Recent Advances in Fluorescent Polyimides.

Polyimide (PI) refers to a type of high-performance polymer containing imide rings in the main chain, which has been widely used in fields of aerospace, microelectronic and photonic devices, gas separation technology, and so on. However, traditional aromatic PIs are, in general, the inefficient fluorescence or even no fluorescence, due to the strong inter- and intramolecular charge transfer (CT) interactions causing unavoidable fluorescence quenching, which greatly restricts their applications as light-emitting functional layers in the fabrication of organic light-emitting diode (OLED) devices. As such, the development of fluorescent PIs with high fluorescence quantum efficiency for their application fields in the OLED is an important research direction in the near future. In this review, we provide a comprehensive overview of fluorescent PIs as well as the methods to improve the fluorescence quantum efficiency of PIs. It is anticipated that this review will serve as a valuable reference and offer guidance for the design and development of fluorescent PIs with high fluorescence quantum efficiency, ultimately fostering further progress in OLED research.

Flexible optical tactile sensor based on a liquid-membrane lens structure.

Based on the liquid lens focus mechanism, a novel, to the best of our knowledge, optical tactile sensor is designed by taking advantage of the structure simplicity, fast response, and environmental immunity. The design of the tactile sensing mechanism used the liquid-membrane lens structure. To integrate the tactile sensing system, we designed a data acquisition circuit unit. A performance test platform was built, and performance testing and two application demonstrations were conducted. The experiment's result showed that the linear fitting degree was greater than 0.988, the load response time was 0.078 s, the target mass was accurately measured, the maximum error was less than 0.02 N, and the fine adjustment of the LED light intensity was achieved.

Implications of Withaferin A for the metastatic potential and drug resistance in hepatocellular carcinoma cells via Nrf2-mediated EMT and ferroptosis.

Hepatocellular carcinoma (HCC) constitutes a major global health threat due to the high incidence and mortality. Sorafenib is known as the first-line medication for advanced HCC; however, it only extends the limited benefit for HCC patients as the development of acquired resistance. Withaferin A exerts broad pharmaceutical applications in several cancers. However, its effects on HCC cell metastatic potential and sorafenib resistance remain elusive. Here, we corroborated that Withaferin A greatly restrained cell viability, invasion, vasculogenic mimicry (VM) formation, and VE-cadherin levels in HepG2 and SNU449 cells. Moreover, Withaferin A sensitized sorafenib (SR)-resistant HCC cells to sorafenib. In striking contrast to the parental cells, lower ferroptosis was observed in SR-resistant cells as the lower ROS, MDA, and higher intracellular GSH levels in SR-resistant cells. Of interest, Withaferin A enhanced ferroptosis in SR-resistant cells, which was reversed by ferroptosis antagonist liproxstation-1. Notably, Withaferin A elevated Keap1 expression to mitigate Nrf2 signaling activation-mediated epithelial to mesenchymal transition (EMT) and ferroptosis-related protein xCT expression. Importantly, blockage of the Keap1/Nrf2 signaling overturned Withaferin A-evoked ferroptosis and facilitated sorafenib resistance. In addition, knockdown of Keap1 antagonized the inhibitory efficacy of Withaferin A on HCC cell viability, invasion, and VM formation. Consequently, Withaferin A may attenuate the metastatic potential and sorafenib resistance by regulating Keap1/Nrf2-associated EMT and ferroptosis. Thus, Withaferin A may serve as a promising agent for HCC therapy, especially for advanced HCC.

Single medium-sized hepatocellular carcinoma treated with sequential conventional transarterial chemoembolization (cTACE) and microwave ablation at 4 weeks versus cTACE alone: a propensity score.

