RESUMO
Developing a flexible temperature sensor with appreciable sensitivity is critical for advancing research related to flexible electronics. Although various flexible sensors are available commercially, most such temperature sensors are made from polymeric materials obtained from petrochemical resources. Such sensors will contribute to electronic waste and increase the carbon footprint after usage. While there are reports on various sensors made from sustainable polymers, research related to developing self-healable flexible temperature sensors made from sustainable polymers is significantly less. Herein, we report on developing a flexible temperature sensor made of gallic acid-grafted epoxidized natural rubber and multi-walled carbon nanotubes. Various spectroscopic and thermal techniques vetted the modification of the epoxidized natural rubber. The highest grafting of 20.9% was achieved in the selected window of stoichiometry. A self-healing behavior was achieved by leveraging the FeCl3 based metal-ligand crosslinking of the composite. The healing efficiency was noted to be 31.2% for the composite material. The fabricated sensor demonstrated an electrical resistance of 4.46 × 103 Ω, thereby warranting the composite to demonstrate an Ohmic behavior in the I-V plot. Appropriate data fitting suggested a variable range hopping mechanism as causation towards excellent electrical conduction. The temperature sensitivity and the thermal index of the developed sensor were noted to be -0.17% °C-1 and 781.2 K, respectively, in the temperature range of 30 °C to 50 °C. The proposed method of fabricating sustainable, high-strength, self-healable, and robust temperature sensors and conductors is a unique and value-added approach for next-generation flexible electronics.
RESUMO
Rapid consumption of traditional energy resources creates utmost research interest in developing self-sufficient electrical devices to progress next-generation electronics to a level up. To address the global energy crisis, moisture-electric generators (MEGs) are proving to be an emerging technology in this field, capable of powering wearable electronics by harvesting energy from abundantly available ambient moisture without any requirement for external/additional energy. Recent advances in MEGs generally utilize an inorganic, metal, or petroleum-based polymeric material as an active material, which may produce sufficient current but lacks the flexibility and stretchability required for wearable electronics. Herein, we prepared an elastomer-based ionic hydrogel as an active material, and an MEG was fabricated by placing the ionic hydrogel on a PET sheet with two copper tapes on both sides of the hydrogel. The preparation of the hydrogel was thoroughly optimized and characterized in terms of spectroscopic analysis, swelling, water retention, and mechanical and rheological studies. The highly stretchable (350%) fabricated MEG is capable of producing a short-circuit current (JSC) of 16.1 µA/cm2, an open-circuit voltage (VOC) of 0.24 V, and a power density of 3.86 µW/cm2. The synergistic effect of the ion concentration gradient and the redox reaction on electrodes can be considered MEG's working principle. Apart from the current generation, this device is also used as a self-powered electronic sensor to monitor different physical activities by measuring breathing patterns. This prepared device is also capable of sensing the proximity of a hand. Therefore, our low-cost, easily fabricable, sustainable MEG device can be a potential aspirant for next-generation self-powered wearable electronics in healthcare applications.
RESUMO
Nanofillers (NFs) are becoming a ubiquitous choice for applications in different technological innovations in various fields, from biomedical devices to automotive product portfolios. Potential physical attributes like large surface areas, high surface energy, and lower structural imperfections make NFs a popular filler over microfillers. One specific application, where NFs are finding applications, is in adhesive science and technology. Incorporating NFs in the adhesive matrix is seen to tune the adhesives' different properties like wettability, rheology, etc. Additionally, the functional benefits (like electrical/thermal conductivity) of these NFs are translated into the adhesives' properties. Such an improvement in the properties is far to achieve using microfillers in the adhesive matrix. This mini-review provides an account of the impact of the addition of various nanofillers (NFs) on the properties of the adhesive composition.