Biphoton engineering using modal spatial overlap on-chip.

Photon pairs generated by spontaneous parametric downconversion are essential for optical quantum information processing, in which the quality of biphoton states is crucial for the performance. To engineer the biphoton wave function (BWF) on-chip, the pump envelope function and the phase matching function are commonly adjusted, while the modal field overlap has been considered as a constant in the frequency range of interest. In this work, by using modal coupling in a system of coupled waveguides, we explore the modal field overlap as a new degree of freedom for biphoton engineering. We provide design examples for on-chip generations of polarization entangled photons and heralded single photons. This strategy can be applied to waveguides of different materials and structures, offering new possibilities for photonic quantum state engineering.

Spectrally pure photon pair generation in asymmetric heterogeneously coupled waveguides.

In this work, we develop a design methodology to generate spectrally pure photon pairs in asymmetric heterogeneously coupled waveguides by spontaneous parametric down conversion. Mode coupling in a system of waveguides is used to directly tailor the group velocity of a supermode to achieve group velocity matching that is otherwise not allowed by material dispersion. Design examples based on thin film lithium niobate waveguides are provided, demonstrating high spectral purity and temperature tunability. This approach is a versatile strategy applicable to waveguides of different materials and structures, allowing more versatility in single-photon source designs.

Distributed feedback lasers using surface gratings in Bragg waveguides.

This Letter presents, to the best of our knowledge, the first report of a narrow-linewidth ∼790-800nm edge-emitting semiconductor distributed feedback Bragg reflection waveguide diode laser (DFB2RL). The DFB2RLs were fabricated using a ridge waveguide structure with 5th order, surface-etched grating forming the wavelength selective element. Unbonded devices with a 500 µm cavity length exhibited continuous wave threshold currents in the region of 25 mA with an output power of 2.5 mW per (uncoated) facet at 100 mA drive current. The devices operated in a single longitudinal mode, with side-mode suppression ratio (SMSR) as high as 49 dB and linewidths as low as 207 kHz. Devices maintained single mode operation with high SMSR over a 9 nm wavelength range as the temperature was swept from 15°C to 50°C.

Supermode Hybridization: A Material-Independent Route toward Record Schottky Detection Sensitivity Using <0.05 µm3 Amorphous Absorber Volume.

Schottky photodetectors are attractive for CMOS-compatible photonic integrated circuits, but the inability to simultaneously optimize the metal emitter thickness for photon absorption and hot carrier emission limits the detection efficiency and sensitivity. Here, we propose and experimentally demonstrate a supermode hybridization waveguiding effect that can overcome the trade-off. By introducing structural asymmetry into coupled plasmonic nanostructures, hybridization-induced field enhancement can help ultrathin metal emitters to achieve greater optical absorption than bulk counterparts. Despite the use of amorphous materials with higher transport losses, our hybridized Schottky detectors demonstrate higher responsivity per device volume compared to crystalline-based and unhybridized Schottky designs with broadband (1.5-1.6 µm) and athermal (15-100 °C) behavior as well as record sensitivity of -55 dBm that approaches Ge counterparts that are 36 times larger. The hybridization effect can be utilized across diverse nanomaterial platforms to facilitate light-matter interaction, paving the way toward backend-compatible, chip-integrated photonics with greater manufacturing flexibility.

Monolithic Plasmonic Waveguide Architecture for Passive and Active Optical Circuits.

Guided-wave plasmonic circuits are promising platforms for sensing, interconnection, and quantum applications in the subdiffraction regime. Nonetheless, the loss-confinement trade-off remains a collective bottleneck for plasmonic-enhanced optical processes. Here, we report a unique plasmonic waveguide architecture that can alleviate such trade-off and improve the efficiencies of plasmonic-based emission, light-matter-interaction, and detection simultaneously. Specifically, record experimental attributes such as normalized Purcell factor approaching 104, 10 dB amplitude modulation with <1 dB insertion loss and fJ-level switching energy, and photodetection sensitivity and internal quantum efficiency of -54 dBm and 6.4% respectively have been realized within our amorphous-based, coupled-mode plasmonic structure. The ability to support multiple optoelectronic phenomena while providing performance gains over existing plasmonic and dielectric counterparts offers a clear path toward reconfigurable, monolithic plasmonic circuits.