BACKGROUND: Microwave ablation (MWA) is a potentially curative treatment for unresectable patients with hepatocellular carcinoma (HCC) ≤ 3 cm, while its therapeutic efficacy decreases significantly for HCC > 3cm. Previous studies have demonstrated that conventional transarterial chemoembolization (cTACE) combined with MWA (cTACE-MWA) may improve local tumor control rate and reduce the recurrence rate for HCC > 3cm. However, there have been few study designs to analyze the clinical efficacy of cTACE-MWA for medium-sized HCC (3-5cm). Therefore, this study aims to compare the clinical efficacy and safety of cTACE-MWA with cTACE alone for a single medium-sized HCC of 3-5 cm in diameter. METHODS: We retrospectively investigate the data of 90 patients with a single medium-sized HCC who were referred to our hospital and underwent cTACE-MWA or cTACE alone from December 2017 to March 2020. Then, patients were identified with propensity score-matched (1:1). The local tumor response to treatment and time to progression (TTP) were compared using mRECIST criteria between the cTACE-MWA group and the cTACE group. RESULTS: A total of 42 patients were included after matching (cTACE-MWA: 21; cTACE: 21). Comparing with cTACE, cTACE-MWA demonstrate significantly better local tumor control (ORR: 95.2% vs 61.9%, p = 0.02; DCR: 95.2% vs 66.7%, p = 0.045) and TTP (median 19.8 months vs 6.8 months, p < 0.001). The 1- and 2-year cumulative probabilities of OS were 100% and 95% in the cTACE-MWA group, which were significantly higher than those in the cTACE group (95% and 76%) (p = 0.032). Multivariate Cox regression analysis illustrates that cTACE-MWA was associated with better TTP (hazard ratio, 0.28; 95% CI: 0.1, 0.76; p = 0.012), but tumor size was associated with worse TTP (hazard ratio, 1.71; 95% CI: 1.01, 2.89; p = 0.045). CONCLUSIONS: cTACE followed by MWA improved TTP and OS in patients with a single medium-sized HCC, and no major complication was observed in this study.

Semiconducting polymer nano-radiopharmaceutical for combined radio-photothermal therapy of pancreatic tumor.

BACKGROUND: Pancreatic ductal adenocarcinoma (PDAC) is a devastatingly malignant tumor with a high mortality. However, current strategies to treat PDAC generally have low efficacy and high side-effects, therefore, effective treatment against PDAC remains an urgent need. RESULTS: We report a semiconducting polymer nano-radiopharmaceutical with intrinsic photothermal capability and labeling with therapeutic radioisotope 177Lu (177Lu-SPN-GIP) for combined radio- and photothermal therapy of pancreatic tumor. 177Lu-SPN-GIP endowed good stability at physiological conditions, high cell uptake, and long retention time in tumor site. By virtue of combined radiotherapy (RT) and photothermal therapy (PTT), 177Lu-SPN-GIP exhibited enhanced therapeutic capability to kill cancer cells and xenograft tumor in living mice compared with RT or PTT alone. More importantly, 177Lu-SPN-GIP could suppress the growth of the tumor stem cells and reverse epithelial mesenchymal transition (EMT), which may greatly reduce the occurrence of metastasis. CONCLUSION: Such strategy we developed could improve therapeutic outcomes over traditional RT as it is able to ablate tumor with relatively lower doses of radiopharmaceuticals to reduce its side effects.

Four new species of Cortinariaceae (Agaricales) from Northwestern China.

Introduction: Cortinariaceae, which belongs to the Agaricales order, is a globally recognized family, known for its high species diversity. Methods: Eight internal transcribed spacer (ITS) and nuclear large ribosomal subunit (LSU) sequences were newly generated, and phylogenetic analyses were performed by combining ITS and LSU datasets. Four species were identified as forming four independent lineages with robust support in phylogenies based on both datasets. Results: These new species in the taxa, Cortinarius gansuensis, Cortinarius tricholomoidus, Cortinarius vinoso-griseum, and Phlegmacium subcalyptratum from Northwestern China are described and illustrated based on morphological and molecular evidence. Cortinarius gansuensis is characterized by a convex and brownish vinaceous pileus, generative hyphae with clamp connections, and ellipsoid basidiospores (8.5-10.6 µm × 5.4-6.8 µm); Cortinarius tricholomoidus is characterized by a broadly umbonate and snuff brown pileus, generative hyphae with clamp connections, and broadly ellipsoid to subglobose basidiospores (7.4-8.5 µm × 6.2-7.3 µm); Cortinarius vinoso-griseum is characterized by a violaceous gray pileus, generative hyphae with clamp connections, and smaller basidiospores (7.5-9.7 µm × 5.6-7.8 µm); and Phlegmacium subcalyptratum is characterized by a small and apricot-orange pileus, generative hyphae with clamp connections, and fusiform basidiospores (10.0-12.7 µm × 5.6-6.8 µm). Discussion: Full descriptions, illustrations, and results of phylogenetic analyses of the four species along with discussions on related species are provided.

A Nile red dye cathode with an asymmetric redox unit for lithium organic batteries.

