Global warming implications from increased forest biomass utilization for bioenergy in a supply-constrained context.

This article analyzes different forest management strategies to meet the increasing demand of biomass for bioenergy and assesses the resulting global warming implications. Applied to maritime pine forest plantations in Portugal, the assessed strategies are: full harvest of residues (FULL); sustainable and proactive management (SMART); expansion of forest plantations on abandoned farmland (EXP); and biomass import (IMP). A dynamic CO2 inventory was obtained for each scenario using a parametric stand-level C-flux model adapted to Portuguese conditions, which was then extended to the landscape-level and coupled to a dynamic climate model. The time-adjusted absolute global warming potential (AGWP) was then calculated at both stand and landscape levels, considering the timing of all CO2 emissions and uptakes (both fossil and biogenic). To test the robustness of the findings, a sensitivity analysis was performed. Results show that, in a supply-constrained context like Portugal, SMART and EXP management strategies can provide important global warming mitigation benefits (GWPbio < 0), although their supply-response is slow (long-term strategies). On the other hand, FULL and IMP management strategies show moderate to null AGWP reduction potential (0 < GWPbio < 1), while involving other possible risks (e.g., exacerbated soil erosion, nutrient depletion or uncertain impacts abroad), but their supply-response is fast (short-term strategies). National forest regulations and energy policies should be revised to address the drawbacks related to all management strategies and to unleash the multiple environmental benefits they can provide in the short- and long-term.

Dynamic Assessment of Construction Materials in Urban Building Stocks: A Critical Review.

There is a lack of understanding on the different types of dynamics of building stocks, in real life and in models. Moreover, there is now a particular interest in the embodied impacts of construction materials, since with the increasing efficiency of buildings operation, embodied impacts gain more importance in the overall building life cycle. This critical review wants to advance the understanding of the type of dynamics, methods, and tools used. The well-known IPAT equation is adapted for building stocks and three dynamics are defined: spatial, evolutionary temporal, and spatial-cohort dynamic. A framework is defined that can help researchers choose a method, tool, and dynamics of input parameters depending on their research goal, case study, and data. Moreover, generally valid conclusions are drawn, including MFA is useful to model spatially dynamic material flows; GIS is needed to include spatial dynamics. Retrofit, compared to construction and demolition, is understudied and usually analyzed through top-down methods. Material intensity and emission intensity are rarely modeled in a dynamic way. Overall, scholars seem to perform increasingly data intensive and complex studies tailored to a specific case study. However, there are big differences in the quality depending on the dynamic of input parameters.

Life-cycle greenhouse gas assessment of Nigerian liquefied natural gas addressing uncertainty.

Natural gas (NG) has been regarded as a bridge fuel toward renewable sources and is expected to play a greater role in future global energy mix; however, a high degree of uncertainty exists concerning upstream (well-to-tank, WtT) greenhouse gas (GHG) emissions of NG. In this study, a life-cycle (LC) model is built to assess uncertainty in WtT GHG emissions of liquefied NG (LNG) supplied to Europe by Nigeria. The 90% prediction interval of GHG intensity of Nigerian LNG was found to range between 14.9 and 19.3 g CO2 eq/MJ, with a mean value of 16.8 g CO2 eq/MJ. This intensity was estimated considering no venting practice in Nigerian fields. The mean estimation can shift up to 25 g CO2 eq when considering a scenario with a higher rate of venting emissions. A sensitivity analysis of the time horizon to calculate GHG intensity was also performed showing that higher GHG intensity and uncertainty are obtained for shorter time horizons, due to the higher impact factor of methane. The uncertainty calculated for Nigerian LNG, specifically regarding the gap of data for methane emissions, recommends initiatives to measure and report emissions and further LC studies to identify hotspots to reduce the GHG intensity of LNG chains.

Impact of policy on greenhouse gas emissions and economics of biodiesel production.

