1.
Acta Crystallogr Sect E Struct Rep Online
; 68(Pt 9): m1198, 2012 Sep 01.
Artigo
em Inglês
| MEDLINE
| ID: mdl-22969487
RESUMO
In the title mol-ecular salt, (C(4)H(10)NO)(2)[CoCl(4)], the morpholinium cations adopt chair conformations and the tetra-chloridocobaltate(II) anion is significantly distorted from regular tetra-hedral geometry [Cl-Co-Cl = 102.183â (19)-117.59â (2)°]. The Co-Cl bond lengths for the chloride ions not accepting hydrogen bonds are significantly shorter than those for the chloride ions accepting such bonds. In the crystal, the components are linked by N-Hâ¯O and N-Hâ¯Cl and bifurcated N-Hâ¯(O,Cl) hydrogen bonds to generate (100) sheets.