Remote detection of a lunar granitic batholith at Compton-Belkovich.

Granites are nearly absent in the Solar System outside of Earth. Achieving granitic compositions in magmatic systems requires multi-stage melting and fractionation, which also increases the concentration of radiogenic elements1. Abundant water and plate tectonics facilitate these processes on Earth, aiding in remelting. Although these drivers are absent on the Moon, small granite samples have been found, but details of their origin and the scale of systems they represent are unknown2. Here we report microwave-wavelength measurements of an anomalously hot geothermal source that is best explained by the presence of an approximately 50-kilometre-diameter granitic system below the thorium-rich farside feature known as Compton-Belkovich. Passive microwave radiometry is sensitive to the integrated thermal gradient to several wavelengths depth. The 3-37-gigahertz antenna temperatures of the Chang'e-1 and Chang'e-2 microwave instruments allow us to measure a peak heat flux of about 180 milliwatts per square metre, which is about 20 times higher than that of the average lunar highlands3,4. The surprising magnitude and geographic extent of this feature imply an Earth-like, evolved granitic system larger than believed possible on the Moon, especially outside of the Procellarum region5. Furthermore, these methods are generalizable: similar uses of passive radiometric data could vastly expand our knowledge of geothermal processes on the Moon and other planetary bodies.

Distinct Carbonate Lithologies in Jezero Crater, Mars.

Jezero crater is the landing site for the Mars 2020 Perseverance rover. The Noachian-aged crater has undergone several periods of fluvial and lacustrine activity and phyllosilicate- and carbonate-bearing rocks were formed and emplaced as a result. It also contains a portion of the regional Nili Fossae olivine-carbonate unit. In this work, we performed spectral mixture analysis of visible/near-infrared hyperspectral imagery over Jezero. We modeled carbonate abundances up to ∼35% and identified three distinct units containing different carbonate phases. Our work also shows that the olivine in Jezero is predominantly restricted to aeolian deposits overlying the carbonate rocks. The diversity of carbonate phases in Jezero points to multiple periods of carbonate formation under varying conditions.

Iraq/Afghanistan war lung injury reflects burn pits exposure.

This descriptive case series retrospectively reviewed medical records from thirty-one previously healthy, war-fighting veterans who self-reported exposure to airborne hazards while serving in Iraq and Afghanistan between 2003 and the present. They all noted new-onset dyspnea, which began during deployment or as a military contractor. Twenty-one subjects underwent non-invasive pulmonary diagnostic testing, including maximum expiratory pressure (MEP) and impulse oscillometry (IOS). In addition, five soldiers received a lung biopsy; tissue results were compared to a previously published sample from a soldier in our Iraq Afghanistan War Lung Injury database and others in our database with similar exposures, including burn pits. We also reviewed civilian control samples (5) from the Stony Brook University database. Military personnel were referred to our International Center of Excellence in Deployment Health and Medical Geosciences, Donald and Barbara Zucker School of Medicine at Hofstra/Northwell under the auspices of Northwell IRB: 17-0140-FIMR Feinstein Institution for Medical Research "Clinicopathologic characteristics of Iraq Afghanistan War Lung Injury." We retrospectively examined medical records, including exposure data, radiologic imaging, and non-invasive pulmonary function testing (MGC Diagnostic Platinum Elite Plethysmograph) using the American Thoracic Society (ATS) standard interpretation based on Morgan et al., and for a limited cohort, biopsy data. Lung tissue, when available, was examined for carbonaceous particles, polycyclic aromatic hydrocarbons (Raman spectroscopy), metals, titanium connected to iron (Brookhaven National Laboratory, National Synchrotron Light Source II, Beamline 5-ID), oxidized metals, combustion temperature, inflammatory cell accumulation and fibrosis, neutrophil extracellular traps, Sirius red, Prussian Blue, as well as polarizable crystals/particulate matter/dust. Among twenty-one previously healthy, deployable soldiers with non-invasive pulmonary diagnostic tests, post-deployment, all had severely decreased MEP values, averaging 42% predicted. These same patients concurrently demonstrated abnormal airways reactance (X5Hz) and peripheral/distal airways resistance (D5-D20%) via IOS, averaging - 1369% and 23% predicted, respectively. These tests support the concept of airways hyperresponsiveness and distal airways narrowing, respectively. Among the five soldiers biopsied, all had constrictive bronchiolitis. We detected the presence of polycyclic aromatic hydrocarbons (PAH)-which are products of incomplete combustion-in the lung tissue of all five warfighters. All also had detectable titanium and iron in the lungs. Metals were all oxidized, supporting the concept of inhaling burned metals. Combustion temperature was consistent with that of burned petrol rather than higher temperatures noted with cigarettes. All were nonsmokers. Neutrophil extracellular traps were reported in two biopsies. Compared to our prior biopsies in our Middle East deployment database, these histopathologic results are similar, since all database biopsies have constrictive bronchiolitis, one has lung fibrosis with titanium bound to iron in fixed mathematical ratios of 1:7 and demonstrated polarizable crystals. These results, particularly constrictive bronchiolitis and polarizable crystals, support the prior data of King et al. (N. Engl. J. Med. 365:222-230, 2011) Soldiers in this cohort deployed to Iraq and Afghanistan since 2003, with exposure to airborne hazards, including sandstorms, burn pits, and improvised explosive devices, are at high risk for developing chronic clinical respiratory problems, including: (1) reduction in respiratory muscle strength; (2) airways hyperresponsiveness; and (3) distal airway narrowing, which may be associated with histopathologic evidence of lung damage, reflecting inhalation of burned particles from burn pits along with particulate matter/dust. Non-invasive pulmonary diagnostic tests are a predictor of burn pit-induced lung injury.

