WO3/Pt/PEG/SiO2 porous film for hydrogen sensing by the sol-gel method.

Tungsten oxide (W O 3) has been widely used in hydrogen sensing due to its stable chemical properties and high oxygen vacancy diffusion coefficient. However, the response of pure W O 3 to hydrogen is slow, and doping is an effective way to improve the hydrogen sensing performance of W O 3 materials. In this paper, W O 3/P t/P E G/S i O 2 porous film was prepared by the sol-gel method using tungsten powder, H 2 O 2 and C 2 H 5 O H as precursors, polyethylene glycol (PEG) as the pore-forming agent, and tetraethyl orthosilicate (TEOS) as the S i O 2 source material. The sensing properties of the W O 3 composite for hydrogen were characterized by a transmission optical fiber hydrogen sensing system made at home. The process parameters such as water bath time, aging time, W:PEG ratio, and W:TEOS ratio were optimized to improve the sensitivity and response time of the sensing film. The experimental results indicate that the sensitivity is 15.68%, the average response time is 45 s, and the repeatability is up to 98.74% in 16 consecutive tests. The linearity index R 2 is 0.9946 within the hydrogen concentration range of 5000 ppm to 50,000 ppm. The film responds only to H 2 when the concentration of interfering gases (C H 4, CO, C O 2) is 2000 ppm. The hydrogen sensing performance of the optimized film is significantly improved compared with that of the undoped film.

pH biosensors based on hydrogel optical fiber.

This paper presents a hydrogel optical fiber fluorescence pH sensor doped with 5(6)-carboxyfluorescein (5(6)-FAM). The hydrogel optical fiber was fabricated with 2-hydroxy-2-methylpropiophenone as a photoinitiator, with different concentrations of polyethylene glycol diacrylate (PEGDA) for the core and cladding. A pH-sensitive fluorescence indicator 5(6)-FAM was doped into the core of the fiber. The prepared hydrogel optical fiber pH sensor showed good response within the pH range of 5.0-9.0. The linear range of the pH sensor is 6.0 to 8.0, with R 2=0.9904; within this range, the sensor shows good repeatability and reversibility, and the resolution is 0.07 pH units. The pHs of pork tissues soaked in different pH buffers were detected by the hydrogel optical fiber pH sensor; the linearity is 0.9828 when the pork tissue pH is in the range of 6.0-7.5. Due to the good ion permeability and biocompatibility of the hydrogel, this hydrogel optical fiber pH sensor is expected to be used in biomedical applications.

Improved phase-measuring deflectometry for aspheric surfaces test.

An improved phase-measuring deflectometry (PMD) is presented for the aspheric surfaces test. We explore this method from the Ronchi test in a reverse way. With this concept, a camera aperture is placed near the center of curvature of the test mirror, and fringes are displayed on a liquid crystal display screen. The fringes reflected off the test mirror are observed by the camera. By analyzing the captured fringes, the deviations of the test mirror from its ideal shape are obtained and the aspheric surface under test is reconstructed. Compared with traditional PMD, this method needs only to determine reflected rays and doesn't need to know the corresponding incident rays by calibrations, moving screen, or approximation. Both a computer simulation and preliminary experiment have been carried out to demonstrate the validity of the improved PMD. This improved PMD provides a new tool to measure aspheric surfaces quantitatively in full field for optical manufacturing.

Distorted Dammann grating.

We introduce the Dammann phase-encoding method into original distorted gratings and propose a modified distorted grating, called a distorted Dammann grating (DDG), to realize multiplane imaging of several tens of layers within the object field onto a single image plane. This property implies that the DDG makes it possible to achieve simultaneously high axial resolving power and large axial imaging range without scanning. This DDG should be of high interest for its potential applications in real-time three-dimensional optical imaging and tracking. Multiplane imaging of 7×7 object layers onto a single camera plane is experimentally demonstrated using a 7×7 DDG for an objective of NA=0.127.

Generation of dipole vortex array using spiral Dammann zone plates.