As an alternative transportation fuel to petrodiesel, biodiesel has been promoted within national energy portfolio targets across the world. Early estimations of low lifecycle greenhouse gas (GHG) emissions of biodiesel were a driver behind extensive government support in the form of financial incentives for the industry. However, studies consistently report a high degree of uncertainty in these emissions estimates, raising questions concerning the carbon benefits of biodiesel. Furthermore, the implications of feedstock blending on GHG emissions uncertainty have not been explicitly addressed despite broad practice by the industry to meet fuel quality standards and to control costs. This work investigated the impact of feedstock blending on the characteristics of biodiesel by using a chance-constrained (CC) blend optimization method. The objective of the optimization is minimization of feedstock costs subject to fuel standards and emissions constraints. Results indicate that blending can be used to manage GHG emissions uncertainty characteristics of biodiesel, and to achieve cost reductions through feedstock diversification. Simulations suggest that emissions control policies that restrict the use of certain feedstocks based on their GHG estimates overlook blending practices and benefits, increasing the cost of biodiesel. In contrast, emissions control policies which recognize the multifeedstock nature of biodiesel provide producers with feedstock selection flexibility, enabling them to manage their blend portfolios cost effectively, potentially without compromising fuel quality or emissions reductions.

Life cycle assessment of pharmaceutical packaging addressing end-of-life alternatives.

Pharmaceutical packaging waste has increased due to a higher global demand for pharmaceutical products, leading to more waste generation and associated environmental impacts. The main goal of this article is to present a cradle-to-grave life cycle assessment of pharmaceutical packaging, evaluating end-of-life (EoL) alternatives, aiming to identify hotspots and opportunities for improvement. A life cycle model was implemented for three types of pharmaceutical packaging (blisters, sachets, bottles; 23 packaging). The functional unit is the storage and delivery of medicines containing the same active pharmaceutical ingredient, dosage, and amount of medicines. Two EoL analyses were performed: 1) compare take-back (recycling and incineration) with domestic waste collection (landfill or incineration); and 2) assess different EoL situations of pharmaceutical packaging in Europe. A life cycle impact assessment was performed for 13 categories. Analysis 1 shows that take-back presents lower environmental impacts than domestic waste collection for seven out of 13 categories due to paper and glass recycling benefits. Analysis 2 shows that in the take-back, higher amounts of packaging are recycled or incinerated, which leads to lower EoL impacts. A sensitivity analysis was performed to evaluate the influence of parameters and assumptions in packaging EoL impacts. Packaging production contributes significantly to life cycle impacts, followed by transportation, EoL, and packing process. Ecodesign initiatives are recommended, such as packaging with less material and volume, using materials with lower impacts to significantly reduce the impacts of pharmaceutical packaging.

Ecodesign approach for pharmaceutical packaging based on Life Cycle Assessment.

Packaging ecodesign can contribute to improve the environmental performance of pharmaceutical products. The main goal of this article is to present an ecodesign approach based on Life Cycle Assessment (LCA) for pharmaceutical packaging, assessing opportunities to improve the packaging environmental performance, and providing ecodesign recommendations to the pharmaceutical sector. The proposed ecodesign approach consists of five phases. I) The most representative packaging of medicines in the market (blister, bottle, and sachet), with different sizes, materials and weights, were investigated. II) Three ecodesign strategies were selected to analyze with LCA: i) weight and/or volume reduction, ii) alternative types of packaging, and iii) transportation with less environmental impact. III-IV) A cradle-to-gate life cycle model has been implemented, including transport to pharmacies. Alternative transportation modes (truck, train, airplane, and ship) and different packaging production locations have been considered. Thirteen environmental categories have been analyzed. V) Ecodesign recommendations for improving the environmental performance of pharmaceutical packaging are presented in two stages: i) specific recommendations based on LCA, illustrated in sheets with examples of ecodesign, quantifying the environmental impact reduction of an ecodesign solution compared to the original; and ii) generic recommendations for different packaging life cycle phases. Ecodesign recommendations highlight the use of smaller-size packaging, avoiding superfluous elements and empty spaces, which reduces material and production costs, and transportation impacts; the selection of modes of transportation with less environmental impact, considering the packaging production location; and the use of electric vehicles for pharmacy distribution. This ecodesign approach based on LCA allows quantifying environmental impacts robustly to support the incorporation of environmental information from the design, material selection, and packaging production to distribution till the final consumer. This article emphasizes the importance of developing specific packaging ecodesign based on LCA to improve environmental performance and provide more informed recommendations to stakeholders.

