Development of a Novel Passive Monitoring Technique to Showcase the 3D Distribution of Tritiated Water (HTO) Vapor in Indoor Air of a Nuclear Facility.

Tritiated water (HTO), a ubiquitous byproduct of the nuclear industry, is a radioactive contaminant of major concern for environmental authorities. Although understanding spatiotemporal heterogeneity of airborne HTO vapor holds great importance for radiological safety as well as diagnosing a reactor's status, comprehensive HTO distribution dynamics inside nuclear facilities has not been studied routinely yet due to a lack of appropriate monitoring techniques. For current systems, it is difficult to simultaneously achieve high representativeness, sensitivity, and spatial resolution. Here, we developed a passive monitoring scheme, including a newly designed passive sampler and a tailored analytical protocol for the first comprehensive 3D distribution characterization of HTO inside a nuclear reactor facility. The technique enables linear sampling in any environment at a one-day resolution and simultaneous preparation of hundreds of samples within 1 day. Validation experiments confirmed the method's good metrological properties and sensitivity to the HTO's spatial dynamics. The air in TU Wien's reactor hall exhibits a range of 3H concentrations from 75-946 mBq m-3 in the entire 3D matrix. The HTO release rate estimated by the mass-balance model (3199 ± 306 Bq h-1) matches the theoretical calculation (2947 ± 254 Bq h-1), suggesting evaporation as the dominant HTO source in the hall. The proposed method provides reliable and quality-controlled 3D monitoring at low cost, which can be adopted not only for HTO and may also inspire monitoring schemes of other indoor pollutants.

Growth and characterization of thorium-doped calcium fluoride single crystals.

We have grown [Formula: see text]Th:CaF[Formula: see text] and [Formula: see text]Th:CaF[Formula: see text] single crystals for investigations on the VUV laser-accessible first nuclear excited state of [Formula: see text]Th, with the aim of building a solid-state nuclear clock. To reach high doping concentrations despite the extreme scarcity (and radioactivity) of [Formula: see text]Th, we have scaled down the crystal volume by a factor 100 compared to established commercial or scientific growth processes. We use the vertical gradient freeze method on 3.2 mm diameter seed single crystals with a 2 mm drilled pocket, filled with a co-precipitated CaF[Formula: see text]:ThF[Formula: see text]:PbF[Formula: see text] powder in order to grow single crystals. Concentrations of [Formula: see text] cm[Formula: see text] have been realized with [Formula: see text]Th with good (> 10%) VUV transmission. However, the intrinsic radioactivity of [Formula: see text]Th drives radio-induced dissociation during growth and radiation damage after solidification. Both lead to a degradation of VUV transmission, currently limiting the [Formula: see text]Th concentration to [Formula: see text] cm[Formula: see text].

Artificial radioactivity in environmental media (air, rainwater, soil, vegetation) in Austria after the Fukushima nuclear accident.

Several environmental media in Austria were monitored for artificial radionuclides released during the Fukushima nuclear accident. Air (up to 1.2 mBq/m(3) particulate (131)I) and rainwater (up to 5.2 Bq/L (131)I) proved to be the media best suited for the environmental monitoring, allowing also a temporal resolution of the activity levels. Significant regional differences in the wet deposition of (131)I with rain could be observed within the city of Vienna during the arrival of the contaminated air masses. Forward-trajectory analysis supported the hypothesis that the contaminated air masses coming from the northwest changed direction to northeast over Northern Austria, leading to a strong activity concentration gradient over Vienna. In the course of the environmental monitoring of the Fukushima releases, this phenomenon-significant differences of (131)I activity concentrations in rainwater on a narrow local scale (8.1 km)-appears to be unique. Vegetation (grass) was contaminated with (131)I and/or (137)Cs at a low level. Soil (up to 22 Bq/kg (137)Cs) was only affected by previous releases (nuclear weapon tests, Chernobyl). Here, also significant local differences can be observed due to different deposition rates during the Chernobyl accident. The effective ecological half-lives of (137)Cs in soil were calculated for four locations in Austria. They range from 7 to 30 years. No Austrian sample investigated herein exceeded the detection limit for (134)Cs; hence, the Fukushima nuclear accident did not contribute significantly to the total radiocesium inventory in Austrian environmental media. The levels of detected radioactivity were of no concern for public health.