We propose a new diffractive optical element, called a spiral Dammann zone plate (SDZP), to generate a series of dipole vortices along the optical axis in the focal region of a focusing objective. By combining this SDZP and another Dammann grating, we describe the generation of three-dimensional dipole vortex arrays in the focal volume of an objective. For experimental demonstration, a 1×5 SDZP with base charge of l=1 is fabricated by using lithography and wet-etching techniques, and a 1×5 coaxial dipole vortex array is achieved for an objective of NA=0.127. Furthermore, by combining the 1×5 SDZP and another 5×5 Dammann grating, a 5×5×5 dipole vortex array is also experimentally demonstrated. The results show that topological charges of these 5×5 vortex arrays on five coaxial planes could be tunable by selecting a vortex beam carrying different charge as the incident field.

Polarization-independent wideband mixed metal dielectric reflective gratings.

A polarization-independent wideband mixed metal dielectric grating with high efficiency of the -1st order is analyzed and designed in Littrow mounting. The mixed metal dielectric grating consists of a rectangular-groove transmission dielectric grating on the top layer and a highly reflective mirror composed of a connecting layer and a metal film. Simplified modal analysis is carried out, and it shows that when the phase difference accumulated by the two propagating modes is odd multiples of π/2, the diffraction efficiency of the -1st order will be high. Selecting grating depth and duty cycle for satisfying the phase difference condition for both TE (electric field parallel to grooves) and TM (magnetic field parallel to grooves) polarizations, a polarization-independent high-efficiency grating can be designed. Using rigorous coupled-wave analysis and a simulated annealing algorithm, geometric parameters of the reflective grating are exactly obtained. The optimized grating for operation around a wavelength of 800 nm exhibits diffraction efficiencies higher than 90% for both TE and TM polarizations over a 120 nm wavelength bandwidth. The simplified modal analysis can be applied in other types of reflective gratings if the top layer is a dielectric transmission grating.

Circular Dammann grating under high numerical aperture focusing.

Circular Dammann grating (CDG) under high numerical aperture (NA) focusing is described based on Richards-Wolf vectorial diffraction theory in this paper. Several CDGs are presented under the condition of NA=0.9 with the illumination of circularly polarized plane-wave laser beams. Numerical results show that the sizes of these circular patterns with equal-intensity are in the wavelength scale, and doughnut-shaped central spots and dark rings are in the subwavelength width. To verify this kind of CDG, a binary pure-phase three-order CDG is fabricated to produce a dark center pattern surrounded by three concentric bright rings. The corresponding intensity distribution of the pattern on the focal plane of a high-NA objective (NA=0.9) is measured, and the results agree well with theoretical simulations. This kind of CDG with annular patterns of equal-intensity in the wavelength scale should be highly interesting for its potential applications in optical trapping, stimulated emission depletion (STED) microscopy, and the study of singular optics, as well as annular array illumination.

Three-dimensional Dammann vortex array with tunable topological charge.

We describe a kind of true 3D array of focused vortices with tunable topological charge, called the 3D Dammann vortex array. This 3D Dammann vortex array is arranged into the structure of a true 3D lattice in the focal region of a focusing objective, and these focused vortices are located at each node of the 3D lattice. A scheme based on a Dammann vortex grating (DVG) and a mirror is proposed to provide a choice for changing the topological charge of the 3D Dammann vortex array. For experimental demonstration, a 5×5×5 Dammann vortex array is implemented by combining a 1×7 DVG, a 1×5 Dammann zone plate, and another 5×5 Dammann grating. The topological charge of this Dammann vortex array can be tuned (from -2 to +2 with an interval of +1) by moving and rotating the mirror to select different diffraction orders of the 1×7 DVG as the incident beam. Because of these attractive properties, this 3D Dammann vortex array should be of high interest for its potential applications in various areas, such as 3D simultaneous optical manipulation, 3D parallel vortex scanning microscope, and also parallel vortex information transmission.