Nano-FTIR spectroscopic identification of prebiotic carbonyl compounds in Dominion Range 08006 carbonaceous chondrite.

Meteorites contain organic matter that may have contributed to the origin of life on Earth. Carbonyl compounds such as aldehydes and carboxylic acids, which occur in meteorites, may be precursors of biologically necessary organic materials in the solar system. Therefore, such organic matter is of astrobiological importance and their detection and characterization can contribute to the understanding of the early solar system as well as the origin of life. Most organic matter is typically sub-micrometer in size, and organic nanoglobules are even smaller (50-300 nm). Novel analytical techniques with nanoscale spatial resolution are required to detect and characterize organic matter within extraterrestrial materials. Most techniques require powdered samples, consume the material, and lose petrographic context of organics. Here, we report the detection of nanoglobular aldehyde and carboxylic acids in a highly primitive carbonaceous chondrite (DOM 08006) with ~ 20 nm spatial resolution using nano-FTIR spectroscopy. Such organic matter is found within the matrix of DOM 08006 and is typically 50-300 nm in size. We also show petrographic context and nanoscale morphologic/topographic features of the organic matter. Our results indicate that prebiotic carbonyl nanoglobules can form in a less aqueous and relatively elevated temperature-environment (220-230 °C) in a carbonaceous parent body.

Olivine Dissolution in Simulated Lung and Gastric Fluid as an Analog to the Behavior of Lunar Particulate Matter Inside the Human Respiratory and Gastrointestinal Systems.

With the Artemis III mission scheduled to land humans on the Moon in 2025, work must be done to understand the hazards lunar dust inhalation would pose to humans. In this study, San Carlos olivine was used as an analog of lunar olivine, a common component of lunar dust. Olivine was dissolved in a flow-through apparatus in both simulated lung fluid and 0.1 M HCl (simulated gastric fluid) over a period of approximately 2 weeks at physiological temperature, 37°C. Effluent samples were collected periodically and analyzed for pH, iron, silicon, and magnesium ion concentrations. The dissolution rate data derived from our measurements allow us to estimate that an inhaled 1.0 µm diameter olivine particle would take approximately 24 years to dissolve in the human lungs and approximately 3 weeks to dissolve in gastric fluid. Results revealed that inhaled olivine particles may generate the toxic chemical, hydroxyl radical, for up to 5-6 days in lung fluid. Olivine dissolved in 0.1 M HCl for 2 weeks transformed to an amorphous silica-rich solid plus the ferric iron oxy-hydroxide ferrihydrite. Olivine dissolved in simulated lung fluid shows no detectable change in composition or crystallinity. Equilibrium thermodynamic models indicate that olivine in the human lungs can precipitate secondary minerals with fibrous crystal structures that have the potential to induce detrimental health effects similar to asbestos exposure. Our work indicates that inhaled lunar dust containing olivine can settle in the human lungs for years and could induce long-term potential health effects like that of silicosis.

Report of the Joint Workshop on Induced Special Regions.

The Joint Workshop on Induced Special Regions convened scientists and planetary protection experts to assess the potential of inducing special regions through lander or rover activity. An Induced Special Region is defined as a place where the presence of the spacecraft could induce water activity and temperature to be sufficiently high and persist for long enough to plausibly harbor life. The questions the workshop participants addressed were: (1) What is a safe stand-off distance, or formula to derive a safe distance, to a purported special region? (2) Questions about RTGs (Radioisotope Thermoelectric Generator), other heat sources, and their ability to induce special regions. (3) Is it possible to have an infected area on Mars that does not contaminate the rest of Mars? The workshop participants reached a general consensus addressing the posed questions, in summary: (1) While a spacecraft on the surface of Mars may not be able to explore a special region during the prime mission, the safe stand-off distance would decrease with time because the sterilizing environment, that is the martian surface would progressively clean the exposed surfaces. However, the analysis supporting such an exploration should ensure that the risk to exposing interior portions of the spacecraft (i.e., essentially unsterilized) to the martian surface is minimized. (2) An RTG at the surface of Mars would not create a Special Region but the short-term result depends on kinetics of melting, freezing, deliquescence, and desiccation. While a buried RTG could induce a Special Region, it would not pose a long-term contamination threat to Mars, with the possible exception of a migrating RTG in an icy deposit. (3) Induced Special Regions can allow microbial replication to occur (by definition), but such replication at the surface is unlikely to globally contaminate Mars. An induced subsurface Special Region would be isolated and microbial transport away from subsurface site is highly improbable.