Environmental impacts of commuting modes in Lisbon: a life-cycle assessment addressing particulate matter impacts on health.

A life-cycle assessment of commuting alternatives is conducted that compares six transportation modes (car, bus, train, subway, motorcycle and bicycle) for eight impact indicators. Fine particulate matter (PM2.5) emissions and health impacts are incorporated in the assessment using intake fractions that differentiate between urban and non-urban emissions, combined with an effect factor. The potential benefits of different strategies for reducing environmental impacts are illustrated. The results demonstrate the need for comprehensive approaches that avoid problem-shifting among transportation-related strategies. Policies aiming to improve the environmental performance of urban transportation should target strategies that decrease local emissions, life-cycle impacts and health effects.

Life cycle assessment of wood pellets and wood split logs for residential heating.

Wood-fuelled systems are commonly used all over the world for residential heating, and recently wood pellets have been replacing traditional firewood. This article presents an environmental life cycle assessment of five wood-based combustion systems for residential heating: i) a pellet stove using maritime pine pellets; a wood stove using ii) eucalyptus (Eucalyptus globulus Labill.) and iii) maritime pine (Pinus pinaster Ait.) split logs; and a fireplace using iv) eucalyptus and v) maritime pine split logs. The functional unit is 1 MJ of thermal energy for residential heating. System boundaries include four stages: (1) forest management; (2) pellet and wood split log production; (3) distribution; and (4) thermal energy generation. Environmental impacts were calculated for seven impact categories from the ReCiPe 2016 midpoint method, and a sensitivity analysis was performed using the Product Environmental Footprint (PEF) life cycle impact assessment method and modifying the distances travelled. Of the five heating systems analysed, the fireplace presents the worst performance for all the impact categories with the exception of freshwater eutrophication and marine eutrophication, when maritime pine split logs are burned in the fireplace. Comparing the pellet stove with the wood stove, neither system is better for all the impact categories analysed. Regarding sensitivity analysis, the use of an alternative characterisation method leads to similar trends in the results in comparison with those obtained from the ReCiPe method, while changes in transport distances do not affect the total impacts to a large extent.

Reducing impacts from ammunitions: A comparative life-cycle assessment of four types of 9mm ammunitions.

Increase of environmental awareness of the population has pressured research activities in the defence area to cover environment and toxicity issues, where have been considered appropriate manners to reduce the environmental and toxicological impacts of ammunition. One of the adopted approaches to achieve such goal involves the replacement of lead and other heavy metals by alternative materials. However, the consequences of using alternative materials in ammunitions manufacturing are uncertain for the other life-cycle phases and trade-offs can occur. The present paper describes the potential benefits from the replacement of lead in the primer and in the projectile of a 9mm calibre ammunition. For that purpose, it is assessed and compared the environmental and toxicological impacts associated with the life-cycle of four ammunitions: combination of two types of projectiles (steel jacket and lead core; copper and nylon composite) with two types of primers (lead primer; non-lead primer). In addition, some potential improvements for the environmental performance of small calibre ammunition are also presented. To assess the impacts two Life-Cycle Impact Assessment methods are applied: CML for six environmental categories and USEtox to three toxicity categories. Results showed that the conclusion drawn for environmental and toxicological impact categories are distinct. In fact, ammunition production phase presents higher impacts for the environmental categories, whilst the operation phase has a higher impact to the toxicity categories. The substitution of lead in the primer and in the projectile provides a suitable alternative from a toxicology perspective; however, the composite projectile still presents some environmental concerns. The conclusions drawn are important for the procurement (and design) of environmental responsible ammunitions, in order to avoid (or decrease) the impacts for their manufacture and the effects on human health (e.g. shooters) and ecosystems near shooting ranges or hunting areas.