Performance of biochar mixed cement paste for removal of Cu, Pb and Zn from stormwater.

Using biochar as a partial replacement of Portland cement in cementitious materials is a promising solution to mitigate negative environmental impacts. However, current studies in available literature primarily focus on the mechanical properties of composites made with cementitious materials and biochar. Therefore, this paper reports the effects of the type of biochar, the percentage of biochar addition, and the particle size of the biochar on the removal efficiency of Cu, Pb, and Zn, as well as the effect of contact time on the removal efficiency of Cu, Pb, and Zn, along with the compressive strength. The peak intensities of OH-, CO32- and Calcium Silicate Hydrate (Ca-Si-H) peaks increase with increasing biochar addition levels, reflecting increased hydration product formation. The reduction of particle size of biochar causes the polymerization of the Ca-Si-H gel. However, no significant changes were observed in heavy metal removal, irrespective of the percentage of biochar addition, the particle size of biochar, or the type of biochar added to the cement paste. Adsorption capacities above 19 mg/g, 11 mg/g and 19 mg/g for Cu, Pb and Zn were recorded in all composites at an initial pH of 6.0. The Pseudo second order model best described the kinetics of the Cu, Pb, and Zn removal. The rate of adsorptive removal increases with the decrease in the density of the adsorbents. Over 40% of Cu and Zn were removed as carbonates and hydroxides through precipitation, whereas over 80% of Pb removal was via adsorption. Heavy metals bonded with OH-, CO32- and Ca-Si-H functional groups. The results demonstrate that biochar can be used as a cement replacement without negatively impacting heavy metal removal. However, neutralization of the high pH is needed before safe discharge.

Life cycle assessment and cost analysis of fly ash-rice husk ash blended alkali-activated concrete.

The utilization of industrial and agricultural by-products for the production of alkali activated concrete (AAC) has the potential to yield significant benefits towards sustainability goals. To be a viable material, the construction industry requires a construction material that achieves the requisite strength and the other property requirements as specified in codes and standards while demonstrating improved sustainability criteria. Fly ash and Rice Husk Ash (RHA) are abundantly available waste products, principally located in Asian countries. Currently, a significant proportion of these materials are disposed of in landfills, lagoons and rivers but offer potential to utilize in AAC. Hence, the identification of variables associated with fly ash and fly ah-RHA blended AAC by utilizing fly ash and RHA is vital. This study quantifies the environmental and economic factors by assessing the Greenhouse gas (GHG) emission, environmental impacts and benefits, and cost analysis of utilizing fly ash and RHA in AAC compared to Portland Cement (PC) concrete. Alkaline activator is a key component responsible for the highest GHG emission, cost and environmental impact amounts obtained for fly ash geopolymer and blended alkali-activated concrete compared with PC concrete. Alkali activators contribute to 74% of the total GHG emission, while heat curing contributed only 9% to the total GHG emission. The addition of 10% RHA to alkali-activated concrete showed a slight benefit for the analysis. Utilization of waste fly ash and RHA is responsible for providing significant benefits in terms of fresh and marine water ecotoxicity by avoiding waste disposal at the dumpsites, rivers, and storage lagoons.

Assessing the Influence of Banana Leaf Ash as Pozzolanic Material for the Production of Green Concrete: A Mechanical and Microstructural Evaluation.

This paper reports an investigation of the mechanical and microscopic properties of partially replaced banana leaf ash (BLA) concrete. In this research, the cement was partially replaced by BLA in two phases: Phase A (0%, 5%, 10%, 15%, 20%, 25% and 30%) and Phase B (0%, 10%, 20% and 30%). The consequence of partially replacing cement with BLA in concrete was investigated by the application of a range of tests, namely X-ray fluorescence (XRF), compressive strength, splitting tensile strength, flexure strength, ultrasonic pulse velocity and scanning electron microscopy (SEM) analysis. The properties were then correlated with the properties of a standard 100% Portland cement concrete of similar strength. The XRF result of the BLA identified a composition with 48.93% SiO2 and 3.48% Al2O3, which indicates that the material potentially possesses pozzolanic properties. The mechanical properties of the partially replaced BLA concrete noted minor strength loss, approximately 5% with 20% partial replacement. The nondestructive testing data showed enhanced performance up to 20% partial replacement, with ultrasonic pulse values above 3500 m/s. The scanning electron microscopy analysis illustrated that the morphology of BLA specimens contained increased microcracks compared with the control. The decrease in strength observed is attributed to the fibrous composition of the BLA. The mechanical, nondestructive testing and microscopic results highlight the potential to utilize BLA as a partial replacement for cement as a pozzolanic material in concrete at up to 20% by weight of cement.

Sustainable Cement Composite Integrating Waste Cellulose Fibre: A Comprehensive Review.

