Converting Nafion into Li+ -Conductive Nanoporous Materials.

Sulfonated polymers have long been used as proton-conducting materials in fuel cells, and their ionic transport features are highly attractive for electrolytes in lithium-ion/metal batteries (LIBs/LMBs). However, most studies are still based on a preconceived notion of using them directly as polymeric ionic carriers, which precludes exploring them as nanoporous media to construct efficient lithium ions (Li+ ) transport network. Here, effective Li+ -conducting channels realized by swelling nanofibrous Nafion is demonstrated, which is a classical sulfonated polymer in fuel cells. The sulfonic acid groups, interact with LIBs liquid electrolytes to form porous ionic matrix of Nafion and assist partial desolvation of Li+ -solvates to further enhance Li+ transport. Li-symmetric cells and Li-metal full cells (Li4 Ti5 O12 or high-voltage LiNi0.6 Co0.2 Mn0.2 O2 as a cathode) with such membrane show excellent cycling performance and stabilized Li-metal anode. The finding provides a strategy to convert the vast sulfonated polymer family into efficient Li+ electrolyte, promoting the development of high-energy-density LMBs.

Detection of Flying Metal Bodies Based on Photoelectric Composite Sensing.

In order to reduce the impact of the environment on the accuracy and sensitivity of detection, and to meet the requirements of concealment from detection and being lightweight, a technology for detecting flying metal objects based on photoelectric composite sensors is proposed. The method first analyzes the target's characteristics and detection environment, and then compares and analyzes the methods for detecting typical flying metal objects. On the basis of the traditional eddy current model, the photoelectric composite detection model that meets the requirements of detecting flying metal objects was studied and designed. For the problems of the short detection distance and the long response time of the traditional eddy current model, the performance of the eddy current sensor was improved to meet the requirements of detection through optimizing the detection circuit and coil parameter model. Meanwhile, to meet the goal of being lightweight, an infrared detection array model applicable to flying metal bodies was designed, and simulation experiments of composite detection based on the model were conducted. The results show that the flying metal body detection model based on photoelectric composite sensors met the requirements of distance and response time for detecting flying metal bodies and may provide an avenue for exploring the composite detection of flying metal bodies.

Biomimetic Gradient Bouligand Structure Enhances Impact Resistance of Ceramic-Polymer Composites.

Biological materials relied on multiple synergistic structural design elements typically exhibit excellent comprehensive mechanical properties. Hierarchical incorporation of different biostructural elements into a single artificial material is a promising approach to enhance mechanical properties, but remains challenging. Herein, a biomimetic structural design strategy is proposed by coupling gradient structure with twisted plywood Bouligand structure, attempting to improve the impact resistance of ceramic-polymer composites. Via robocasting and sintering, kaolin ceramic filaments reinforced by coaxially aligned alumina nanoplatelets are arranged into Bouligand structure with a gradual transition in filament spacing along the thickness direction. After the following polymer infiltration, biomimetic ceramic-polymer composites with a gradient Bouligand (GB) structure are eventually fabricated. Experimental investigations reveal that the incorporation of gradient structure into Bouligand structure improves both the peak force and total energy absorption of the obtained ceramic-polymer composites. Computational modeling further suggests the substantial improvement in impact resistance by adopting GB structure, and clarifies the underlying deformation behavior of the biomimetic GB structured composites under impact. This biomimetic design strategy may provide valuable insights for developing lightweight and impact-resistant structural materials in the future.

Batch synthesis of high activity and durability carbon supported platinum catalysts for oxygen reduction reaction using a new facile continuous microwave pipeline technology.

Traditional synthesis methodologies for fuel cell catalyst production involve long reactions and uncontrollable reaction processes. Synthesis methods for the production of catalysts typically have difficulties to achieve catalysts materials with consistency, high activity, and durability. In this study, a fast, simple, and suitable continuous pipeline microwave method for catalyst mass production was developed, with the carbon carrier being treated at different temperatures simultaneously. The method herein developed resulted in carbon-supported platinum (Pt) catalysts with high activity and high durability. In addition, the half-wave potential of the catalyst exceeded 0.9 V, the electrochemical active surface area reached 85.7 m2-gPt-1, and the mass specific activity reached 171.1 mA-mg-1. Remarkably, after 30,000 cycles of Pt attenuation tests and 30,000 cycles of carbon carrier attenuation tests, the retention rate of the annealed carbon carrier catalyst reached 80 %. As a membrane electrode, the catalyst generated a single cell maximum power density of 1.4 W-cm-2, and the Pt content reached 0.286 gPt-kW-1. The work provides an effective and practical method for the mass production of high-performance and high-durability catalysts, which guiding significance for mass production of catalysts.