Regulation of Ocean Surface Currents and Seasonal Sea Ice Variations on the Occurrence and Transport of Organophosphate Esters in the Central Arctic Ocean.

Organophosphate esters (OPEs) have been observed in the remote Arctic Ocean, yet the influence of hydrodynamics and seasonal sea ice variations on the occurrence and transport of waterborne OPEs remains unclear. This study comprehensively examines OPEs in surface seawater of the central Arctic Ocean during the summer of 2020, integrating surface ocean current and sea ice concentration data. The results confirm significant spatiotemporal variations of the OPEs, with the total concentration of seven major OPEs averaging 780 ± 970 pg/L. Chlorinated OPEs, particularly tris(1-chloro-2-propyl) phosphate (TCPP), were dominant. The significant impact of hydrodynamics on the OPE transport is demonstrated by higher OPE concentrations in regions with strong surface currents, especially at the edge of the Beaufort Gyre and the confluence of the Beaufort Gyre and the Transpolar Drift. Furthermore, OPE levels were generally higher in drifting-ice-covered regions compared to ice-free regions, attributed to the volatilization of dissolved OPEs formerly trapped below the sea ice or newly released from melting snow and sea ice. Notably, TCPP decreased by only 19% in the ice-free area, while the more volatile triphenyl phosphate decreased by 63% compared with the partial ice region.

Pollution of organophosphorus pesticides in the Dongting Lake, China and its relationship with dissolved organic matter: Occurrence, source identification and risk assessment.

The escalating global demand for food and industrialization has placed significant pressure on the integrity and management of inland lake ecosystems. Herein, the organophosphorus pesticides (OPPs) pollution status and their relationship with dissolved organic matter (DOM) in Dongting Lake were investigated to identify the ecological risks and potential sources of OPPs. The total concentrations of 18 detected OPPs were in the range of 13.49-375.24 ng/L, with higher concentration observed in east and west lake regions. Among these, fenthion was the dominant contributor, accounting for 64% of total OPPs, posing significant ecological risk to aquatic organisms. Nearly all of sites showed high combined risk of total OPPs. Parallel factor analysis (PARAFAC) and fluorescence regional integration (FRI) technique showed that DOM was mainly composed of terrestrial humic-like and tryptophan-like substances. Moreover, correlation analysis revealed a close association between DOM optical parameters and OPP concentrations. Specifically, OPPs exhibited a significantly positive correlation with tyrosine-like substances, while displaying a negative correlation with fulvic acid-like substances. These results indicated that OPP concentrations may decrease with increasing humification levels and declining tyrosine-like substance contents. This study underscores the critical role of DOM in assessing the occurrence and sources of OPPs in aquatic environments, providing valuable insights for effective environmental management strategies.

Occurrence, multiphase partition and risk assessment of organic amine pesticides in drinking water source of Xiang River, China.

The extensive use of organic amine pesticides (OAPs) in agricultural practices has resulted in the contamination of water environments, posing threats to ecosystems and human health. This study focused on the Xiang River (XR), a representative drinking water source, as the research area to investigate the occurrence characteristics of 34 OAPs. Diphenylamine emerged as the most prevalent OAP in surface water due to industrial and agricultural activities, while cycloate dominated in sediments due to cumulative effects. Generally, the concentration of OAPs in a mixed tap water sample was lower than those in surface water samples, indicating OAPs can be removed by water plants to a certain extent. The water-sediment distribution coefficients (kd) of ΣOAPs were much less than 1 L/g, the majority of OAPs maintained relatively high concentrations in water samples instead of accumulating in sediments. Furthermore, risk assessment revealed that carbofuran showed a moderate risk to the aquatic environment, with a risk quotient of 0.23, while other OAPs presented minor risks. This study provided crucial insights for regional pesticide management and control in the XR basin, emphasizing the importance of implementing strategies to minimize the release of OAPs into the environment and protect human health.