A Nile red (NR) dye cathode with an asymmetric redox structure of para CN and CO bonds was developed for use in an efficient lithium organic battery with a good capacity of 125 mA h g-1 and two visible discharge/charge voltage plateaus (≈2.0 V and ≈1.7 V). The NR cathode demonstrated the advantages of employing cost-effective dyes to achieve multigradient voltage platform regulation.

YOLO-Faster: An efficient remote sensing object detection method based on AMFFN.

As a pivotal task within computer vision, object detection finds application across a diverse spectrum of industrial scenarios. The advent of deep learning technologies has significantly elevated the accuracy of object detectors designed for general-purpose applications. Nevertheless, in contrast to conventional terrestrial environments, remote sensing object detection scenarios pose formidable challenges, including intricate and diverse backgrounds, fluctuating object scales, and pronounced interference from background noise, rendering remote sensing object detection an enduringly demanding task. In addition, despite the superior detection performance of deep learning-based object detection networks compared to traditional counterparts, their substantial parameter and computational demands curtail their feasibility for deployment on mobile devices equipped with low-power processors. In response to the aforementioned challenges, this paper introduces an enhanced lightweight remote sensing object detection network, denoted as YOLO-Faster, built upon the foundation of YOLOv5. Firstly, the lightweight design and inference speed of the object detection network is augmented by incorporating the lightweight network as the foundational network within YOLOv5, satisfying the demand for real-time detection on mobile devices. Moreover, to tackle the issue of detecting objects of different scales in large and complex backgrounds, an adaptive multiscale feature fusion network is introduced, which dynamically adjusts the large receptive field to capture dependencies among objects of different scales, enabling better modeling of object detection scenarios in remote sensing scenes. At last, the robustness of the object detection network under background noise is enhanced through incorporating a decoupled detection head that separates the classification and regression processes of the detection network. The results obtained from the public remote sensing object detection dataset DOTA show that the proposed method has a mean average precision of 71.4% and a detection speed of 38 frames per second.

An electrospun three-layer nanofibrous membrane-based in situ gel separator for efficient lithium-organic batteries.

An in situ gel separator based on an electrospun three-layer nanofibrous membrane (PSE11-Gel) is developed for high-performance lithium-organic batteries (LOBs). The highly efficient shuttle effect inhibition of organic cathode molecules or lithiated intermediates has been demonstrated for PSE11-Gel to realize high-capacity stable LOBs.

HSP90AA1 is an unfavorable prognostic factor for hepatocellular carcinoma and contributes to tumorigenesis and chemotherapy resistance.

Hepatocellular carcinoma (HCC) is still one of the leading causes of tumor-related deaths. Accumulating evidence indicates that immunogenic cell death (ICD) could occur in tumor cells. However, ICD-related studies are limited in HCC. This study collected HCC RNA sequencing data from the Cancer Genome Atlas, International Cancer Genome Consortium, and Gene Expression Omnibus databases. R software was used to analyze the expression of ICD in HCC and to screen essential genes with prognostic value. qRT-PCR and WB determined the mRNA and protein expressions of hub gene. Cell viability assay, Clonal formation assay, and Live/dead staining assay were employed to determine the gene functions. After cross-analysis of differentially expressed genes (DEGs) and ICD-related genes (ICDRGs), 7 differentially expressed ICDRGs were identified in HCC. Of them, HSP90AA1, with the most excellent prognostic value in HCC, was selected, whose expression was also validated in public cohorts, cell lines, and clinical tissue samples. High HSP90AA1 expression indicated an inferior prognosis of HCC, and HSP90AA1 knockdown significantly suppressed cell viability and chemotherapy resistance of HCC. ICD-related gene HSP90AA1 was an unfavorable factor for HCC, and high HSP90AA1 expression contributed to tumor cell survival and chemotherapy resistance.

LARS1 is a Prognostic Biomarker and Exhibits a Correlation with Immune Infiltrates in Hepatocellular Carcinoma.