Single-mode Bragg ring laser diodes.

We have designed and fabricated a monolithic semiconductor ring laser based on a Bragg waveguide structure. Through careful control of the waveguiding, we have overcome the inherent "leaky" nature of this waveguide mode and demonstrated a ring laser lasing in the Bragg mode. Best behavior was obtained from lasers with a diameter of 400 µm, where they exhibited output power ${ \gt }{1}\;{\rm mW}$>1mW, in continuous wave (CW) operation. A tangent waveguide provided access to the ring cavity using two ports through evanescent coupling. To meet the stringent waveguiding requirements imposed by the Bragg structure, a two-step etching process, consisting of a shallow-etched coupler and a deep-etched bend section of the ring, was developed in order to reduce the bend and scattering losses. The laser showed a threshold current density of ${\sim}{2.2}\;{{\rm kA/cm}^2}$∼2.2kA/cm2 in CW operation with single longitudinal mode operation with a signal-to-noise ratio of 30 dBm obtained at 1.5 ${I_{\rm th}}$Ith. Broadband phase-matching of $\chi ^{(2)}$χ(2) nonlinearity is observed, offering self-pumped parametric C-band conversion ${ \gt }{40}\;{\rm nm}$>40nm with efficiency of ${142}\% \;{{\rm W}^{ - 1}}\;{{\rm cm}^{ - 2}}$142%W-1cm-2.

Dynamically reconfigurable sources for arbitrary Gaussian states in integrated photonics circuits.

We present a modular design for integrated programmable multimode sources of arbitrary Gaussian states of light. The technique is based on current technologies, in particular recent demonstrations of on-chip photon manipulation and the generation of highly squeezed vacuum states in semiconductors. While the design is generic and independent of the choice of integrated platform, we adopt recent experimental results on compound semiconductors as a demonstrative example. Such a device would be valuable as a source for many quantum protocols that range from imaging to communication and information processing.

Multilayer Black Phosphorus as a Versatile Mid-Infrared Electro-optic Material.

We investigate the electro-optic properties of black phosphorus (BP) thin films for optical modulation in the mid-infrared frequencies. Our calculation indicates that an applied out-of-plane electric field may lead to red-, blue-, or bidirectional shift in BP's absorption edge. This is due to the interplay between the field-induced quantum-confined Franz-Keldysh effect and the Pauli-blocked Burstein-Moss shift. The relative contribution of the two electro-absorption mechanisms depends on doping range, operating wavelength, and BP film thickness. For proof-of concept, simple modulator configuration with BP overlaid over a silicon nanowire is studied. Simulation results show that operating BP in the quantum-confined Franz-Keldysh regime can improve the maximal attainable absorption as well as power efficiency compared to its graphene counterpart.

Size-Tunable Photothermal Germanium Nanocrystals.

Germanium nanocrystals (ncGe) have not received as much attention as silicon nanocrystals (ncSi). However, Ge has demonstrated superiority over Si nanomaterials in some applications. Examples include, high charge-discharge rate lithium-ion batteries, small band-gap opto-electronic devices, and photo-therapeutics. When stabilized in an oxide matrix (ncGe/GeOx ), its high charge-retention has enabled non-volatile memories. It has also found utility as a high-capacity anode material for Li-ion batteries with impressive stability. Herein, we report an organic-free synthesis of size-controlled ncGe in a GeOx matrix as well as freestanding ncGe, via the thermal disproportionation of GeO prepared from thermally induced dehydration of Ge(OH)2 . The photothermal effect of ncGe, quantified by Raman spectroscopy, is found to be size dependent and superior to ncSi. This advance suggests applications of ncGe in photothermal therapy, desalination, and catalysis.

Monolithic semiconductor chips as a source for broadband wavelength-multiplexed polarization entangled photons.

