1.
Chemistry
; 20(32): 9910-3, 2014 Aug 04.
Artigo
em Inglês
| MEDLINE
| ID: mdl-25042733
RESUMO
Vicinal diamines constitute one the most important functional motif in organic chemistry because of its wide occurrence in a variety of biological and pharmaceutical molecules. We report an efficient metal-free, highly stereoselective intramolecular diamination using a novel chiral hypervalent iodine reagent together with its application as an efficient catalyst for the synthesis of diamines.