Purpose: To study the relationship between LARS1 expression and immune infiltration and prognosis in hepatocellular carcinoma (HCC). Patients and Methods: The clinical characteristics together with LARS1 expression levels were obtained from the TCGA database. Immunohistochemistry confirmed LARS1 expression levels in paraneoplastic and tumor tissues. To investigate LARS1-related downstream molecules, a network of protein-protein interactions (PPIs) and the Gene Ontology (GO)/Kyoto Encyclopedia of Genes and Genomes (KEGG) were built. Furthermore, gene set enrichment analysis (GSEA) was used to analyze the pathways associated with LARS1 expression, whereas Single-sample GSEA (ssGSEA) was applied to perform an association study between immune infiltration and LARS1 gene expression. The TISCH Database and the TISIDB database were used to compare the difference of LARS1 expression in hepatocellular carcinoma and immunomodulators. Results: In comparison to that in normal tissues, the LARS1 expression level was elevated in tumor tissues. LARS1 expression exhibited substantial correlation with AFP, Histologic grade, pathologic stage, Residual tumor, and Vascular invasion in HCC. Higher LARS1 expression in HCC was linked to lower progression-free survival (PFS), disease-specific survival (DSS), and overall survival (OS). According to the GO/KEGG study, the important biological process (neutral lipid metabolic process), cellular component (triglyceride-rich plasma lipoprotein), molecular functions (lipase inhibitor activity), and KEGG pathway (cholesterol metabolism) could be a probable function mechanism in promoting HCC. Various pathways as per GSEA revealed that they were enriched in samples with elevated LARS1 expression. The expression level of LARS1 in malignant tumor cells after immunotherapy was significantly higher than that before immunotherapy. LARS1 was also remarkably linked to the infiltration level and the immunomodulators. Conclusion: LARS1 can be used as a biomarker of HCC, which is associated to immune infiltration of HCC.

Fomitiporellacrystallina sp. nov. (Basidiomycota, Hymenochaetales) from China.

Background: Fomitiporella is an important genus of wood-decaying fungi. Many new species were revealed in the last five years, based on morphological characters and molecular data. During a study on the taxonomy of Fomitiporella, two specimens from China were investigated, which have morphological characteristics close to Fomitiporella. After morphological examinations and phylogenetic analyses, a new species was confirmed to be a member of the Fomitiporella clade. New information: Fomitiporellacrystallina sp. nov. is described and illustrated as a new species, based on morphological characters and molecular evidence. It has perennial, irregular, pileate basidiocarps, an indistinct subiculum (ultrathin to almost lacking), lack of any kind of setae, has brownish, thick-walled basidiospores and causes a white rot. A molecular study, based on the combined ITS (internal transcribed spacer region) and nrLSU (the large nuclear ribosomal RNA subunit) dataset, supports the new species in Fomitiporella. The differences between the new species and phylogenetically related and morphologically similar species are discussed. A key to species with pileate to effused-reflexed basidiocarps of Fomitiporella is given.

Biomimetic three-layer hierarchical scaffolds for efficient water management and cell recruitment.

Taking inspiration from the structures of roots, stems and leaves of trees in nature, a biomimetic three-layered scaffold was designed for efficient water management and cell recruitment. Using polycaprolactone (PCL) and polyacrylonitrile (PAN) as raw materials, radially oriented nanofiber films and multistage adjustable nanofiber films were prepared through electrospinning technology as the base skin-friendly layer (roots) and middle unidirectional moisture conductive material (stems), the porous polyurethane foam was integrated as the outer moisturizing layer (leaves). Among which, radially oriented nanofiber films could promote the directional migration of fibroblasts and induce cell morphological changes. For the spatially hierarchically nanofiber films, the unidirectional transport of liquid was effectively realized. While the porous polyurethane foam membrane could absorb 9 times its weight in biofluid and retain moisture for up to 10 h. As a result, the biomimetic three-layered scaffolds with different structures can promote wound epithelization and drain biofluid while avoiding wound inflammation caused by excessive biofluid, which is expected to be applied in the field of skin wounds.

Platelet-rich plasma-loaded bioactive chitosan@sodium alginate@gelatin shell-core fibrous hydrogels with enhanced sustained release of growth factors for diabetic foot ulcer healing.

The ability of autologous platelet-rich plasma (PRP) gel to promote rapid wound healing without immunological rejection has opened new avenues for the treatment of diabetic foot wounds. However, PRP gel still suffers from the quick release of growth factors (GFs) and requires frequent administration, thus resulting in decreased wound healing efficiency, higher cost as well as greater pain and suffering for the patients. In this study, the flow-assisted dynamic physical cross-linked coaxial microfluidic three-dimensional (3D) bio-printing technology, combined with the calcium ion chemical dual cross-linking method was developed to design PRP-loaded bioactive multi-layer shell-core fibrous hydrogels. The prepared hydrogels exhibited outstanding water absorption-retention capacity, good biocompatibility as well as a broad-spectrum antibacterial effect. Compared with clinical PRP gel, these bioactive fibrous hydrogels displayed a sustained release of GFs, reducing the administration frequency by 33 % availably during the wound treatment, but more prominent therapeutic effects such as effective reduced inflammation, in addition to promoting the growth of granulation tissue and angiogenesis, the formation of high-density hair follicles, and the generation of regular ordered and high-density collagen fiber network, which suggested great promise as exceptional candidates for treatment of diabetic foot ulcer in clinical settings.