Chemodynamics of Polycyclic Aromatic Hydrocarbons and Their Alkylated and Nitrated Derivatives in the Yellow Sea and East China Sea.

The occurrence of continuously released polycyclic aromatic hydrocarbons (PAHs) in marginal seas is regulated by hydrological and biogeochemical processes; however, scarce knowledge is about their derivatives in marine environments. In this study, the dissolved and particulate PAHs and their alkylated/nitrated derivatives (A-PAHs/N-PAHs) in surface seawater of the southwestern Yellow Sea (YS) and northwestern East China Sea (ECS) during September 2022 were comprehensively discussed. Results confirm higher levels of Σ26PAHs (9.3-70 ng/L) and Σ43A-PAHs (13-76 ng/L) than Σ20N-PAHs (0.80-6.6 ng/L). The spatial heterogeneity of contaminants was regulated by substantial riverine runoff and ocean currents. Lagrangian Coherent Structure analysis further revealed the existence of a transport barrier at the shelf break of the southwestern YS where contaminants hardly crossed and tended to accumulate. The relationship between dissolved compounds and chlorophyll a indicated both biodegradation and the biological pump contributed to the depletion of PAHs and A-PAHs from surface seawater while the biological pump was the major driver for N-PAHs, despite their complicated water-particle partition behavior due to variations in physicochemical properties in the presence of nitro groups. Source identification demonstrated that pyrogenic and petrogenic sources dominated the YS and ECS, respectively, while photochemical transformations appeared more active in the YS.

Occurrence, sources, and risk assessment of pyrethroid insecticides in surface water and tap water from Taihu Lake, China.

Pyrethroid insecticides are one of the most widely used insecticides globally, posing a severe threat to human health and the environment. In this study, we applied high-throughput organic analysis testing combined with high-volume solid-phase extraction (Hi-throat/Hi-volume SPE) to elucidate the occurrence of 11 pyrethroid insecticides in lake water (n = 37), tributary river water (n = 15), and tap water (n = 6) in the Taihu Lake Basin. Permethrin was found to be the major contributing pyrethroid insecticide (detection rate = 100%). The concentrations of pyrethroid insecticides from different lake regions were revealed in the following descending order: southern > eastern > western > northern. The principal component analysis and multiple linear regression demonstrated that landscape maintenance, agricultural cultivation, and livestock breeding were the main sources of pyrethroid insecticides in the Taihu Lake surface water. Moreover, runoff input plays an important role in their accumulation, while the surrounding rivers contribute 2292 kg of pyrethroid insecticides to Taihu Lake annually. The risk assessment analysis demonstrated that pyrethroid insecticides pose a high risk to both the ecological environment and the surrounding human populations, thereby necessitating effective countermeasures. Furthermore, the pyrethroid insecticides in the Yangtze River Delta region have to be controlled. Overall, this is the first study focused on China that revealed the residue levels in water sources and tap water.

Polycyclic Aromatic Hydrocarbons in the Marine Atmosphere from the Western Pacific to the Southern Ocean: Spatial Variability, Gas/Particle Partitioning, and Source Apportionment.

The spatial variability of polycyclic aromatic hydrocarbons (PAHs) in the marine atmosphere contributes to the understanding of the global sources, fate, and impact of this contaminant. Few studies conducted to measure PAHs in the oceanic atmosphere have covered a large scale, especially in the Southern Ocean. In this study, high-volume air samples were taken along a cross-section from China to Antarctica and analyzed for gaseous and particulate PAHs. The data revealed the spatial distribution, gas-particle partitioning, and source contributions of PAHs in the Pacific, Indian, and Southern Oceans. The median concentration (gaseous + particulate) of ∑24PAHs was 3900 pg/m3 in the Pacific Ocean, 2000 pg/m3 in the Indian Ocean, and 1200 pg/m3 in the Southern Ocean. A clear latitudinal gradient was observed for airborne PAHs from the western Pacific to the Southern Ocean. Back trajectories (BTs) analysis showed that air masses predominantly originated from populated land had significantly higher concentrations of PAHs than those from the oceans or Antarctic continents/islands. The air mass origins and temperature have significant influences on the gas-particle partitioning of PAHs. Source analysis by positive matrix factorization (PMF) showed that the highest contribution to PAHs was from coal combustion emissions (52%), followed by engine combustion emissions (27%) and wood combustion emissions (21%). A higher contribution of PAHs from wood combustion was found in the eastern coastal region of Australia. In contrast, engine combustion emissions primarily influenced the sites in Southeast Asia.

