RESUMO
It is critical to design bifunctional passivation molecules to simultaneously passivate the charge transport layer and perovskite layer at the charge transport layer/perovskite interface in perovskite solar cells (PSCs). In this study, we investigate the effect of para-substituted benzoic acid with different Hammett constants (σ) on the photovoltaic performance of PSCs. Two passivation molecules 4-aminomethylbenzoic acid (4-AMBA) and 4-sulfamoylbenzoic acid (4-SABA) are used to passivate the SnO2 surface with carboxylic acid and the perovskite with para-substituent electron-donating -CH2NH2 (σ = ca. -0.02) and electron-withdrawing -SO2NH2 (σ = ca. +0.60). Compared with non-passivated PSC, the passivation improves the power conversion efficiency (PCE) mainly due to the increased open-circuit voltage (VOC) and fill factor (FF), where the -SO2NH2 substituent is better in improving the photovoltaic performance than the -CH2NH2 one. The trap density is more reduced and the charge extraction ability is more improved by 4-SABA than by 4-AMBA, which indicates that the weak electron-withdrawing nature of a para-substituent such as -SO2NH2 is better for the passivation of the bottom perovskite than a weak electron-donating -CH2NH2 substituent. Consequently, the passivation with 4-SABA enhances the PCE from 22.27% to 23.64%, along with improved long-term stability. This work highlights for the first time the role of the Hammett constant in the surface passivation of PSCs.
RESUMO
In this study, the shear performance of a reinforced concrete (RC) beam with Fe-based shape memory alloy (Fe-SMA) stirrups was evaluated experimentally and analytically. Five specimens that had a possibility of shear failure under four-point loading were prepared. The major experimental variables were the spacings (300 and 200 mm) between the Fe-SMA stirrups and whether the stirrups were activated or non-activated. The shear strength of the specimen reinforced with the Fe-SMA stirrups at a spacing of 200 mm was 27.1% higher than that of the specimen reinforced at a spacing of 300 mm. The activation of the Fe-SMA stirrups, which produced active confining pressure, increased the shear strength by up to 7.6% and decreased the number of shear cracks compared to the case of the non-activated specimen. Therefore, the use of Fe-SMA stirrups could significantly improve the usability of concrete members by increasing their shear strength and initial stiffness and by controlling crack formation. Furthermore, finite element method (FEM) analysis was conducted using LS-DYNA, a commercial software program, to predict the shear performance of the RC beam reinforced with the Fe-SMA stirrups. The ultimate load and displacement of each specimen were predicted with errors less than 1.4 and 9.4%, respectively. Furthermore, the FEM predicted the change in failure mode and the stiffness improvement due to the activation of the Fe-SMA stirrups. Therefore, the proposed finite element analysis model can effectively predict the behavior of an RC beam reinforced with Fe-SMA stirrups.
RESUMO
This paper proposes the mixing design of concrete having modified sulfur-coated aggregate (MSCA) to enhance the durability of Portland cement concrete. The mechanical properties and durability of the proposed MSCA concrete were evaluated experimentally. Melting-modified sulfur was mixed with aggregate in order to coat the aggregate surface at a speed of 20 rpm for 120 s. The MSCA with modified sulfur corresponding to 5% of the cement weight did not significantly affect the flexural strength in a prism concrete beam specimen, regardless of the water-cement ratio (W/C). However, a dosage of more than 7.5% decreased the flexural strength. On the other hand, the MSCA considerably improved the resistance to the sulfuric acid and the freezing-thawing, regardless of the sulfur dosage in the MSCA. The coating modified sulfur of 5% dosage consequently led to good results for the mechanical properties and durability of MSCA concrete.