1.
Chem Asian J
; 18(2): e202201180, 2023 Jan 17.
Artigo
em Inglês
| MEDLINE
| ID: mdl-36495085
RESUMO
We developed a Cp*Rh(III)-catalyzed C-H arylation of ferrocenethionamides with arylboronic acids for the synthesis of aryl-ferrocenes under mild and base-free conditions, using Ag2 CO3 as oxidant. The reaction results in high yields and excellent regioselectivity accommodating a broad scope of substrate range and functional group compatibility, and provides an alternative protocol for the generation of highly functionalized aryl-ferrocene compounds.