Application of Hi-throat/Hi-volume SPE technique in assessing organophosphorus pesticides and their degradation products in surface water from Tai Lake, east China.

Organophosphorus pesticides (OPPs) are among the most commonly used pesticides worldwide. However, these compounds pose a serious threat to aquatic environments. Here, thirty-seven pesticides and eight degradation products were determined in surface water samples from Tai Lake, East China, using a high-volume solid phase extraction technique (Hi-throat/Hi-volume SPE). Surface water was pumped in-situ through a portable sampler, and OPPs in the water retained on the Hi-volume SPE adsorption column, finally extracted for analysis. This technique efficiently reduced the detection limits to below 0.3 ng/L. In total, 40 out of 45 OPP congeners were detected, which far exceeded the amount of OPPs in previous studies. The total concentration of OPPs ranged between 101.4 and 1530 ng/L (median: 378.9 ng/L). Parathion exhibited the highest concentration (median: 112.0 ng/L), followed by paraoxon-methyl (median: 90.3 ng/L), as well as carbophenothion, fenthion, and mevinphos. Agricultural areas were more polluted than residential and industrial regions. However, degradation products persisted in residential and industrial waters. The ecological risks of OPPs in these areas were estimated based on the risk quotient index (RQ). Parathion, fenthion, carbophenothion, and tolclofos-methyl occurred at high-risk levels, and the levels of degradation products were also non-trivial. Our findings thus indicated that OPP degradation products pose a potential threat to natural environments and should therefore be closely monitored.

Application of Hi-throat/Hi-volume SPE technique in analyzing occurrence, influencing factors and human health risk of organophosphate esters (OPEs) in drinking water of China.

Organophosphate esters (OPEs) are typical industrial additives widely applied in various industrial and household products, but they may pollute drinking water. In the present study, the occurrence of OPEs in drinking water was analyzed. For this purpose, 25 drinking water samples were collected from households in 25 cities in China. The concentrations of OPEs were accurately determined according to a high-throughput organic analysis testing combined with high-volume solid phase extraction (Hi-throat/Hi-volume SPE) technique. Through this technique, nine OPEs were detected, with spiked recoveries from 77% to 101%, and their total concentrations (ΣOPEs) ranging from 46.8 to 251 (average 126) ng L-1. The detection frequencies of the selected OPEs determined via Hi-throat/Hi-volume SPE were 88.0%-100%, which are much higher than those previously reported. The limit of detections of the OPEs was low at < 0.01 ng L-1, which could be mainly attributed to the high volume of accumulated drinking water (>20 L). OPEs in drinking water presented a decreasing trend from cities in coastal provinces to inland cities of China. Redundancy analysis showed that the concentrations of OPEs in drinking water were significantly influenced by economic-demographic influencing factors. The non-carcinogenic and lifetime carcinogenic risks (non-CR and CR) of the analyzed OPEs in drinking water were negligible for urban residents in China.

Sources apportionment and carcinogenic risk of polycyclic aromatic hydrocarbons in gas phase of urban Shanghai: Based on high volume solid phase extraction (Hi-volume SPE).