Generating entangled photons from a monolithic chip is a major milestone towards real-life applications of optical quantum information processing including quantum key distribution and quantum computing. Ultrabroadband entangled photons are of particular interest to various applications such as quantum metrology and multi-party entanglement distribution. In this work, we demonstrate the direct generation of broadband wavelength-multiplexed polarization entangled photons from a semiconductor chip for the first time. Without the use of any off-chip compensation or interferometry, entangled photons with a signal-idler separation as large as 95 nm in the telecom band were observed. The highest concurrence of 0.98±0.01 achieved in this work is also the highest, to the best of our knowledge, comparing to all previously demonstrated semiconductor waveguide sources. This work paves the way for fully integrated, ultrabroadband sources of polarization entangled photons.

Injection locking for stable all-optical pulse generation via gain-induced FWM.

We propose and demonstrate a technique to stabilize pulse generation based on gain-induced four wave mixing (FWM) via injection locking with no feedback. Robust and low-phase noise pulse generation was achieved. Pulse-train generation from 230 MHz to ∼76 GHz with a linewidth of ∼1 Hz is experimentally demonstrated. The injection locking effectively narrows the linewidth of the generated pulse by four orders of magnitude. The fiber ring cavity reduces the sideband phase noise by 100 times and suppresses the residual injection signal by three orders of magnitude.

Widely tunable frequency conversion in monolithic semiconductor waveguides at 2.4 µm.

We report on the generation of continuous-wave widely tunable light between 2360 and 2530 nm using difference-frequency generation with a pump tuned between 938 and 952 nm and a signal tuned between 1490 and 1590 nm in a type-II phase-matched monolithic semiconductor waveguide. The device internal conversion efficiency is estimated to be 0.29% W(-1) cm(-2). This design which uses a single-sided Bragg reflection waveguide has the potential for on-chip spectroscopy, as well as environmental monitoring applications, where a tunable source of coherent radiation tuned between 2 and 3 µm wavelength is desired.

Gigahertz to terahertz tunable all-optical single-side-band microwave generation via semiconductor optical amplifier gain engineering.

We propose and demonstrate a technique to generate low-noise broadly tunable single-side-band microwaves using cascaded semiconductor optical amplifiers (SOAs) using no RF bias. The proposed technique uses no RF components and is based on polarization-state controlled gain-induced four-wave mixing in SOAs. Microwave generation from 40 to 875 GHz with a line-width ~22 KHz is experimentally demonstrated.

All-optical pulse generation based on gain-induced four-wave mixing in a semiconductor optical amplifier.

A simple all-optical pulse generation technique based on gain-induced four-wave mixing in a semiconductor optical amplifier is introduced. The introduced concept is theoretically investigated and experimentally demonstrated. For a concept demonstration, 10 GHz and 42.5 GHz pulse trains are generated. A 20 nm central wavelength tunability is achieved.

Widely tunable mid-infrared generation via frequency conversion in semiconductor waveguides.

Phase matching in a multilayer AlGaAs waveguide is used to generate mid-IR (7.5-8.5 µm) light through difference frequency generation (DFG) between a 1550 nm pump and 1950 nm signal. This represents the longest wavelength generated through DFG in a 2D waveguide mode in a semiconductor waveguide. It was produced with an efficiency of 1.2×10(-4) %/W in a 1 mm long sample. The process is shown to be tunable across >2 µm through appropriate tuning of the input pump and signal wavelengths and/or waveguide geometry, and is therefore a viable platform for monolithic, tunable, mid-IR sources.

Compact all-fiber quantum-inspired LiDAR with over 100 dB noise rejection and single photon sensitivity.

Entanglement and correlation of quantum light can enhance LiDAR sensitivity in the presence of strong background noise. However, the power of such quantum sources is fundamentally limited to a stream of single photons and cannot compete with the detection range of high-power classical LiDAR transmitters. To circumvent this, we develop and demonstrate a quantum-inspired LiDAR prototype based on coherent measurement of classical time-frequency correlation. This system uses a high-power classical source and maintains the high noise rejection advantage of quantum LiDARs. In particular, we show that it can achieve over 100dB rejection (with 100ms integration time) of indistinguishable (with statistically identical properties in every degree of freedom) in-band noise while still being sensitive to single photon signals. In addition to the LiDAR demonstration, we also discuss the potential of the proposed LiDAR receiver for quantum information applications. In particular, we propose the chaotic quantum frequency conversion technique for coherent manipulation of high dimensional quantum states of light. It is shown that this technique can provide improved performance in terms of selectivity and efficiency as compared to pulse-based quantum frequency conversion.

