Tuning the magnetic exchange via a control of orbital hybridization in Cr(2)(Te(1-x)W(x))O(6).

We report the complex magnetic phase diagram and electronic structure of Cr_{2}(Te_{1-x}W_{x})O_{6} systems. While compounds with different x values possess the same crystal structure, they display different magnetic structures below and above x_{c}=0.7, where both the transition temperature T_{N} and sublattice magnetization (M_{s}) reach a minimum. Unlike many known cases where magnetic interactions are controlled either by injection of charge carriers or by structural distortion induced via chemical doping, in the present case it is achieved by tuning the orbital hybridization between Cr 3d and O 2p orbitals through W 5d states. The result is supported by ab initio electronic structure calculations. Through this concept, we introduce a new approach to tune magnetic and electronic properties via chemical doping.

Successive magnetic phase transitions and multiferroicity in the spin-one triangular-lattice antiferromagnet Ba3NiNb2O9.

We report the magnetic and electric properties of Ba3NiNb2O9, which is a quasi-two-dimensional spin-one triangular-lattice antiferromagnet with trigonal structure. At low T and with increasing magnetic field, the system evolves from a 120 degree magnetic ordering phase (A phase) to an up-up-down (uud) phase (B phase) with a change of slope at 1/3 of the saturation magnetization, and then to an "oblique" phase (C phase). Accordingly, the ferroelectricity switches on at each phase boundary with appearance of spontaneous polarization. Therefore, Ba3NiNb2O9 is a unique triangular-lattice antiferromagnet exhibiting both uud phase and multiferroicity.

A suite-level review of the neutron powder diffraction instruments at Oak Ridge National Laboratory.

The suite of neutron powder diffractometers at Oak Ridge National Laboratory (ORNL) utilizes the distinct characteristics of the Spallation Neutron Source and High Flux Isotope Reactor to enable the measurements of powder samples over an unparalleled regime at a single laboratory. Full refinements over large Q ranges, total scattering methods, fast measurements under changing conditions, and a wide array of sample environments are available. This article provides a brief overview of each powder instrument at ORNL and details the complementarity across the suite. Future directions for the powder suite, including upgrades and new instruments, are also discussed.

Magnetism and multiferroicity of an isosceles triangular lattice antiferromagnet Sr3NiNb2O9.

Various experimental measurements were performed to complete the phase diagram of a weakly distorted triangular lattice system, Sr3NiNb2O9 with Ni(2+) , spin-1 magnetic ions. This compound possesses an isosceles triangular lattice with two shorter bonds and one longer bond. It shows a two-step magnetic phase transition at [Formula: see text] K and [Formula: see text] K at zero magnetic field, characteristic of an easy-axis anisotropy. In the magnetization curves, a series of magnetic phase transitions was observed such as an up-up-down phase at [Formula: see text] T with 1/3 of the saturation magnetization (M sat) and an oblique phase at [Formula: see text] T with [Formula: see text]/3 M sat. Intriguingly, the magnetic phase transition below T N2 is in tandem with the ferroelectricity, which demonstrates multiferroic behaviors. Moreover, the multiferroic phase persists in all magnetically ordered phases regardless of the spin structure. The comparison between the phase diagrams of Sr3NiNb2O9 and its sister compound with an equilateral triangular lattice antiferromagnet Ba3NiNb2O9 (Hwang et al 2012 Phys. Rev. Lett. 109 257205), illustrates how a small imbalance among exchange interactions change the magnetic ground states of the TLAFs.

Periodic lateralized epileptiform discharges in acquired immunodeficiency syndrome.

A patient with AIDS, who exhibited periodic lateralized epileptiform discharges, is described. The possible implications are discussed.