Polycyclic aromatic hydrocarbons (PAHs) are ubiquitous environmental pollutants, posing potentially serious threats to human health. This study analyzed compositional characteristics, sources, and carcinogenic risks of PAHs in the atmospheric gas phase at an urban site in Shanghai, East China. Seventy-four gas phase samples were collected during the warm months of May-October 2018 using a high-volume solid phase extraction (Hi-volume SPE) technique. The total concentration of sixteen priority PAHs (ΣPAHs) was in the range of 5.54-182.05 ng m-3 (average 34.47 ng m-3) and the total of seven carcinogenic PAHs (ΣCPAHs) was in range of 0.03-1.49 ng m-3 (average 0.48 ng m-3), accounting for 1.47% of ΣPAHs and indicating low carcinogenic potential. Redundancy analyses indicated positive correlations between ΣPAHs and air quality, and ΣCPAHs and average high temperature, and a negative correlation between ΣPAHs and wind speed. Four possible sources, namely petroleum and petrogenic sources, traffic emissions, coal combustion, and mixed gasoline and coal combustion sources, were identified by positive matrix factorization (PMF), accounting for 62.84%, 19.31%, 10.15%, and 7.69% of ΣPAHs, respectively. The overall lifetime lung cancer risk (LLCR) through inhalation of PAHs was estimated to be at a low risk level of 1.61 × 10-5. The LLCR based on PMF apportionment decreased in the order of mixed gasoline and coal combustion sources (47.07%) > traffic emissions (35.10%) > petroleum and petrogenic sources (11.06%) > coal combustion (6.74%). This study demonstrates the effectiveness of Hi-volume SPE in collecting and analyzing atmospheric gas phase PAHs.

Fate of Polycyclic Aromatic Hydrocarbons in Seawater from the Western Pacific to the Southern Ocean (17.5°N to 69.2°S) and Their Inventories on the Antarctic Shelf.

Semivolatile organic compounds such as polycyclic aromatic hydrocarbons (PAHs) have the potential to reach pristine environments through long-range transport. To investigate the long-range transport of the PAHs and their fate in Antarctic seawater, dissolved PAHs in the surface waters from the western Pacific to the Southern Ocean (17.5°N to 69.2°S), as well as down to 3500 m PAH profiles in Prydz Bay and the adjacent Southern Ocean, were observed during the 27th Chinese National Antarctic Research Expedition in 2010. The concentrations of Σ9PAH in the surface seawater ranged from not detected (ND) to 21 ng L(-1), with a mean of 4.3 ng L(-1); and three-ring PAHs were the most abundant compounds. Samples close to the Australian mainland displayed the highest levels across the cruise. PAHs originated mainly from pyrogenic sources, such as grass, wood, and coal combustion. Vertical profiles of PAHs in Prydz Bay showed a maximum at a depth of 50 m and less variance with depth. In general, we inferred that the water masses as well as the phytoplankton were possible influencing factors on PAH surface-enrichment depth-depletion distribution. Inventory estimation highlighted the contribution of intermediate and deep seawater on storing PAHs in seawater from Prydz Bay, and suggested that climate change rarely shows the rapid release of the PAHs currently stored in the major reservoirs (intermediate and deep seawater).

Untargeted Screening and Distribution of Organo-Iodine Compounds in Sediments from Lake Michigan and the Arctic Ocean.

The majority of halogenated organic compounds present in the environment remain unidentified. To address this data gap, we recently developed an untargeted method (data-independent precursor isolation and characteristic fragment; DIPIC-Frag) for identification of unknown organo-bromine compounds. In this study, the method was adapted to enable untargeted screening of natural and synthetic organo-iodine compounds (NSOICs) in sediments. A total of 4,238 NSOIC peaks were detected in sediments from Lake Michigan. Precursor ions and formulas were determined for 2,991 (71%) of the NSOIC peaks. These compounds exhibited variations in abundances (<10(3) to ∼10(7)), m/z values (206.9304-996.9474), retention times (1.0-29.7 min), and number of iodine atoms (1-4). Hierarchical cluster analysis showed that sediments in closer proximity exhibited similar profiles of NSOICs. NSOICs were screened in 10 samples of sediment from the Arctic Ocean to compare the profiles of NSOICs between freshwater and marine sediments. A total of 3,168 NSOIC peaks were detected, and profiles of NSOICs in marine sediments were clearly distinct from Lake Michigan. The coexistence of brominated and iodinated analogues indicated that some NSOICs are of natural origin. Different ratios of abundances of iodinated compounds to brominated analogues were observed and proposed as a marker to distinguish sources of NSOICs.