Over-expression of RRM2 predicts adverse prognosis correlated with immune infiltrates: A potential biomarker for hepatocellular carcinoma.

Background: Ribonucleotide reductase regulatory subunit M2 (RRM2) has been reported to be an oncogene in some malignant tumors, such as lung adenocarcinoma, oral squamous cell carcinoma, glioblastoma, and breast cancer. However, the clinical significance of RRM2 in hepatocellular carcinoma has been less studied. The aim of this study was to assess the importance of RRM2 in hepatocellular carcinoma (HCC) based on the Cancer Genome Atlas (TCGA) database. Methods: The RRM2 expression levels and clinical features were downloaded from the TCGA database. Immunohistochemistry results between tumor tissues and normal tissues were downloaded from the Proteinatlas database. Meanwhile, the expression levels of RRM2 in tumor and paraneoplastic tissues were further verified by qRT-PCR and Western Blotting. Gene Ontology (GO)/Kyoto Encyclopedia of Genes and Genomes (KEGG) and protein-protein-interactions (PPI) network were constructed to analyze RRM2-related downstream molecules. In addition, RRM2 expression-related pathways performed by gene set enrichment analysis (GSEA). Association analysis of RRM2 gene expression and immune infiltration was performed by single-sample GSEA (ssGSEA). Results: The RRM2 expression level in tumor tissues was higher than normal tissues (P <0.001). The elevated expression of RRM2 in HCC was significantly correlated with T stage (P <0.05), pathologic stage (P <0.05), tumor status (P <0.05), histologic grade (P<0.001), and AFP (P <0.001). HCC with higher RRM2 expression was positively associated with worse OS (overall survival), PFS (progression-free survival), and DSS (disease-specific survival). In the univariate analysis, the expression of RRM2, T stage, M stage, pathologic stage, and tumor status were negatively correlated with OS (P <0.05). Further analysis using multivariate Cox regression showed that tumor status (P<0.01) and RRM2 expression (P<0.05) were independent prognostic factors of OS in HCC. GO/KEGG analysis showed that the critical biological process (chromosome condensation and p53 signaling pathway) might be the possible function mechanism in promoting HCC. Moreover, GSEA showed that several pathways were enriched in RRM2 high-expression samples, including PD-1 signaling, cell cycle, P27 pathway, and T cell receptor signaling pathway. RRM2 was significantly correlated with the infiltration level of CD8 T cells, Cytotoxic cells, DCs, Neutrophils, NK cells, and T helper cells (P <0.05). Conclusion: Over-expression of RRM2 predict adverse prognosis and is correlated with immune infiltrates in HCC. RRM2 may be a significant molecular biomarker for HCC diagnosis and prognosis.

3D PCL/collagen nanofibrous medical dressing for one-time treatment of diabetic foot ulcers.

Nanofibrous dressings exhibit high specific surface areas, good histocompatibility, enhanced wound healing, and reduced inflammation, which have broad technological implications for treating diabetic foot ulcers (DFUs). However, current nanofibrous dressings still suffer from high resistance to cell infiltration and multiple dressing changes. In this study, polycaprolactone (PCL) and collagen were adopted as electrospinning materials to prepare a 3D PCL/Collagen (PC) nanofibrous dressing (3D-PC) using aqueous phase fibre reassembly technology. The matrix metalloproteinases (MMPs) inhibitor doxycycline hyclate (DCH)-loaded halloysite nanotubes (HNTs) (DCH@HNTs) and antibacterial agent cephalexin (CEX) were loaded onto the dressing to prepare a multifunctional 3D drug-loaded PCL/Collagen nanofibrous dressing to promote DFU wound healing. The obtained 3D nanofibrous dressing exhibited high water absorption capacity and swelling capacity. It showed good antibacterial activity against Escherichia coli (E. coli) and Staphylococcus aureus (S. aureus) in vitro antibacterial test. In addition, the 3D nanofibrous dressing demonstrated good biocompatibility. It could significantly reduce the frequency of dressing changes and improve the healing of DFU wounds compared with the conventional multiple dressing changes method, suggesting a potential candidate for healing diabetic wounds.

