RESUMO
The surface characteristics of stimuli-responsive Pickering emulsifiers can be modified by external environmental triggers, making them highly versatile in various applications. In this study, we report three novel organic-inorganic composite structure emulsifiers. These emulsifiers were designed with a core of magnetic Fe3O4 particles, surrounded by a protective silica layer, and coated on the exterior with three distinct types of modified chitosan (CS). Experimental results demonstrate that these emulsifiers can stabilize emulsion systems consisting of liquid paraffin and deionized water at a concentration of 0.5 wt%. The unique properties of the modified CS coatings allowed for the controlled demulsification of two types of emulsions by adjusting the proton concentration. Additionally, these emulsifiers exhibited magnetic-responsive demulsification under the control of an external magnetic field. The findings of this study provide valuable insights into the design and construction of multi-responsive chitosan-based magnetic Pickering emulsifiers with controllable properties.
RESUMO
In recent years, Pickering emulsifiers have been widely used in various production fields due to their excellent structural stability, biocompatibility and environmental friendliness. For some applications, it is required that the emulsifier can quickly respond to environmental stimuli and control the transition between stable and unstable emulsions. In this paper, we report a novel composite Pickering emulsifier with Fe3O4 as the core and magnetic response recognition body, silica as the intermediate protective layer, and chitosan (CS) of different molecular weights to endow solid particles with surface activity and pH-responsive properties. This emulsifier can stabilize the emulsion in the emulsion system with deionized water as the aqueous phase and liquid paraffin as the oil phase and can control the demulsification of the formed emulsion under the dual pH/magnetic stimulation. The experimental results show that Fe3O4@SiO2@CS has good paramagnetism and pH responsiveness. The particle size of the composite emulsifier nanoparticles is between 90 nm and 120 nm, and the best stabilizing effect of the emulsion is achieved when the dosage is 0.5 wt%. In the pH range of 3-11, the emulsifier can rapidly demulsify a stable paraffin oil-water emulsion system under the action of a magnetic field of strength 0.4 T. The pH response of the emulsifier is as follows: when pH ≤ 2, the system can form a stable emulsion, which is composed of fully protonated chitosan as a free chain segment and Fe3O4@SiO2. Emulsion stabilization was achieved with monolithic Fe3O4@SiO2@CS as an emulsifier at pH > 2, and demulsification was achieved at pH ≈ pKb (CS) at 298 K. The research in this paper can provide a feasible idea and synthesis method for the preparation of organic-inorganic composite structure emulsifier.
RESUMO
Conventional polyamide (PA) nanofiltration (NF) membranes can readily adsorb aromatic compounds, such as endocrine disrupting compounds (EDCs). Therefore, these substances can easily be transported across the membrane by solution-diffusion, resulting in a poor EDC-rejection. In this work, a novel thin film nanocomposite (TFN) membrane was fabricated by incorporating covalent organic frameworks (COFs) into the PA layer via an interfacial polymerization reaction. COFs with functional groups can provide abundant active binding sites for highly efficient EDC-capture. The rejection of the optimal TFN-COF membrane for bisphenol A, bisphenol AF, and sodium 2-biphenylate was 98.3%, 99.1%, and 99.3%, respectively, which was much higher than of the rejection of the pristine NF-membrane (82.4%, 95.5%, and 96.4%, respectively). Additionally, the TFN-COF membrane could be regenerated fast and efficiently by washing with ethanol for some minutes. COF nanofillers with porous structures provide additional water channels, making it possible to overcome the permeability-selectivity trade-off of NF membranes. The water permeance (17.1 L m-2 h-1 bar-1) of the optimal membrane was about two times higher than for the pristine NF-membrane (8.7 L m-2 h-1 bar-1). In addition, the TFN-COF membrane with a COF-loading of 0.05% w/v had an excellent Na2SO4 rejection (95.2%) due to size exclusion and strong Donnan effect. This work combines traditional NF membranes and adsorption materials to achieve efficient capture and rapid release of EDCs without sacrificing salt rejections, which opens the door to develop fit-for-purpose adsorptive NF membranes.