Occurrence, sources and transport of triazine herbicides in the Antarctic marginal seas.

The extensively applied triazine herbicides are easily transported by ocean currents over long distances. This study analyzed ten triazine herbicides in the Antarctic marginal seas and the Southern Indian Ocean during the austral summer for the first time, addressing their largely unexplored behavior in remote marine environments. The total triazine herbicides showed great spatial heterogeneity, with a range of 20-790 pg/L and an average of 31 ± 66 pg/L. The waterborne transport of triazine herbicides in the Antarctic was affected by hydrological processes, especially the blocking and accumulation effect of the polar front. Variations in sea ice extent and temperature were also important influencing factors, resulting in elevated triazine herbicides in surface seawater of East Antarctica, but reduced levels in West Antarctica. Furthermore, the source apportionment results indicated that approximately 55 % of the herbicides originated from sugarcane cultivation, 28 % from algaecide use, and 16 % from corn and sorghum farming.

Spatial distribution and risk assessment of pyrethroid insecticides in surface waters of East China Sea estuaries.

Pyrethroid insecticides are the most commonly used household insecticides and pose substantial risks to marine aquatic organisms. many studies have detected pyrethroid insecticides in the waters and estuaries of the western United States, but their distributions within western Pacific estuaries have not been reported. Accordingly, we used high-throughput organic analyses combined with high volume solid-phase extraction to comprehensively assess 13 pyrethroid insecticides in East China Sea estuaries and the Huangpu River. The results demonstrated the presence of various ∑13pyrethroid insecticides in East China Sea estuaries (mean and median values of 8.45 ± 5.57 and 7.78 ng L-1, respectively), among which cypermethrin was the primary contaminant. The concentrations of ∑12pyrethroid insecticide detected in the surface waters at the Huangpu River (mean 6.7 ng L-1, outlet 16.4 ng L-1) were higher than those in the Shanghai estuary (4.7 ng L-1), suggesting that runoff from inland areas is a notable source of insecticides. Wetlands reduced the amount of runoff containing pyrethroid insecticides that reached the ocean. Several factors influenced pesticide distributions in East China Sea estuaries, and higher proportions were derived from agricultural sources than from urban sources, with a higher proportion of agricultural sources than urban sources, influenced by anthropogenic use in the region. Permethrin and cypermethrin were the main compounds contributing to the high ecological risk in the estuaries. Consequently, to prevent risks to marine aquatic life, policymakers should aim to reduce insecticide contaminants derived from urban and agricultural sources.

Distribution, sources, and eco-risk of Current-Use Pesticides (CUPs) in the coastal waters of the northern Shandong Peninsula, China.

This study investigated the spatial distributions and seasonal variations of 19 CUPs in the coastal areas of the Shandong Peninsula and its surrounding rivers and assessed their ecological risk. In freshwater and seawater, insecticides (chlorpyrifos, methoxychlor, and pyridaben), as well as fungicides (fenarimol) and herbicides (dichlobenil) were the main pollutants (Detection Frequency: 100 %). Spatially, during winter, the regional pollution levels of Σ19CUPs in seawater showed a trend of Laizhou Bay (LZB, mean:4.13 ng L-1) > Yellow River Estuary (YRE, mean:2.57 ngL-1) > Bohai Bay (BHB, mean:2.21 ng L-1) > Yanwei Area (YWA, mean:1.94 ng L-1). The similarities of major substances between rivers and the marine environment suggest that river discharge is the main source of CUPs pollution in coastal areas. In summer, CUPs in rivers posed a high risk. In winter, the risk significantly decreased, indicating a moderate overall risk. Seawater exhibited a low risk in winter.