Radiative-transfer modeling of spectra of planetary regoliths using cluster-based dense packing modifications.

In remote sensing of planetary bodies, the development of analysis techniques that lead to quantitative interpretations of datasets has relatively been deficient compared to the wealth of acquired data, especially in the case of regoliths with particle sizes on the order of the probing wavelength. Radiative transfer theory has often been applied to the study of densely packed particulate media like planetary regoliths, but with difficulty; here we continue to improve theoretical modeling of spectra of densely packed particulate media. We use the superposition T-matrix method to compute the scattering properties of an elementary volume entering the radiative transfer equation by modeling it as a cluster of particles and thereby capture the near-field effects important for dense packing. Then, these scattering parameters are modified with the static structure factor correction to suppress the irrelevant far-field diffraction peak rendered by the T-matrix procedure. Using the corrected single- scattering parameters, reflectance (and emissivity) is computed via the invariant-imbedding solution to the scalar radiative transfer equation. We modeled the emissivity spectrum of the 3.3 µm particle size fraction of enstatite, representing a common regolith component, in the mid-infrared (~5 - 50 µm). The use of the static structure factor correction coupled with the superposition T-matrix method produced better agreement with the corresponding laboratory spectrum than the sole use of the T-matrix method, particularly for volume scattering wavelengths (transparency features). This work demonstrates the importance of proper treatment of the packing effects when modeling semi-infinite densely packed particulate media using finite, cluster-based light scattering models.

Formation of lunar swirls by magnetic field standoff of the solar wind.

Lunar swirls are high-albedo markings on the Moon that occur in both mare and highland terrains; their origin remains a point of contention. Here, we use data from the Lunar Reconnaissance Orbiter Diviner Lunar Radiometer to support the hypothesis that the swirls are formed as a result of deflection of the solar wind by local magnetic fields. Thermal infrared data from this instrument display an anomaly in the position of the silicate Christiansen Feature consistent with reduced space weathering. These data also show that swirl regions are not thermophysically anomalous, which strongly constrains their formation mechanism. The results of this study indicate that either solar wind sputtering and implantation are more important than micrometeoroid bombardment in the space-weathering process, or that micrometeoroid bombardment is a necessary but not sufficient process in space weathering, which occurs on airless bodies throughout the solar system.

Highly silicic compositions on the Moon.

Using data from the Diviner Lunar Radiometer Experiment, we show that four regions of the Moon previously described as "red spots" exhibit mid-infrared spectra best explained by quartz, silica-rich glass, or alkali feldspar. These lithologies are consistent with evolved rocks similar to lunar granites in the Apollo samples. The spectral character of these spots is distinct from surrounding mare and highlands material and from regions composed of pure plagioclase feldspar. The variety of landforms associated with the silicic spectral character suggests that both extrusive and intrusive silicic magmatism occurred on the Moon. Basaltic underplating is the preferred mechanism for silicic magma generation, leading to the formation of extrusive landforms. This mechanism or silicate liquid immiscibility could lead to the formation of intrusive bodies.

Global silicate mineralogy of the Moon from the Diviner lunar radiometer.

We obtained direct global measurements of the lunar surface using multispectral thermal emission mapping with the Lunar Reconnaissance Orbiter Diviner Lunar Radiometer Experiment. Most lunar terrains have spectral signatures that are consistent with known lunar anorthosite and basalt compositions. However, the data have also revealed the presence of highly evolved, silica-rich lunar soils in kilometer-scale and larger exposures, expanded the compositional range of the anorthosites that dominate the lunar crust, and shown that pristine lunar mantle is not exposed at the lunar surface at the kilometer scale. Together, these observations provide compelling evidence that the Moon is a complex body that has experienced a diverse set of igneous processes.

Diviner Lunar Radiometer observations of cold traps in the Moon's south polar region.

Diviner Lunar Radiometer Experiment surface-temperature maps reveal the existence of widespread surface and near-surface cryogenic regions that extend beyond the boundaries of persistent shadow. The Lunar Crater Observation and Sensing Satellite (LCROSS) struck one of the coldest of these regions, where subsurface temperatures are estimated to be 38 kelvin. Large areas of the lunar polar regions are currently cold enough to cold-trap water ice as well as a range of both more volatile and less volatile species. The diverse mixture of water and high-volatility compounds detected in the LCROSS ejecta plume is strong evidence for the impact delivery and cold-trapping of volatiles derived from primitive outer solar system bodies.

Spectroscopic identification of carbonate minerals in the martian dust.

Thermal infrared spectra of the martian surface indicate the presence of small concentrations (approximately 2 to 5 weight %) of carbonates, specifically dominated by magnesite (MgCO3). The carbonates are widely distributed in the martian dust, and there is no indication of a concentrated source. The presence of small concentrations of carbonate minerals in the surface dust and in martian meteorites can sequester several bars of atmospheric carbon dioxide and may have been an important sink for a thicker carbon dioxide atmosphere in the martian past.