Concentration-dependent structural transitions of human telomeric DNA sequences.

Oligodeoxyribonucleotides (ODNs) that have four repeats of the human telomeric sequence d(TTAGGG)(n) can assume multiple monomolecular G-quadruplex topologies. These are determined by the cation species present, the bases at the 5' or 3' end, and the sample preparation technique. In this work, we report our studies of the concentration dependence of the circular dichroism (CD) and the vibrational modes probed by Raman scattering of three previously characterized monomolecular G-quadruplexes: H-Tel, d[5'-A(GGGTTA)(3)GGG-3']; hybrid-1, d[5'-AAA(GGGTTA)(3)GGGAA-3']; and hybrid-2, d[5'-TTA(GGGTTA)(3)GGGTT-3']. At high (millimolar) ODN concentrations, we observed a transformation of the CD spectrum of H-Tel, with a relaxation time on the order of 10 h. Analysis of the kinetics of this process is consistent with the formation of an aggregated complex of folded H-Tel monomers. Upon dilution, the aggregates dissociate rapidly, yielding spectra identical to those of monomeric H-Tel. Both hybrid sequences undergo a similar transition under high-salt (1 M) conditions. The measurements suggest that for these ODN concentrations, which are typically used in high-resolution spectroscopies, the monomolecular G-quadruplex structures undergo a transition to multimolecular structures at room temperature. Guided by our findings, we propose that the terminal bases of the hybrid-1 and hybrid-2 ODNs impede the formation of these aggregates; however, in solutions containing 1 M salt, the hybrid oligonucleotides aggregate.

Generation of polarization entangled photons using concurrent type-I and type-0 processes in AlGaAs ridge waveguides.

A technique to generate polarization entangled photons using concurrent type-I and type-0 second-order nonlinear processes in monolithic Bragg reflection waveguides is presented and analyzed. Concurrent phase matching is achieved by lithographic tuning of the waveguide ridge width. Nearly perfect entanglement is achievable on-chip through appropriate epistructure design without the need of spectral filtering and group velocity compensation. Theoretical calculations predict that a high quantum interference visibility could be experimentally achieved with the pair generation rate of each process being approximately 3.0×10(6) pairs/s/mW/GHz.

Examining metal nanoparticle surface chemistry using hollow-core, photonic-crystal, fiber-assisted SERS.

In this Letter, we demonstrate the efficacy of hollow core photonic crystal fibers (HCPCFs) as a surface-enhanced Raman spectroscopy (SERS) platform for investigating the ligand exchange process on the surface of gold nanoparticles. Raman measurements carried out using this platform show the capability to monitor minute amounts of surface ligands on gold nanoparticles used as an SERS substrate. The SERS signal from an HCPCF exhibits a tenfold enhancement compared to that in a direct sampling scheme using a cuvette. Using exchange of cytotoxic cetyltrimethylammonium bromide with α-methoxy-ω-mercaptopoly(ethylene glycol) on the surface of gold nanorods as an exemplary system, we show the feasibility of using HCPCF SERS to monitor the change in surface chemistry of nanoparticles.

Quantum and non-local effects offer over 40 dB noise resilience advantage towards quantum lidar.

Non-local effects have the potential to radically move forward quantum enhanced imaging to provide an advantage over classical imaging not only in laboratory environments but practical implementation. In this work, we demonstrate a 43dB higher signal-to-noise ratio (SNR) using a quantum enhanced LiDAR based on time-frequency entanglement compared with a classical phase-insensitive quantum imaging system. Our system can tolerate more than 3 orders of magnitude higher noise than classical single-photon counting quantum imaging systems before detector saturation with a detector dead time of 25ns. To achieve these advantages, we use non-local cancellation of dispersion to take advantage of the strong temporal correlations in photon pairs in spite of the orders of magnitude larger detector temporal uncertainty. We go on to incorporate this scheme with purpose-built scanning collection optics to image non-reflecting targets in an environment with noise.