Exploring global oceanic persistence and ecological effects of legacy persistent organic pollutants across five decades.

Global monitoring of persistent organic pollutants (POPs) has intensified following regulatory efforts aimed at reducing their release. In this context, we compiled over 10,000 POP measurements, reported from 1980 to 2023, to assess the effectiveness of these legislative measures in the global marine environments. While a general decreasing trend in legacy POP concentrations is evident across various maritime regions, highlighting the success of source control measures, the Arctic Ocean and its marginal seas have experienced a rise in POP levels. This increase suggests the northward migration of pollutants via ocean currents from mid-latitude regions to polar areas. Despite global efforts to reduce emissions, the continued transport and accumulation of pollutants to the Arctic regions may have substantial ecological impacts. Addressing these environmental challenges demands a thorough understanding of POP dynamics, including response times, multiphase transport, and biogeochemical cycling. Continued research into these processes is vital to accurately map their distribution and temporal variations within marine systems.

Levels and distribution of trace metals in surface sediments from Kongsfjorden, Svalbard, Norwegian Arctic.

Trace metal contents (Cd, Co, Cr, Cu, Hg, Mn, Ni, Pb and Zn) have been measured in 27 surface sediment samples collected from Kongsfjorden, Svalbard, Norwegian Arctic. The analyses yielded concentration values (in mg kg(-1)) of 0.13-0.63 for Cd, 11.89-21.90 for Co, 48.65-81.84 for Cr, 21.26-36.60 for Cu, 299.59-683.48 for Mn, 22.43-35.39 for Ni, 10.68-36.59 for Pb, 50.28-199.07 for Zn and 8.09-65.34 for Hg (in ng g(-1)), respectively. Relative cumulative frequency method has been used to define the baseline values of these metals, which (in mg kg(-1)) were 0.14 for Cd, 13.56 for Co, 57.86 for Cr, 25.14 for Cu, 364.08 for Mn, 26.22 for Ni, 17.46 for Pb, 70.49 for Zn and 9.76 for Hg (in ng g(-1)), respectively. The enrichment factor analysis indicated that Hg showed some extent of anthropogenic pollution, while Pb, Zn and Cd showed limited anthropogenic contamination in the study areas.

Denaturing gradient gel electrophoresis fingerprinting of soil bacteria in the vicinity of the Chinese Great Wall Station, King George Island, Antarctica.

Bacterial diversity was investigated in soil samples collected from 13 sites around the Great Wall Station, Fildes Peninsula, King George Island, Antarctica, using denaturing gradient gel electrophoresis (DGGE) of 16S rRNA genes. The classes alpha-, beta-, and gamma-Proteobacteria, as well as the phylum Actinobacteria, were found to be the dominant bacteria in the soils around the Great Wall Station. Although the selected samples were not contaminated by oil, a relationship between soil parameters, microbial biodiversity, and human impact was still seen. Sample sites in human impacted areas showed lower bacterial biodiversity (average H' = 2.65) when compared to non-impacted sites (average H' = 3.05). There was no statistically significant correlation between soil bacterial diversity and total organic carbon (TOC), total nitrogen, or total phosphorus contents of the soil. Canonical correlation analysis showed that TOC content was the most important factor determining bacterial community profiles among the measured soil parameters. In conclusion, microbial biodiversity and community characteristics within relatively small scales (1.5 km) were determined as a function of local environment parameters and anthropogenic impact.

Spatial assessment of triazole organic compounds in surface water from the coastal estuaries to the East China sea.