This review presents the research conducted to date in the field of cement-based composites reinforced with waste paper-based cellulose fibres, focusing on their composition, mechanical properties, and durability characteristics. The literature demonstrates that the properties of raw material (depending on their own chemical composition) significantly influence the formation of the cement composite binders. When considering fresh properties, the presence of silica and magnesium compounds generally lead to favourable effects on the setting of the cement composite when combined with waste paper cellulose fibre. Reduction in density values, i.e., approximately 25%, was observed with the inclusion of waste paper fibres from 20 to 80% in cement composites. The homogeneous dispersion of fibres in the matrix is one of the crucial factors to achieve in order to develop composites with well-balanced mechanical properties incorporating waste paper cellulose fibres. Hence, dispersion of fibres can be improved by increasing water quantity corresponding to the optimal value, which was a water/cement ratio of 0.64 leading to optimum strength properties of the composite. Even though the effect of fibre dispersion in the matrix improves with the addition of water, higher porosity and voids govern the strength properties beyond an optimum water-to-cement ratio. Higher porosity leads to an increase in the water absorption and a lowering of the thermal conductivity properties with the addition of paper fibre in cement binders. Paper fibre absorbs a high amount of water leading to higher water absorption. This phenomenon is related to the hydrophilic nature of cellulosic fibres absorbing some volume of water due to their microporous structure.

Improvement of heavy metal removal from urban runoff using modified pervious concrete.

Heavy metals are one of the major chemical pollutant groups in urban runoff. The application of porous concrete is a potential alternative to conventional runoff management systems with the ability to remove heavy metals. Hence, a thorough understanding of the heavy metal removal mechanisms and constraints of conventional porous concrete opens a path for the development of effective modifications. This review critically discusses the major contributors in ordinary porous concrete which supports heavy metal removal. The effects of initial concentration, contact time and competing ions on heavy metal removal using porous concrete are also discussed. Additionally, the effect of decalcification, atmospheric carbonation, acid influent on heavy metal removal is reviewed. The major drawback of porous concrete is the high pH (>8.5) of the effluent water, decalcification of the porous concrete and leaching of adsorbed pollutants. Overall, the addition of adsorbent materials to the porous concrete increases removal efficiencies (7% - 65% increase) without neutralizing the effluent pH. Meanwhile, the addition of Reduced Graphene Oxide is successful in reducing the leachability of the removed heavy metals. The addition of pozzolanic materials can lower the effluent pH while maintaining similar removal efficiencies to unmodified porous concrete. Therefore, developing a novel method of neutralizing the effluent pH must be prioritized in future studies. Additionally, the toxicity that can occur due to the abrasion of modified porous concrete requires study in future research. Further, advanced characterization methods should be used in future studies to understand the mechanisms of removal via the modified porous concrete materials.

Novel Analytical Method for Mix Design and Performance Prediction of High Calcium Fly Ash Geopolymer Concrete.

Despite extensive in-depth research into high calcium fly ash geopolymer concretes and a number of proposed methods to calculate the mix proportions, no universally applicable method to determine the mix proportions has been developed. This paper uses an artificial neural network (ANN) machine learning toolbox in a MATLAB programming environment together with a Bayesian regularization algorithm, the Levenberg-Marquardt algorithm and a scaled conjugate gradient algorithm to attain a specified target compressive strength at 28 days. The relationship between the four key parameters, namely water/solid ratio, alkaline activator/binder ratio, Na2SiO3/NaOH ratio and NaOH molarity, and the compressive strength of geopolymer concrete is determined. The geopolymer concrete mix proportions based on the ANN algorithm model and contour plots developed were experimentally validated. Thus, the proposed method can be used to determine mix designs for high calcium fly ash geopolymer concrete in the range 25-45 MPa at 28 days. In addition, the design equations developed using the statistical regression model provide an insight to predict tensile strength and elastic modulus for a given compressive strength.

Engineering Performance of Concrete Incorporated with Recycled High-Density Polyethylene (HDPE)-A Systematic Review.

Incorporating recycled plastic waste in concrete manufacturing is one of the most ecologically and economically sustainable solutions for the rapid trends of annual plastic disposal and natural resource depletion worldwide. This paper comprehensively reviews the literature on engineering performance of recycled high-density polyethylene (HDPE) incorporated in concrete in the forms of aggregates or fiber or cementitious material. Optimum 28-days' compressive and flexural strength of HDPE fine aggregate concrete is observed at HDPE-10 and splitting tensile strength at HDPE-5 whereas for HDPE coarse aggregate concrete, within the range of 10% to 15% of HDPE incorporation and at HDPE-15, respectively. Similarly, 28-days' flexural and splitting tensile strength of HDPE fiber reinforced concrete is increased to an optimum of 4.9 MPa at HDPE-3 and 4.4 MPa at HDPE-3.5, respectively, and higher than the standard/plain concrete matrix (HDPE-0) in all HDPE inclusion levels. Hydrophobicity, smooth surface texture and non-reactivity of HDPE has resulted in weaker bonds between concrete matrix and HDPE and thereby reducing both mechanical and durability performances of HDPE concrete with the increase of HDPE. Overall, this is the first ever review to present and analyze the current state of the mechanical and durability performance of recycled HDPE as a sustainable construction material, hence, advancing the research into better performance and successful applications of HDPE concrete.