are much more attenuated than the fundamental resonance, thus providing support for investigating the dissipation process in detail. In this range, there are many applications in the field of chemical sensors or biosensors, such as VOC sensors, humidity sensors, or dew point sensors. The evolution of D factor with increasing medium viscosity is significantly different for spurious resonances compared to fundamental resonance, suggesting the usefulness of monitoring them in liquid media.

Quartz Crystal Microbalance with Impedance Analysis Based on Virtual Instruments: Experimental Study.

The impedance quartz crystal microbalance (QCMI) is a versatile and simple method for making accurate measurements of the QCM sensor electrical parameters. The QCM sensor provides access to the physical parameters of the sample beyond the mass per unit area by measuring the dissipation factor, or another equivalent, ensuring a detailed analysis of the surface. By establishing a cooperative relationship between custom software and modular configurable hardware we obtain a user-defined measurement system that is called a virtual instrument. This paper aims primarily to improve and adapt existing concepts to new electronics technologies to obtain a fast and accurate virtual impedance analyzer (VIA). The second is the implementation of a VIA by software to cover a wide range of measurements for the impedance of the QCM sensor, followed by the calculation of the value of lumped electrical elements in real time. A method for software compensation of the parallel and stray capacitance is also described. The development of a compact VIA with a decent measurement rate (192 frequency points per second) aims, in the next development steps, to create an accurate impedance analyzer for QCM sensors. The experimental results show the good working capacity of QCMI based on VIA.

Advanced Impedance Spectroscopy for QCM Sensor in Liquid Medium.

Technological evolution has allowed impedance analysis to become a versatile and efficient method for the precise measurement of the equivalent electrical parameters of the quartz crystal microbalance (QCM). By measuring the dissipation factor, or another equivalent electrical parameter, the QCM sensor provides access to the sample mass per unit area and its physical parameters, thus ensuring a detailed analysis. This paper aims to demonstrate the benefits of advanced impedance spectroscopy concerning the Butterworth-van Dyke (BVD) model for QCM sensors immersed with an electrode in a liquid medium. The support instrument in this study is a fast and accurate software-defined virtual impedance analyzer (VIA) with real-time computing capabilities of the QCM sensor's electric model. Advanced software methods of self-calibration, real-time compensation, innovative post-compensation, and simultaneous calculation by several methods are the experimental resources of the results presented in this paper. The experimental results validate the theoretical concepts and demonstrate both the capabilities of VIA as an instrument and the significant improvements brought by the advanced software methods of impedance spectroscopy analysis related to the BVD model.

Segmented bimorph mirrors for adaptive optics: segment design and experiment.

We discuss the concept of lightweight segmented bimorph mirrors for adaptive optics. The segment consists of a monocrystal silicon substrate actuated by an array of in-plane piezoceramic (PZT) actuators with honeycomb electrodes. We focus on technological aspects of the segment design that are critical for space applications and describe a single segment demonstrator. The morphing capability of the segment is evaluated experimentally. We also discuss the local deformations (dimples) associated with the shape of the electrodes acting on the PZT array.

Virtual Quartz Crystal Microbalance: Bioinspired Resonant Frequency Tracking.

The reference acoustic properties of the quartz crystal used as a resonator are ensured by its high-quality factor (Q-factor). The microbalance of the quartz crystal (QCM) exploits the bulk acoustic properties of the quartz crystal. Turning a network analyzer or impedance analyzer into a QCM with a decent measurement rate is a challenge. The use of a virtual instrument to implement an impedance analyzer (VIA) provides greater flexibility to the virtual QCM. In this paper, VIA's flexibility is exploited for the experimental evaluation of conventional scanning procedures and the influence of associated parameters, in order to identify elements that can lead to a limitation of the performance of a virtual QCM. The results of the experimental investigation justify the use of an innovative and optimized bioinspired scanning procedure to effectively track the serial resonance frequency of the QCM sensor. Variable-resolution spatial sampling of the human retina and the ability of the eye to refocus on the area of interest is the source of bioinspiration for achieving an adaptive virtual QCM. The design methodology and physics are described in detail, and the experimental investigations demonstrate the effectiveness of the proposed bioinspired scanning procedure.

Note: sensitivity multiplication module for quartz crystal microbalance applications.

In this Note, a novel sensitivity multiplication module was added to classical quartz crystal microbalance (QCM). The purpose is to increase QCM frequency shift without changing nominal frequency of the quartz crystal resonator or nominal frequency value delivered to the frequency counter. Allan deviance measurement confirms that the multiplication of the frequency shift is limited by the quartz crystal loads with direct effect in quartz crystal quality factor and oscillator stability. An experimental implementation of this new sensitivity multiplication module that can increase up to six times the frequency shift of the QCM was experimentally investigated using different load conditions.

Quartz crystal microbalance based on passive frequency to voltage converter.

In dynamics of evaporation or drying of microdrops from a solid surface, a faster and precise quartz crystal microbalance (QCM) is needed. The fast QCM based on frequency to voltage converter is an attractive and powerful tool in the investigation of the dynamic regime of evaporation to translate the frequency shift in terms of a continuous voltage change. The frequency shift monitoring in fast QCM applications is a real challenge for electronic processing interface. Originally developed as a frequency shift processing interface, this novel passive frequency to voltage converter can produce faster, stable, and accurate results in regard to the QCM sensor behavior. In this article, the concept and circuit of passive frequency to voltage converter will be explained followed by static and dynamic characterization. Experimental results of microdrops evaporation will be given.