Triazole is widely used in the synthesis of pharmaceuticals, pesticides, and fungicides. However, triazole organic compounds are often a source of toxicity in the water environment due to the presence of chlorobenzene. This study reported on the occurrence and distribution of 15 TrOCs in the surface waters of estuaries and the East China sea, and identified the influences of TrOCs originating from the estuarine environment on the ocean. The results showed that the total concentrations of ∑TrOCs in the surface water of estuaries along the coasts of Jiangsu (JS), Zhejiang (ZJ), and Shanghai (SH), China ranged from 0.020 to 104 ng L-1 (7.49 ± 18.2 ng L-1), whereas they ranged from 0.235 to 1.25 ng L-1 (mean 0.711 ± 0.235 ng L-1) in the East China sea. Difenoconazole and tebuconazole were the dominant TrOCs in the estuaries, whereas fenbuconazole and hexaconazole dominated in the ocean. TrOCs in surface water of estuaries showed a continuous spatial distribution and presented regional characteristics mainly related to agricultural activities. In contrast, TrOCs in the East China Sea showed a low spatial variation and dispersion, which may be related to complex disturbance by currents and dilution. The low levels of estuarine TrOCs measured in SH estuaries (<0.5 ng L-1) indicates that the Yangtze River may only pose a low-level TrOC contamination risk to the East China Sea. Moreover, estuary transport in the estuaries of ZJ may have influenced the occurrence of TrOCs in the offshore East China Sea area, although they may have also undergone a filter process in the estuary turbid zone; whereas it had little influence on the open sea. This study can act as a critical reference for the presence of TrOCs in surface water both estuaries and the ocean.

Dissolved legacy and emerging organochlorine pesticides in the Antarctic marginal seas: Occurrence, sources and transport.

Polar regions are recognized as final sinks of the persistent contaminants, however, environmental investigations in the Antarctica are greatly limited by harsh field conditions. In this study, seawater samples were collected in the Antarctic marginal seas during the austral summer of 2021 to investigate the environmental behavior and fate of organochlorine pesticides (OCPs). The concentrations and source markers of representative legacy hexachlorocyclohexane (HCH), hexachlorobenzene (HCB) and dichlorodiphenyltrichloroethanes (DDTs) indicated the coexistent sources of historical residues and fresh inputs. While the emerging OCPs, including quintozene, pentachloroaniline and dichlobenil, showed relatively lower detection frequency. Due to the differences in temperature and sea ice coverage, dissolved OCPs generally displayed higher concentrations in the eastern Antarctic than those in the western Antarctic. The 'surface depleted and depth enrichment' vertical profile of representative OCPs in the continental shelf of Prydz Bay was jointly controlled by biological pump and water mass structure.

Organophosphorus pesticides in southeastern China marginal seas: Land-based export and ocean currents redistribution.

Organophosphorus pesticides (OPPs) have raised an increasing public concern due to their harmful impacts. To explore the occurrence and distribution of OPPs in southeastern China marginal seas (SCMS), a sampling campaign was carried out from East China Sea (ECS) to South China Sea (SCS). A total of 33 OPPs are quantified with the ΣOPPs concentrations ranging from 4.73 to 14.15 ng/L. Higher ΣOPPs concentrations in the surface seawater from the estuaries of Yangtze River, Minjiang River, and Pearl River than those at other sampling sites indicates that riverine emissions are the principal sources of OPPs in SCMS. Different compositions of OPPs in ECS and SCS highlight the different priority of use categories for OPPs in China coastal region. In addition, the vertical diffusion and upwelling ocean currents play critical roles in the redistribution of OPPs in SCMS. For the first time, the ΣOPPs mass inventories in surface seawater of ECS and SCS are estimated at 8.51 and 11.26 t, respectively. Although the current ecological risk of OPPs is at low level in surface seawater of SCMS, the long-term use and bio-accumulative potential point to the necessity for the normalized monitoring of OPPs in China.