Experimental investigation of Cd (II) ion adsorption on surface-modified mixed seaweed Biosorbent: A study on analytical interpretation and thermodynamics.

Despite advancements in wastewater treatment technologies, heavy metal contamination, especially cadmium (Cd), severely threatens human health and ecosystems. The purpose of this work is to compare the removal of Cd (II) ions from aqueous solutions by chemically modified mixed seaweed biosorbent (CMSB) and physically modified mixed seaweed biosorbent (PMSB). BET, SEM, EDAX, FTIR, and XRD techniques characterized the mixed seaweed biosorbents before and after adsorption. They are well-known for their sustainability, affordability, and biodegradability. The BET study revealed that CMSB had a surface area of 19.682 m2/g, while PMSB had a lower surface area of 14.803 m2/g. The optimum adsorption conditions were a temperature of 303 K, pH of 6.0, and biosorbent dosages of 1 g/L for CMSB and 2.5 g/L for PMSB. For CMSB and PMSB, the most efficient contact times were 40 and 80 min, respectively. The Langmuir model was demonstrated to be the best fit for the experimental data when compared to other isotherm models, with a coefficient of determination, or R2, of 0.9713 and a maximum monolayer capacity of 151.2 mg/g and 181.6 mg/g for physical and chemical activated mixed seaweed biomass. There was a significant relationship between the R2 values of chemically modified and physically modified biomass. The findings demonstrate that pseudo-second-order kinetics more accurately represent the adsorption process than pseudo-first-order and Elovich models. Thermodynamic experiments validated the endothermic, spontaneous and favourable characteristics of the removal process. According to the results of the current study, PMSB and CMSB may be used as effective adsorbents to remove Cd (II) from aqueous solutions.

Microorganism-mediated bioremediation of dyes from contaminated soil: Mechanisms, recent advances, and future perspectives.

Many methods have been proposed for the remediation of dye-contaminated soils, a widespread form of environment pollution. Bioremediation, it is hoped, can combine ecological benefits with efficiency of dye decontamination. We review the types and sources of dye contaminants; their possible effects on plant, animal, and human health; and emerging strategies for microbial bioremediation. Challenges, limitations, recommendations for future research, and prospects for large-scale commercialization of microbial bioremediation are discussed.

Current strategies on bioremediation of personal care products and detergents: Sustainability and life cycle assessment.

The increased use of personal care products and detergents in modern society has raised concerns about their potential adverse effects on the environment. These products contain various chemical compounds that can persist in water bodies, leading to water pollution and ecological disturbances. Bioremediation has emerged as a promising approach to address these challenges, utilizing the natural capabilities of microorganisms to degrade or remove these contaminants. This review examines the current strategies employed in the bioremediation of personal care products and detergents, with a specific focus on their sustainability and environmental impact. This bioremediation is essential for environmental rejuvenation, as it uses living organisms to detergents and other daily used products. Its distinctiveness stems from sustainable, nature-centric ways that provide eco-friendly solutions for pollution eradication and nurturing a healthy planet, all while avoiding copying. Explores the use of microbial consortia, enzyme-based treatments, and novel biotechnological approaches in the context of environmental remediation. Additionally, the ecological implications and long-term sustainability of these strategies are assessed. Understanding the strengths and limitations of these bioremediation techniques is essential for developing effective and environmentally friendly solutions to mitigate the impact of personal care products and detergents on ecosystems.

Agricultural waste biomass for sustainable bioenergy production: Feedstock, characterization and pre-treatment methodologies.

The worldwide trend in energy production is moving toward circular economy systems and sustainable availability of sources. Some advanced methods support the economic development of energy production by the utilization of waste biomass, while limiting ecological effects. The use of agro waste biomass is viewed as a major alternative energy source that expressively lowers greenhouse gas emissions. Agricultural residues produced as wastes after each step of agricultural production are used as sustainable biomass assets for bioenergy production. Nevertheless, agro waste biomass needs to go through a few cyclic changes, among which biomass pre-treatment contributes to the removal of lignin and has a significant role in the efficiency and yield of bioenergy production. As a result of rapid innovation in the utilization of agro waste for biomass-derived bioenergy, a comprehensive overview of the thrilling highlights and necessary advancements, in addition to a detailed analysis of feedstock, characterization, bioconversion, and contemporary pre-treatment procedures, appear to be vital. To this end, the current status in the generation of bioenergy from agro biomass through various pre-treatment procedures was examined in this study, along with presenting relevant challenges and a perspective for future investigations.

A comprehensive review on the biological conversion of lignocellulosic biomass into hydrogen: Pretreatment strategy, technology advances and perspectives.

The globe has dependent on energy generation and utilization for many years; conversely, ecological concerns constrained the world to view hydrogen as an alternative for economic development. Lignocellulosic biomass is broadly accessible as a low-cost renewable feedstock and nonreactive nature; it has received a lot of consideration as a global energy source and the most attractive alternative to replace fossil natural substances for energy production. Pretreatment of lignocellulosic biomass is essential to advance its fragmentation and lower the lignin content for sustainable energy generation. This review's goal is to provide the different pretreatment strategies for enlarging the solubility and surface area of lignocellulosic biomass. The biological conversion of lignocellulosic biomass to hydrogen was reviewed and operational conditions and enhancing methods were discussed. This review summarizes the working conditions, parameters, yield percentages, techno-economic analysis, challenges, and future recommendations on the direct conversion of biomass to hydrogen.

CO2 bio-mitigation using genetically modified algae and biofuel production towards a carbon net-zero society.

CO2 sequestration carried by biological methodologies shows enhanced potential and has the advantage that biomass produced from the captured CO2 can be used for different applications. Bio-mitigation of carbons through a micro-algal system addresses a promising and feasible option. This review mostly focused on the role of algae, particular mechanisms, bioreactors in algae cultivation, and genetically modified algae in CO2 fixation and energy generation systems. A combination of CO2 bio-mitigation and biofuel production might deliver an extremely promising alternative to current CO2 mitigation systems. Bio mitigation in which the excess carbon is captured and bio fixation which the carbon is captured by algae or autotrophs and used for producing biofuel. This review revealed that steps for biofuel production from algae include factors affecting, harvesting techniques, oil extraction and transesterification. This review helps environmentalists and researchers to assess the effect of algae-based biorefinery on the green environment.

A detailed review on advanced oxidation process in treatment of wastewater: Mechanism, challenges and future outlook.

The presence of several contaminants in waterbodies raises global pollution and creates major risks to mankind, wildlife, as well as other living organisms. Development of an effective, feasible, cost-effective and eco-friendly approach for treating wastewater that is discharged from various industries is important for bringing down the deposition of contaminants into environment. Advanced oxidation process is an efficient technique for treating wastewater owing to its advantages such as high oxidation efficacy and does not produce any secondary pollutants. Advanced oxidation process can be performed through various methods such as ozone, Fenton, electrochemical, photolysis, sonolysis, etc. These methods have been widely utilized for degradation of emerging pollutants that cannot be destroyed using conventional approaches. This review focuses on wastewater treatment using advanced oxidation process. A brief discussion on mechanism involved is provided. In addition, various types of advanced oxidation process and their mechanism are explained in detail. Challenges faced during wastewater treatment process using oxidation, electrochemical, Fenton, photocatalysis and sonolysis are discussed elaborately. Advanced oxidation process can be viewed as potential approach for treating wastewater with certain modifications and solving challenges.