Learning Feature Channel Weighting for Real-Time Visual Tracking.

Recently, the siamese convolutional neural network plays an important role in the field of visual tracking, which can obtain high tracking accuracy and good real-time performance. However, the requirement of offline training a specific neural network results in the hardware source and time consumption. In order to improve the tracking efficiency and save computation resources, we adopt pre-trained densely connected neural network to extract robust target features. Since the pre-trained model is mainly used for classification task, it is not appropriate to directly adopt these deep features for visual tracking. We design a regression network to measure the importance of each channel to the target, and then propose a weighting fusion strategy to select the suitable features for visual tracking. Besides, we provide deep analysis about the proposed channel weighting method to demonstrate the superiority of this method through visualization of feature heatmaps. Extensive experiments on four classical benckmarks show that compared with state-of-the-art methods, our algorithm achieves the best results on several standard indicators and comparable results on other indicators.

Near-infrared upconversion multimodal nanoparticles for targeted radionuclide therapy of breast cancer lymphatic metastases.

The theranostics of lymph node metastasis has always been one of the major obstacles to defeating breast cancer and an important decisive factor in the prognosis of patients. Herein, we design NaGdF4:Yb,Tm@NaLuF4 upconversion nanoparticles with PEG and anti-HER2 monoclonal antibody (trastuzumab, Herceptin) (NP-mAb), the delivery of NP-mAb through the lymphatic system allows for effective targeting and accumulation in lymphatic metastasis. Combination of radionuclides 68Ga and 177Lu could be chelated by the bisphosphate groups of NP-mAb. The obtained nanoprobe (NP-mAb) and nanonuclear drug (68Ga-NP-mAb or 177Lu-NP-mAb) exhibited excellent stability and show high accumulation and prolong retention in the lymph node metastasis after intratumoral injection into the foot pad by near-infrared fluorescence (NIRF), single-photon emission computed tomography (SPECT) and positron emission tomography (PET) imaging. Utilizing the ß-rays released by 177Lu, 177Lu-NP-mAb could not only decrease the incidence of lymph node metastasis, but also significantly decrease the volumes of lymph node metastasis. Additionally, 177Lu-NP-mAb induce no obvious toxicity to treated mice through blood routine, liver and kidney function assay. Therefore, nanoprobe and nanonuclear drug we designed could be acted as excellent theranostics agents for lymph node metastasis, providing potential alternatives diagnose and treatment option for lymph node metastasis.

Preparation of aminated porous polyacrylonitrile nanofibers as adsorbent for methyl orange removal.

In this study, porous electrospinning polyacrylonitrile nanofiber (PPAN) surface functionalization with amine groups is studied for methyl orange (MO) dye removal from aqueous solution. A series of adsorption experiments were carried out to investigate the influence of initial solution pH value, contact time, initial solution concentration, and adsorption temperature on the adsorption performance. The experimental results showed that the removal of MO on these PPAN-PEI and PPAN-TEPA nanofibrous mats was a pH-dependent process with the maximum adsorption capacity at the initial solution pH of 3, and that the PPAN-PEI and PPAN-TEPA nanofibrous mats could be regenerated successfully after 4 recycling processes. The adsorption equilibrium data were all fitted well to the Langmuir isotherm equation, with maximum adsorption capacity of 1414.52 mg g-1 and 1221.09 mg g-1 for PPAN-PEI and PPAN-TEPA, respectively. The kinetic study indicated that the adsorption of MO could be well fitted by the pseudo-second-order equation and Weber-Morris model. Thermodynamic parameters such as free energy, enthalpy, and entropy of adsorption of the MO were also evaluated, and the results showed that the adsorption was a spontaneous exothermic adsorption process.

Efficient neutron radiation shielding by boron-lithium imidazolate frameworks.

Radiation protective materials are widely applied to avoid occupational hazards from either particle emissions or high-energy electromagnetic waves. Herein, we present a boron imidazolate framework (BIF) as a novel neutron shielding additive with high neutron capture cross-section elements B/Li and H. The BIF1-based epoxy resin matrix (Ep-BIF1) possesses high thermal stability and excellent resistance capacity. The neutron radiation shielding property was characterized using an Am-Be source, in which the thermal neutron shielding efficiency of Ep-BIF1 is notably higher than that of Ep-B4C with equal boron concentration, showing potential applications as an advanced efficient neutron radiation shielding composite.